{"id":"https://openalex.org/W2319502575","doi":"https://doi.org/10.1021/jp206224k","title":"Synthesis and Phase Transitional Behavior of Dimer-like Optically Active Liquid Crystals","display_name":"Synthesis and Phase Transitional Behavior of Dimer-like Optically Active Liquid Crystals","publication_year":2011,"publication_date":"2011-08-10","ids":{"openalex":"https://openalex.org/W2319502575","doi":"https://doi.org/10.1021/jp206224k","mag":"2319502575","pmid":"https://pubmed.ncbi.nlm.nih.gov/21830781"},"language":"en","primary_location":{"id":"doi:10.1021/jp206224k","doi":"https://doi.org/10.1021/jp206224k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp206224k","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5054339294","display_name":"Govindaswamy Shanker","orcid":"https://orcid.org/0000-0003-1294-7149","observed_orcids":["https://orcid.org/0000-0003-1294-7149"]},"institutions":[{"id":"https://openalex.org/I4210115714","display_name":"Centre for Nano and Soft Matter Sciences","ror":"https://ror.org/02n8rnw93","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210098748","https://openalex.org/I4210115714","https://openalex.org/I4210134808"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Govindaswamy Shanker","raw_affiliation_strings":["Centre for Soft Matter Research, Prof. U. R. Rao Road, P. B. No. 1329, Jalahalli, Bangalore 560 013, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Soft Matter Research, Prof. U. R. Rao Road, P. B. No. 1329, Jalahalli, Bangalore 560 013, India","institution_ids":["https://openalex.org/I4210115714"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5033697487","display_name":"Channabasaveshwar Veerappa Yelamaggad","orcid":"https://orcid.org/0000-0003-3098-8358","observed_orcids":["https://orcid.org/0000-0003-3098-8358"]},"institutions":[{"id":"https://openalex.org/I4210115714","display_name":"Centre for Nano and Soft Matter Sciences","ror":"https://ror.org/02n8rnw93","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210098748","https://openalex.org/I4210115714","https://openalex.org/I4210134808"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Channabasaveshwar V. Yelamaggad","raw_affiliation_strings":["Centre for Soft Matter Research, Prof. U. R. Rao Road, P. B. No. 1329, Jalahalli, Bangalore 560 013, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Soft Matter Research, Prof. U. R. Rao Road, P. B. No. 1329, Jalahalli, Bangalore 560 013, India","institution_ids":["https://openalex.org/I4210115714"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5033697487"],"corresponding_institution_ids":["https://openalex.org/I4210115714"],"apc_list":null,"apc_paid":null,"fwci":0.8704,"has_fulltext":false,"cited_by_count":38,"citation_normalized_percentile":{"value":0.69420015,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"115","issue":"37","first_page":"10849","last_page":"10859"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11025","display_name":"Nonlinear Optical Materials Research","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11298","display_name":"Synthesis and Properties of Aromatic Compounds","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cholesterol","display_name":"cholesterol","score":0.39500001072883606},{"id":"https://openalex.org/keywords/salicylaldimine","display_name":"salicylaldimine","score":0.9900000095367432},{"id":"https://openalex.org/keywords/phase-transitions","display_name":"phase transitions","score":0.578000009059906},{"id":"https://openalex.org/keywords/chiral-nematic-phase","display_name":"chiral nematic phase","score":0.8629999756813049},{"id":"https://openalex.org/keywords/twist-grain-boundary-phase","display_name":"twist grain boundary phase","score":0.8180000185966492},{"id":"https://openalex.org/keywords/chiral-smectic-a-phase","display_name":"chiral smectic A phase","score":0.9340000152587891},{"id":"https://openalex.org/keywords/chiral-smectic-c-phase","display_name":"chiral smectic C phase","score":0.9070000052452087},{"id":"https://openalex.org/keywords/odd-even-effect","display_name":"odd-even effect","score":0.7879999876022339},{"id":"https://openalex.org/keywords/clearing-temperature","display_name":"clearing temperature","score":0.9049999713897705},{"id":"https://openalex.org/keywords/structure-property-relationships","display_name":"structure-property relationships","score":0.675000011920929},{"id":"https://openalex.org/keywords/electrochemical-switching","display_name":"electrochemical switching","score":0.6269999742507935},{"id":"https://openalex.org/keywords/gelation","display_name":"gelation","score":0.9419999718666077}],"concepts":[{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.7134115099906921},{"id":"https://openalex.org/C178017875","wikidata":"https://www.wikidata.org/wiki/Q10328910","display_name":"Mesogen","level":4,"score":0.7065231204032898},{"id":"https://openalex.org/C13274807","wikidata":"https://www.wikidata.org/wiki/Q203989","display_name":"Liquid crystal","level":2,"score":0.6973408460617065},{"id":"https://openalex.org/C2776482079","wikidata":"https://www.wikidata.org/wiki/Q741844","display_name":"Homologous series","level":2,"score":0.691822350025177},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6268418431282043},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5757673978805542},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.5666043162345886},{"id":"https://openalex.org/C79090758","wikidata":"https://www.wikidata.org/wiki/Q1045739","display_name":"Ferroelectricity","level":3,"score":0.5607821941375732},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.4846971035003662},{"id":"https://openalex.org/C2777151079","wikidata":"https://www.wikidata.org/wiki/Q141160","display_name":"Parity (physics)","level":2,"score":0.46562546491622925},{"id":"https://openalex.org/C196503311","wikidata":"https://www.wikidata.org/wiki/Q145623","display_name":"Molar mass","level":3,"score":0.43004122376441956},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.25694671273231506},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.21732065081596375},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1540166735649109},{"id":"https://openalex.org/C2994273327","wikidata":"https://www.wikidata.org/wiki/Q203989","display_name":"Liquid crystalline","level":3,"score":0.09301638603210449},{"id":"https://openalex.org/C133386390","wikidata":"https://www.wikidata.org/wiki/Q184996","display_name":"Dielectric","level":2,"score":0.07907643914222717},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C109214941","wikidata":"https://www.wikidata.org/wiki/Q18334","display_name":"Particle physics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/jp206224k","doi":"https://doi.org/10.1021/jp206224k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp206224k","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},{"id":"pmid:21830781","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/21830781","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. B","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":56,"referenced_works":["https://openalex.org/W580227274","https://openalex.org/W599159858","https://openalex.org/W1891994603","https://openalex.org/W1963292121","https://openalex.org/W1970924778","https://openalex.org/W1971940966","https://openalex.org/W1974148594","https://openalex.org/W1976275344","https://openalex.org/W1979592939","https://openalex.org/W1979737660","https://openalex.org/W1985516228","https://openalex.org/W1986146687","https://openalex.org/W1994174641","https://openalex.org/W2002363341","https://openalex.org/W2007533646","https://openalex.org/W2010079052","https://openalex.org/W2011139853","https://openalex.org/W2012398561","https://openalex.org/W2013956508","https://openalex.org/W2017395463","https://openalex.org/W2022142780","https://openalex.org/W2025787767","https://openalex.org/W2027972748","https://openalex.org/W2029161848","https://openalex.org/W2034050127","https://openalex.org/W2039394062","https://openalex.org/W2044978245","https://openalex.org/W2047228394","https://openalex.org/W2048400654","https://openalex.org/W2050367796","https://openalex.org/W2053791627","https://openalex.org/W2061314963","https://openalex.org/W2064861328","https://openalex.org/W2069294440","https://openalex.org/W2069709862","https://openalex.org/W2071114671","https://openalex.org/W2081958041","https://openalex.org/W2083383837","https://openalex.org/W2088565143","https://openalex.org/W2089066050","https://openalex.org/W2093900624","https://openalex.org/W2094262736","https://openalex.org/W2099645781","https://openalex.org/W2116490145","https://openalex.org/W2129268511","https://openalex.org/W2142488832","https://openalex.org/W2146444425","https://openalex.org/W2160670341","https://openalex.org/W2161158952","https://openalex.org/W2197099669","https://openalex.org/W2333988885","https://openalex.org/W2478399003","https://openalex.org/W2551057181","https://openalex.org/W2911885276","https://openalex.org/W4236581529","https://openalex.org/W4248768009"],"related_works":["https://openalex.org/W2168388436","https://openalex.org/W2125053486","https://openalex.org/W2083383837","https://openalex.org/W2107046742","https://openalex.org/W1988511879","https://openalex.org/W2059778394","https://openalex.org/W2001529171","https://openalex.org/W2010379678","https://openalex.org/W1978413789","https://openalex.org/W2782468119"],"abstract_inverted_index":{"The":[0,64,158,206],"results":[1],"of":[2,12,22,45,71,91,101,162,169,193,202,233,245],"our":[3,238],"detailed":[4],"studies":[5],"pertaining":[6],"to":[7,36,107,114,222,231,252],"a":[8,37,42,130,186],"relatively":[9],"new":[10,243],"class":[11,244],"low":[13,246],"molar":[14,247],"mass":[15,248],"mesogens":[16],"are":[17,140],"presented.":[18],"Four":[19],"homologous":[20],"series":[21,225],"optically":[23],"active":[24],"dimer-like":[25,219],"mesogens,":[26],"comprising":[27],"cholesterol":[28],"as":[29,197,199],"the":[30,68,89,92,99,102,118,137,163,170,182,189,194,200,203,214,217],"conventional":[31],"pro-mesogenic":[32],"core":[33,110],"covalently":[34],"tethered":[35],"nonmesogenic":[38,108],"salicylaldimine":[39,109],"segment":[40],"through":[41],"flexible":[43],"spacer":[44,94,196],"varying":[46],"length":[47,90,100,190,201],"and":[48,53,61,82,123,152,166,191,258],"parity,":[49],"have":[50,173,261],"been":[51,75,112,174,210,262],"synthesized":[52],"evaluated":[54],"for":[55,176,264],"their":[56],"thermal,":[57],"electrical":[58,83],"switching,":[59],"electrochemical,":[60],"gelation":[62,259],"properties.":[63,126],"thermal":[65],"behavior,":[66],"being":[67],"prime":[69],"focus":[70],"this":[72],"study,":[73],"has":[74,111,209],"characterized":[76],"by":[77],"optical,":[78],"calorimetric,":[79],"X-ray":[80],"diffraction,":[81],"switching":[84],"studies.":[85],"In":[86,180],"each":[87],"series,":[88],"even/odd-parity":[93],"is":[95],"held":[96],"constant,":[97],"while":[98],"terminal":[103,204],"N-alkyl":[104],"tail":[105],"attached":[106],"varied":[113],"gain":[115],"insight":[116],"into":[117],"fundamental":[119],"correlation":[120],"between":[121],"structure":[122],"phase":[124,165,172,183],"transitional":[125],"These":[127],"compounds,":[128],"with":[129],"few":[131],"exceptions,":[132],"exhibit":[133,226],"liquid":[134,253],"crystal":[135,254],"phase(s);":[136],"identified":[138],"phases":[139],"chiral":[141,148,153],"nematic":[142],"(N*),":[143],"twist":[144],"grain":[145],"boundary":[146],"(TGB),":[147],"smectic":[149,154],"A":[150],"(SmA),":[151],"C":[155],"(SmC*)":[156],"phases.":[157],"selective":[159],"reflection":[160],"property":[161],"N*":[164],"ferroelectric":[167],"behavior":[168,184,257],"SmC*":[171],"ascertained":[175],"some":[177,265],"selected":[178,266],"members.":[179],"general,":[181],"shows":[185],"dependence":[187],"on":[188],"parity":[192],"central":[195],"well":[198],"tail.":[205],"odd-even":[207],"effect":[208],"prominently":[211],"found":[212],"in":[213],"clearing":[215],"temperatures;":[216],"even-parity":[218],"compounds":[220],"belonging":[221],"three":[223],"different":[224],"higher":[227],"values":[228],"when":[229],"compared":[230],"members":[232],"an":[234],"odd-parity":[235],"series.":[236],"Thus,":[237],"study":[239],"demonstrates":[240],"that":[241],"these":[242],"materials":[249],"behave":[250],"analogous":[251],"dimers.":[255],"Electrochemical":[256],"ability":[260],"demonstrated":[263],"materials.":[267]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":3}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}