{"id":"https://openalex.org/W2318123791","doi":"https://doi.org/10.1021/ic401421h","title":"Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand","display_name":"Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand","publication_year":2013,"publication_date":"2013-09-24","ids":{"openalex":"https://openalex.org/W2318123791","doi":"https://doi.org/10.1021/ic401421h","mag":"2318123791","pmid":"https://pubmed.ncbi.nlm.nih.gov/24063409"},"language":"en","primary_location":{"id":"doi:10.1021/ic401421h","doi":"https://doi.org/10.1021/ic401421h","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic401421h","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2318123791"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5074550545","display_name":"Feng Gao","orcid":"https://orcid.org/0000-0003-3020-8489","observed_orcids":["https://orcid.org/0000-0003-3020-8489"]},"institutions":[{"id":"https://openalex.org/I881766915","display_name":"Nanjing University","ror":"https://ror.org/01rxvg760","country_code":"CN","type":"education","lineage":["https://openalex.org/I881766915"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Feng Gao","raw_affiliation_strings":["State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China","institution_ids":["https://openalex.org/I881766915"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032611465","display_name":"Long Cui","orcid":"https://orcid.org/0000-0002-1917-2254","observed_orcids":["https://orcid.org/0000-0002-1917-2254"]},"institutions":[{"id":"https://openalex.org/I881766915","display_name":"Nanjing University","ror":"https://ror.org/01rxvg760","country_code":"CN","type":"education","lineage":["https://openalex.org/I881766915"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Long Cui","raw_affiliation_strings":["State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China","institution_ids":["https://openalex.org/I881766915"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100431971","display_name":"Wei Liu","orcid":"https://orcid.org/0000-0003-2940-7755","observed_orcids":["https://orcid.org/0000-0003-2940-7755","https://orcid.org/0000-0002-1207-204X"]},"institutions":[{"id":"https://openalex.org/I3923682","display_name":"Soochow University","ror":"https://ror.org/05t8y2r12","country_code":"CN","type":"education","lineage":["https://openalex.org/I3923682"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Wei Liu","raw_affiliation_strings":["College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren'ai Road, Suzhou 215006, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren'ai Road, Suzhou 215006, People\u2019s Republic of China","institution_ids":["https://openalex.org/I3923682"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009521293","display_name":"Liang Hu","orcid":"https://orcid.org/0000-0002-2960-9560","observed_orcids":["https://orcid.org/0000-0002-2960-9560"]},"institutions":[{"id":"https://openalex.org/I881766915","display_name":"Nanjing University","ror":"https://ror.org/01rxvg760","country_code":"CN","type":"education","lineage":["https://openalex.org/I881766915"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Liang Hu","raw_affiliation_strings":["State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China","institution_ids":["https://openalex.org/I881766915"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5026343813","display_name":"Yu\u2010Wu Zhong","orcid":"https://orcid.org/0000-0003-0712-0374","observed_orcids":["https://orcid.org/0000-0003-0712-0374"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yu-Wu Zhong","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of\rChemistry, Chinese Academy of Sciences, North First Street 2, Beijing 100190, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of\rChemistry, Chinese Academy of Sciences, North First Street 2, Beijing 100190, People\u2019s Republic of China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023694591","display_name":"Yizhi Li","orcid":"https://orcid.org/0009-0000-1692-5778","observed_orcids":["https://orcid.org/0009-0000-1692-5778"]},"institutions":[{"id":"https://openalex.org/I881766915","display_name":"Nanjing University","ror":"https://ror.org/01rxvg760","country_code":"CN","type":"education","lineage":["https://openalex.org/I881766915"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yi-Zhi Li","raw_affiliation_strings":["State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China","institution_ids":["https://openalex.org/I881766915"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057154243","display_name":"Jing\u2010Lin Zuo","orcid":"https://orcid.org/0000-0003-1219-8926","observed_orcids":["https://orcid.org/0000-0003-1219-8926"]},"institutions":[{"id":"https://openalex.org/I881766915","display_name":"Nanjing University","ror":"https://ror.org/01rxvg760","country_code":"CN","type":"education","lineage":["https://openalex.org/I881766915"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jing-Lin Zuo","raw_affiliation_strings":["State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key\rLaboratory of Coordination Chemistry, School of Chemistry and Chemical\rEngineering, Nanjing National Laboratory of Microstructures, Nanjing University, Hankou Road 9, Nanjing 210093, People\u2019s Republic of China","institution_ids":["https://openalex.org/I881766915"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5057154243"],"corresponding_institution_ids":["https://openalex.org/I881766915"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.0517,"has_fulltext":false,"cited_by_count":58,"citation_normalized_percentile":{"value":0.94923056,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"52","issue":"19","first_page":"11164","last_page":"11172"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.7026000022888184,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.7026000022888184,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11279","display_name":"Lanthanide and Transition Metal Complexes","score":0.24390000104904175,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.014499999582767487,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sandwich-complexes","display_name":"sandwich complexes","score":0.8679999709129333},{"id":"https://openalex.org/keywords/tetrathiafulvalene","display_name":"tetrathiafulvalene","score":0.9599999785423279},{"id":"https://openalex.org/keywords/lanthanide-iii-complexes","display_name":"lanthanide(III) complexes","score":0.703000009059906},{"id":"https://openalex.org/keywords/dysprosium-complexes","display_name":"dysprosium complexes","score":0.843999981880188},{"id":"https://openalex.org/keywords/terbium-complexes","display_name":"terbium complexes","score":0.9919999837875366},{"id":"https://openalex.org/keywords/holmium-complexes","display_name":"holmium complexes","score":1.0},{"id":"https://openalex.org/keywords/slow-magnetic-relaxation","display_name":"slow magnetic relaxation","score":0.8370000123977661},{"id":"https://openalex.org/keywords/single-molecule-magnets","display_name":"single-molecule magnets","score":0.8379999995231628},{"id":"https://openalex.org/keywords/spectroelectrochemistry","display_name":"spectroelectrochemistry","score":0.7879999876022339},{"id":"https://openalex.org/keywords/redox-active-ligands","display_name":"redox-active ligands","score":0.7509999871253967},{"id":"https://openalex.org/keywords/organic-inorganic-hybrid-materials","display_name":"organic-inorganic hybrid materials","score":0.7929999828338623},{"id":"https://openalex.org/keywords/tripodal-ligands","display_name":"tripodal ligands","score":0.6710000038146973}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9641184210777283},{"id":"https://openalex.org/C2776428424","wikidata":"https://www.wikidata.org/wiki/Q2602701","display_name":"Schiff base","level":2,"score":0.8509090542793274},{"id":"https://openalex.org/C201770740","wikidata":"https://www.wikidata.org/wiki/Q19569","display_name":"Lanthanide","level":3,"score":0.7994276285171509},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6875826716423035},{"id":"https://openalex.org/C2778421084","wikidata":"https://www.wikidata.org/wiki/Q2179180","display_name":"Tetrathiafulvalene","level":3,"score":0.642865002155304},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3742976486682892},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.16379818320274353},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14731746912002563},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.10215684771537781},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.04635506868362427},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic401421h","doi":"https://doi.org/10.1021/ic401421h","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic401421h","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:24063409","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24063409","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":86,"referenced_works":["https://openalex.org/W943037454","https://openalex.org/W1823409394","https://openalex.org/W1970881901","https://openalex.org/W1972021141","https://openalex.org/W1973141298","https://openalex.org/W1975798060","https://openalex.org/W1976032581","https://openalex.org/W1978071160","https://openalex.org/W1978239898","https://openalex.org/W1981366834","https://openalex.org/W1981815412","https://openalex.org/W1982201073","https://openalex.org/W1983466095","https://openalex.org/W1984614201","https://openalex.org/W1984749699","https://openalex.org/W1987463119","https://openalex.org/W1997218399","https://openalex.org/W1997287556","https://openalex.org/W1997436070","https://openalex.org/W1997599212","https://openalex.org/W2003608478","https://openalex.org/W2003618810","https://openalex.org/W2004905941","https://openalex.org/W2011546133","https://openalex.org/W2017329762","https://openalex.org/W2021301774","https://openalex.org/W2022730250","https://openalex.org/W2023271753","https://openalex.org/W2025508459","https://openalex.org/W2026039351","https://openalex.org/W2028527009","https://openalex.org/W2030181768","https://openalex.org/W2034706873","https://openalex.org/W2038840998","https://openalex.org/W2039435476","https://openalex.org/W2042933518","https://openalex.org/W2043177224","https://openalex.org/W2043368447","https://openalex.org/W2047293663","https://openalex.org/W2054125484","https://openalex.org/W2056059080","https://openalex.org/W2057642180","https://openalex.org/W2058583883","https://openalex.org/W2060300161","https://openalex.org/W2066969355","https://openalex.org/W2070150426","https://openalex.org/W2072289345","https://openalex.org/W2073833971","https://openalex.org/W2075010462","https://openalex.org/W2076288658","https://openalex.org/W2076874507","https://openalex.org/W2077479030","https://openalex.org/W2081347532","https://openalex.org/W2083494937","https://openalex.org/W2088012940","https://openalex.org/W2089740902","https://openalex.org/W2092014254","https://openalex.org/W2093986406","https://openalex.org/W2095424002","https://openalex.org/W2095706164","https://openalex.org/W2101614125","https://openalex.org/W2108101881","https://openalex.org/W2109477907","https://openalex.org/W2116195309","https://openalex.org/W2125622961","https://openalex.org/W2126398015","https://openalex.org/W2131705949","https://openalex.org/W2135728817","https://openalex.org/W2136474078","https://openalex.org/W2137179183","https://openalex.org/W2143402290","https://openalex.org/W2143981217","https://openalex.org/W2145776938","https://openalex.org/W2146099614","https://openalex.org/W2148064030","https://openalex.org/W2153799385","https://openalex.org/W2168167113","https://openalex.org/W2315614157","https://openalex.org/W2315704004","https://openalex.org/W2324955067","https://openalex.org/W2326241143","https://openalex.org/W2328099927","https://openalex.org/W2329192006","https://openalex.org/W2334684877","https://openalex.org/W2335189680","https://openalex.org/W2395518647"],"related_works":["https://openalex.org/W2324955067","https://openalex.org/W2303202273","https://openalex.org/W2883062482","https://openalex.org/W4299818820","https://openalex.org/W2077479030","https://openalex.org/W2991418314","https://openalex.org/W1856958538","https://openalex.org/W3098704485","https://openalex.org/W2018593066","https://openalex.org/W2395957639"],"abstract_inverted_index":{"Three":[0],"seven-coordinate":[1],"lanthanide(III)":[2,87],"sandwich-type":[3,86],"mononuclear":[4],"complexes":[5,41,88],"with":[6,64,89],"\u03c0-conjugated":[7],"TTF-Schiff":[8],"base":[9],"ligand":[10,18],"H2L":[11],"(L(2-)":[12],"=":[13,21,25],"2,2'-((2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-1,3-benzodithiole-5,6-diyl)bis(nitrilomethylidyne)bis(4-chlorophenolate))":[14],"and":[15,35,48,51],"the":[16,40,58,80,85],"tripodal":[17],"L(OEt)(-)":[19],"(L(OEt)(-)":[20],"[(\u03b7(5)-C5H5)Co(P(\u2550O)(OEt)2)3](-)),":[22],"[(L(OEt))Ln(L)]\u00b70.25H2O":[23],"(Ln(3+)":[24],"Dy(3+),":[26],"1;":[27],"Tb(3+),":[28],"2;":[29],"Ho(3+),":[30],"3),":[31],"have":[32],"been":[33],"synthesized":[34],"structurally":[36],"characterized.":[37],"All":[38],"of":[39,62,68,79,98],"are":[42],"also":[43],"characterized":[44],"by":[45],"absorption":[46],"spectra":[47],"electrochemical,":[49],"spectroelectrochemical,":[50],"magnetic":[52,91],"studies.":[53],"The":[54],"Dy":[55],"complex":[56],"exhibits":[57],"field-induced":[59],"slow":[60],"relaxation":[61],"magnetization":[63],"an":[65],"energy":[66],"barrier":[67],"41.6":[69],"K,":[70],"indicating":[71],"it":[72],"shows":[73],"single":[74],"lanthanide-based":[75],"SMM":[76],"behavior.":[77],"Introduction":[78],"redox-active":[81],"TTF":[82],"unit":[83],"into":[84],"interesting":[90],"properties":[92],"renders":[93],"them":[94],"promising":[95],"for":[96],"elaboration":[97],"new":[99],"hybrid":[100],"inorganic-organic":[101],"materials.":[102]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":12},{"year":2015,"cited_by_count":12},{"year":2014,"cited_by_count":10},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}