{"id":"https://openalex.org/W2320190455","doi":"https://doi.org/10.1515/zna-1987-0509","title":"Assignment for the Infrared Spectrum of Solid Sodium Propionate from Low-Temperature Measurements in Combination with 13C Isotopic Shifts","display_name":"Assignment for the Infrared Spectrum of Solid Sodium Propionate from Low-Temperature Measurements in Combination with 13C Isotopic Shifts","publication_year":1987,"publication_date":"1987-05-01","ids":{"openalex":"https://openalex.org/W2320190455","doi":"https://doi.org/10.1515/zna-1987-0509","mag":"2320190455"},"language":"en","primary_location":{"id":"doi:10.1515/zna-1987-0509","doi":"https://doi.org/10.1515/zna-1987-0509","is_oa":true,"landing_page_url":"https://doi.org/10.1515/zna-1987-0509","pdf_url":"https://www.degruyter.com/document/doi/10.1515/zna-1987-0509/pdf","source":{"id":"https://openalex.org/S4210168924","display_name":"Zeitschrift f\u00fcr Naturforschung A","issn_l":"0340-4811","issn":["0340-4811","0932-0784","1865-7109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310313990","host_organization_name":"De Gruyter","host_organization_lineage":["https://openalex.org/P4310313990"],"host_organization_lineage_names":["De Gruyter"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Zeitschrift f\u00fcr Naturforschung A","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://www.degruyter.com/document/doi/10.1515/zna-1987-0509/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109921124","display_name":"Masato Kakihana","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I443798","display_name":"National Defense Academy of Japan","ror":"https://ror.org/05xszy717","country_code":"JP","type":"education","lineage":["https://openalex.org/I443798"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masato Kakihana","raw_affiliation_strings":["Department of Chemistry, The National Defense Academy, Yokosuka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The National Defense Academy, Yokosuka, Japan","institution_ids":["https://openalex.org/I443798"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5108594932","display_name":"Tadashi Nagumo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I443798","display_name":"National Defense Academy of Japan","ror":"https://ror.org/05xszy717","country_code":"JP","type":"education","lineage":["https://openalex.org/I443798"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Tadashi Nagumo","raw_affiliation_strings":["Department of Chemistry, The National Defense Academy, Yokosuka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The National Defense Academy, Yokosuka, Japan","institution_ids":["https://openalex.org/I443798"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I443798"],"apc_list":{"value":2400,"currency":"EUR","value_usd":2712},"apc_paid":{"value":2400,"currency":"EUR","value_usd":2712},"fwci":0.0,"has_fulltext":true,"cited_by_count":12,"citation_normalized_percentile":{"value":0.24318064,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"42","issue":"5","first_page":"477","last_page":"484"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.7143999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.7143999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.16769999265670776,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.06669999659061432,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sodium-propionate","display_name":"sodium propionate","score":0.953000009059906},{"id":"https://openalex.org/keywords/infrared-spectra","display_name":"infrared spectra","score":0.6980000138282776},{"id":"https://openalex.org/keywords/fundamental-vibrations","display_name":"fundamental vibrational frequencies","score":0.5569999814033508},{"id":"https://openalex.org/keywords/13c-labeled-compounds","display_name":"13C-labeled compounds","score":0.6830000281333923},{"id":"https://openalex.org/keywords/low-temperature-infrared-spectroscopy","display_name":"low-temperature infrared spectroscopy","score":0.8259999752044678},{"id":"https://openalex.org/keywords/liquid-nitrogen-temperature","display_name":"liquid nitrogen temperature","score":0.6949999928474426},{"id":"https://openalex.org/keywords/coupled-vibrational-modes","display_name":"coupled vibrational modes","score":0.734000027179718}],"concepts":[{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.6324608325958252},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5831120014190674},{"id":"https://openalex.org/C108939769","wikidata":"https://www.wikidata.org/wiki/Q1139370","display_name":"Liquid nitrogen","level":2,"score":0.5817470550537109},{"id":"https://openalex.org/C2780014933","wikidata":"https://www.wikidata.org/wiki/Q422956","display_name":"Propionate","level":2,"score":0.5785372257232666},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.5655206441879272},{"id":"https://openalex.org/C52003146","wikidata":"https://www.wikidata.org/wiki/Q909660","display_name":"Isotopic shift","level":3,"score":0.5590396523475647},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.5105980038642883},{"id":"https://openalex.org/C2778074193","wikidata":"https://www.wikidata.org/wiki/Q3498942","display_name":"Carboxylate","level":2,"score":0.5037614703178406},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.47945085167884827},{"id":"https://openalex.org/C2777454769","wikidata":"https://www.wikidata.org/wiki/Q11172462","display_name":"Methylene","level":2,"score":0.4404948949813843},{"id":"https://openalex.org/C138268822","wikidata":"https://www.wikidata.org/wiki/Q1051925","display_name":"Resolution (logic)","level":2,"score":0.4311105012893677},{"id":"https://openalex.org/C2781271576","wikidata":"https://www.wikidata.org/wiki/Q420130","display_name":"Sodium propionate","level":3,"score":0.4223178029060364},{"id":"https://openalex.org/C537181965","wikidata":"https://www.wikidata.org/wiki/Q658","display_name":"Sodium","level":2,"score":0.4184415936470032},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.36563098430633545},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.2412075698375702},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14987078309059143},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.13301008939743042},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C154945302","wikidata":"https://www.wikidata.org/wiki/Q11660","display_name":"Artificial intelligence","level":1,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1515/zna-1987-0509","doi":"https://doi.org/10.1515/zna-1987-0509","is_oa":true,"landing_page_url":"https://doi.org/10.1515/zna-1987-0509","pdf_url":"https://www.degruyter.com/document/doi/10.1515/zna-1987-0509/pdf","source":{"id":"https://openalex.org/S4210168924","display_name":"Zeitschrift f\u00fcr Naturforschung A","issn_l":"0340-4811","issn":["0340-4811","0932-0784","1865-7109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310313990","host_organization_name":"De Gruyter","host_organization_lineage":["https://openalex.org/P4310313990"],"host_organization_lineage_names":["De Gruyter"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Zeitschrift f\u00fcr Naturforschung A","raw_type":"journal-article"},{"id":"pmh:oai:irdb.nii.ac.jp:00897:0003861578","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100425056","pdf_url":null,"source":{"id":"https://openalex.org/S7407056385","display_name":"Institutional Repositories DataBase (IRDB)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I184597095","host_organization_name":"National Institute of Informatics","host_organization_lineage":["https://openalex.org/I184597095"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Zeitschrift fur Naturforschung","raw_type":"journal article"},{"id":"pmh:oai:t2r2.star.titech.ac.jp:00026777","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100425056","pdf_url":null,"source":{"id":"https://openalex.org/S4377196385","display_name":"Tokyo Tech Research Repository (Tokyo Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114531698","host_organization_name":"Tokyo Institute of Technology","host_organization_lineage":["https://openalex.org/I114531698"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1515/zna-1987-0509","doi":"https://doi.org/10.1515/zna-1987-0509","is_oa":true,"landing_page_url":"https://doi.org/10.1515/zna-1987-0509","pdf_url":"https://www.degruyter.com/document/doi/10.1515/zna-1987-0509/pdf","source":{"id":"https://openalex.org/S4210168924","display_name":"Zeitschrift f\u00fcr Naturforschung A","issn_l":"0340-4811","issn":["0340-4811","0932-0784","1865-7109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310313990","host_organization_name":"De Gruyter","host_organization_lineage":["https://openalex.org/P4310313990"],"host_organization_lineage_names":["De Gruyter"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Zeitschrift f\u00fcr Naturforschung A","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2320190455.pdf","grobid_xml":"https://content.openalex.org/works/W2320190455.grobid-xml"},"referenced_works_count":1,"referenced_works":["https://openalex.org/W4210318935"],"related_works":["https://openalex.org/W7026774854","https://openalex.org/W7145244745","https://openalex.org/W1969310113","https://openalex.org/W2315287938","https://openalex.org/W2771915853","https://openalex.org/W2066761911","https://openalex.org/W2046696153","https://openalex.org/W2082720383","https://openalex.org/W2061079683","https://openalex.org/W2073231043"],"abstract_inverted_index":{"The":[0],"infrared":[1],"spectra":[2],"of":[3,40,99,108,113,124],"CH3CH2COONa":[4],"and":[5,11,28,64],"its":[6],"13C-labeled":[7],"modifications":[8],"(1-13C,":[9],"2-13C,":[10],"3-13C)":[12],"suspended":[13],"in":[14,19,37,47,88],"KBr":[15],"disks":[16],"were":[17,94,127],"measured":[18],"the":[20,41,48,59,79,89,100,106,109,114,125],"region":[21,49,92],"4000":[22],"-200":[23],"cm-1":[24],"at":[25,78],"room":[26,42],"temperature":[27,43],"liquid":[29],"nitrogen":[30],"temperature.":[31],"Overlapping":[32],"complex":[33],"band":[34],"contours":[35],"appeared":[36],"some":[38],"regions":[39],"spectrum,":[44],"most":[45],"notably":[46],"1500":[50],"-1350":[51],"cm-1,":[52],"where":[53],"5":[54],"fundamentals":[55,86,101,126],"having":[56,133],"contributions":[57,134],"from":[58,82,135],"methyl":[60],"deformation,":[61],"methylene":[62],"bending,":[63],"carboxylate":[65],"stretching":[66],"modes":[67,132],"should":[68],"occur.":[69],"In":[70],"contrast":[71],"to":[72,129],"this,":[73],"excellent":[74],"resolution":[75],"was":[76],"reached":[77],"low":[80],"temperature,":[81],"which":[83],"all":[84],"22":[85],"expected":[87],"whole":[90],"spectral":[91],"investigated":[93],"detected.":[95],"A":[96,121],"complete":[97],"assignment":[98],"is":[102],"proposed":[103],"mainly":[104],"on":[105],"basis":[107],"characteristic":[110],"isotopic":[111],"shifts":[112],"three":[115],"13C":[116],"substituted":[117],"sodium":[118],"propionate":[119],"species.":[120],"fair":[122],"number":[123],"found":[128],"feature":[130],"coupled":[131],"several":[136],"group":[137],"vibrations.":[138]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":3}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}