{"id":"https://openalex.org/W2320480353","doi":"https://doi.org/10.1107/s1600536812049434","title":"Aqua(4-cyanopyridine-\u03baN4)(5,10,15,20-tetraphenylporphyrinato-\u03ba4N)magnesium","display_name":"Aqua(4-cyanopyridine-\u03baN4)(5,10,15,20-tetraphenylporphyrinato-\u03ba4N)magnesium","publication_year":2012,"publication_date":"2012-12-07","ids":{"openalex":"https://openalex.org/W2320480353","doi":"https://doi.org/10.1107/s1600536812049434","mag":"2320480353","pmid":"https://pubmed.ncbi.nlm.nih.gov/23476319","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/3588276"},"language":"en","primary_location":{"id":"doi:10.1107/s1600536812049434","doi":"https://doi.org/10.1107/s1600536812049434","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812049434","pdf_url":null,"source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1107/s1600536812049434","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5035908266","display_name":"Khaireddine Ezzayani","orcid":"https://orcid.org/0000-0001-9334-6788","observed_orcids":["https://orcid.org/0000-0001-9334-6788"]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Khaireddine Ezzayani","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l'Environnement, 5019 Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l'Environnement, 5019 Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110387251","display_name":"M. Salah Belkhiria","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Mohamed Salah Belkhiria","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l\u2019Environnement, 5019 Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l\u2019Environnement, 5019 Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037099802","display_name":"Shabir Najmudin","orcid":"https://orcid.org/0000-0002-0429-5454","observed_orcids":["https://orcid.org/0000-0002-0429-5454"]},"institutions":[{"id":"https://openalex.org/I4405264366","display_name":"Universidade T\u00e9cnica de Lisboa","ror":"https://ror.org/01qc02b16","country_code":"PT","type":"education","lineage":["https://openalex.org/I141596103","https://openalex.org/I4405264366"]}],"countries":["PT"],"is_corresponding":false,"raw_author_name":"Shabir Najmudin","raw_affiliation_strings":["Faculdade de Medicina, Veterin\u00e0ria, Universidade Tecnica de Lisboa, Avenida da Universidade Tecnica, 1300-477 Lisboa, Portugal"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculdade de Medicina, Veterin\u00e0ria, Universidade Tecnica de Lisboa, Avenida da Universidade Tecnica, 1300-477 Lisboa, Portugal","institution_ids":["https://openalex.org/I4405264366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047369633","display_name":"C. Bonif\u00e1cio","orcid":"https://orcid.org/0000-0002-5660-7333","observed_orcids":["https://orcid.org/0000-0002-5660-7333"]},"institutions":[{"id":"https://openalex.org/I83558840","display_name":"Universidade Nova de Lisboa","ror":"https://ror.org/02xankh89","country_code":"PT","type":"education","lineage":["https://openalex.org/I83558840"]}],"countries":["PT"],"is_corresponding":false,"raw_author_name":"Cecilia Bonif\u00e1cio","raw_affiliation_strings":["REQUIMTE/CQFB Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"REQUIMTE/CQFB Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal","institution_ids":["https://openalex.org/I83558840"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014522854","display_name":"Habib Nasri","orcid":"https://orcid.org/0000-0002-7565-8240","observed_orcids":["https://orcid.org/0000-0002-7565-8240"]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":true,"raw_author_name":"Habib Nasri","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l'Environnement, 5019 Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Universit\u00e9 de Monastir, Facult\u00e9 des Sciences de Monastir, Avenue de l'Environnement, 5019 Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5014522854"],"corresponding_institution_ids":["https://openalex.org/I166928557"],"apc_list":{"value":500,"currency":"USD","value_usd":500},"apc_paid":{"value":500,"currency":"USD","value_usd":500},"fwci":0.1304,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.44738964,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":93},"biblio":{"volume":"69","issue":"1","first_page":"m17","last_page":"m18"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.875,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.875,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.11900000274181366,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12441","display_name":"Porphyrin Metabolism and Disorders","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/magnesium-complexes","display_name":"magnesium complexes","score":0.8889999985694885},{"id":"https://openalex.org/keywords/tetraphenylporphyrin","display_name":"tetraphenylporphyrin","score":0.9480000138282776},{"id":"https://openalex.org/keywords/aqua-ligands","display_name":"aqua ligands","score":0.8069999814033508},{"id":"https://openalex.org/keywords/octahedral-coordination","display_name":"octahedral coordination","score":0.9010000228881836},{"id":"https://openalex.org/keywords/inversion-center","display_name":"inversion centre","score":0.5059999823570251},{"id":"https://openalex.org/keywords/substitutional-disorder","display_name":"substitutional disorder","score":0.7379999756813049},{"id":"https://openalex.org/keywords/crystal-packing","display_name":"crystal packing","score":0.8460000157356262},{"id":"https://openalex.org/keywords/c-hpi-interactions","display_name":"C-H\u22ef\u03c0 interactions","score":0.8309999704360962},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.44699999690055847}],"concepts":[{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.7395100593566895},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.685767412185669},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6698741316795349},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.6639783382415771},{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.6063234210014343},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5936948657035828},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.48981377482414246},{"id":"https://openalex.org/C2777873363","wikidata":"https://www.wikidata.org/wiki/Q13533436","display_name":"Tetra","level":2,"score":0.487621933221817},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4744735062122345},{"id":"https://openalex.org/C2779400197","wikidata":"https://www.wikidata.org/wiki/Q242627","display_name":"Pyrrole","level":2,"score":0.4120291769504547},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.296429842710495},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.1358477771282196},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.08568498492240906},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.05127868056297302},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1107/s1600536812049434","doi":"https://doi.org/10.1107/s1600536812049434","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812049434","pdf_url":null,"source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},{"id":"pmh:oai:europepmc.org:2591293","doi":null,"is_oa":true,"landing_page_url":"http://europepmc.org/articles/PMC3588276","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"","raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:3588276","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3588276","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallogr Sect E Struct Rep Online","raw_type":"Text"},{"id":"pmid:23476319","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23476319","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta crystallographica. Section E, Structure reports online","raw_type":"Journal Article"},{"id":"pmh:oai:doaj.org/article:132d3ae0728d488f8d345591692b75ad","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/132d3ae0728d488f8d345591692b75ad","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta Crystallographica Section E, Vol 69, Iss 1, Pp m17-m18 (2013)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.1107/s1600536812049434","doi":"https://doi.org/10.1107/s1600536812049434","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812049434","pdf_url":null,"source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4245398301","display_name":"Estrutura, fun\u00e7\u00e3o e mecanismos de ac\u00e7\u00e3o de novas Glicosido Hidrolases e M\u00f3dulos de Liga\u00e7\u00e3o a Carbohidratos do celulossoma do Clostridium thermocellum","funder_award_id":"PTDC/BIA-PRO/103980/2008","funder_id":"https://openalex.org/F4320334779","funder_display_name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia"}],"funders":[{"id":"https://openalex.org/F4320310000","display_name":"Universidade de Aveiro","ror":"https://ror.org/00nt41z93"},{"id":"https://openalex.org/F4320334779","display_name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","ror":"https://ror.org/00snfqn58"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1972124215","https://openalex.org/W1975217371","https://openalex.org/W1986502985","https://openalex.org/W1990170643","https://openalex.org/W2019413807","https://openalex.org/W2032842297","https://openalex.org/W2052946234","https://openalex.org/W2056865348","https://openalex.org/W2077678053","https://openalex.org/W2131350133","https://openalex.org/W2225667184"],"related_works":["https://openalex.org/W1888635688","https://openalex.org/W7100144379","https://openalex.org/W2057361220","https://openalex.org/W2129870970","https://openalex.org/W2228891360","https://openalex.org/W4252390368","https://openalex.org/W2070629195","https://openalex.org/W1976479479","https://openalex.org/W2055178560","https://openalex.org/W2319939393"],"abstract_inverted_index":{"In":[0],"the":[1,5,18,37,45,49,54,58,69],"title":[2],"complex,":[3],"[Mg(C44H28N4)(C6H4N2)(H2O)],":[4],"Mg(2+)":[6],"cation":[7],"is":[8,34,74,81],"octa-hedrally":[9],"coordinated":[10],"and":[11,22,64,68],"lies":[12],"on":[13],"an":[14],"inversion":[15,38],"center":[16],"with":[17],"axially":[19],"located":[20],"4-cyano-pyridine":[21,31],"aqua":[23],"ligands":[24],"exhibiting":[25],"50%":[26],"substitutional":[27],"disorder.":[28],"The":[29,40,78],"cyano-bound":[30],"mol-ecule":[32],"also":[33],"disordered":[35],"across":[36],"centre.":[39],"four":[41],"N":[42],"atoms":[43],"of":[44,48,57],"pyrrole":[46],"rings":[47],"dianionic":[50],"5,10,15,20-tetra-phenyl-porphyrin":[51],"ligand":[52],"occupy":[53],"equatorial":[55],"sites":[56],"octa-hedron":[59],"[Mg-N":[60],"=":[61],"2.0552":[62],"(10)":[63],"2.0678":[65],"(11)":[66],"\u00c5]":[67],"axial":[70],"Mg-(N,O)":[71],"bond":[72],"length":[73],"2.3798":[75],"(12)":[76],"\u00c5.":[77],"crystal":[79],"packing":[80],"stabilized":[82],"by":[83],"weak":[84],"inter-molecular":[85],"C-H\u22ef\u03c0":[86],"inter-actions.":[87]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}