{"id":"https://openalex.org/W2317769887","doi":"https://doi.org/10.5254/1.3539320","title":"Acetylene Polymers and Their Derivatives. II. A New Synthetic Rubber: Chloroprene and Its Polymers","display_name":"Acetylene Polymers and Their Derivatives. II. A New Synthetic Rubber: Chloroprene and Its Polymers","publication_year":1932,"publication_date":"1932-03-01","ids":{"openalex":"https://openalex.org/W2317769887","doi":"https://doi.org/10.5254/1.3539320","mag":"2317769887"},"language":"en","primary_location":{"id":"doi:10.5254/1.3539320","doi":"https://doi.org/10.5254/1.3539320","is_oa":false,"landing_page_url":"https://doi.org/10.5254/1.3539320","pdf_url":null,"source":{"id":"https://openalex.org/S133775183","display_name":"Rubber Chemistry and Technology","issn_l":"0035-9475","issn":["0035-9475","1943-4804"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Rubber Chemistry and Technology","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5027451009","display_name":"Wallace H. Carothers","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Wallace H. Carothers","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049735864","display_name":"Ira Williams","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ira Williams","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011266750","display_name":"Arnold M. Collins","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Arnold M. Collins","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5068686345","display_name":"James E. Kirby","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"James E. Kirby","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.40721649,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"5","issue":"1","first_page":"7","last_page":"29"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.9262999892234802,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.9262999892234802,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14454","display_name":"Polymer Science and Applications","score":0.052000001072883606,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.009800000116229057,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chloroprene","display_name":"chloroprene","score":0.9890000224113464},{"id":"https://openalex.org/keywords/chloroprene-rubber","display_name":"neoprene","score":0.8989999890327454},{"id":"https://openalex.org/keywords/synthetic-rubber","display_name":"synthetic rubber","score":0.9789999723434448},{"id":"https://openalex.org/keywords/polymerization","display_name":"polymerization","score":0.5220000147819519},{"id":"https://openalex.org/keywords/emulsion-polymerization","display_name":"emulsion polymerization","score":0.7699999809265137},{"id":"https://openalex.org/keywords/polymer-structure","display_name":"polymer structure","score":0.6079999804496765},{"id":"https://openalex.org/keywords/polymer-morphology","display_name":"polymer morphology","score":0.3230000138282776},{"id":"https://openalex.org/keywords/gas-permeability","display_name":"gas permeability","score":0.5809999704360962},{"id":"https://openalex.org/keywords/chemical-resistance","display_name":"chemical resistance","score":0.8410000205039978}],"concepts":[{"id":"https://openalex.org/C2776264970","wikidata":"https://www.wikidata.org/wiki/Q410871","display_name":"Chloroprene","level":3,"score":0.9930196404457092},{"id":"https://openalex.org/C176933379","wikidata":"https://www.wikidata.org/wiki/Q131877","display_name":"Natural rubber","level":2,"score":0.8150913715362549},{"id":"https://openalex.org/C51179264","wikidata":"https://www.wikidata.org/wiki/Q188631","display_name":"Vulcanization","level":3,"score":0.777786135673523},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.7263579368591309},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6848437190055847},{"id":"https://openalex.org/C45014336","wikidata":"https://www.wikidata.org/wiki/Q6714735","display_name":"Synthetic rubber","level":3,"score":0.5947917103767395},{"id":"https://openalex.org/C27618995","wikidata":"https://www.wikidata.org/wiki/Q143937","display_name":"Neoprene","level":3,"score":0.5822713971138},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5248356461524963},{"id":"https://openalex.org/C2780959689","wikidata":"https://www.wikidata.org/wiki/Q271943","display_name":"Isoprene","level":4,"score":0.4814578890800476},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.4490273594856262},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.39494845271110535},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.3927803039550781},{"id":"https://openalex.org/C126348684","wikidata":"https://www.wikidata.org/wiki/Q3456979","display_name":"Polymer science","level":1,"score":0.3824693560600281},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.21850958466529846},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.5254/1.3539320","doi":"https://doi.org/10.5254/1.3539320","is_oa":false,"landing_page_url":"https://doi.org/10.5254/1.3539320","pdf_url":null,"source":{"id":"https://openalex.org/S133775183","display_name":"Rubber Chemistry and Technology","issn_l":"0035-9475","issn":["0035-9475","1943-4804"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Rubber Chemistry and Technology","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2322785206","https://openalex.org/W2289540485","https://openalex.org/W2317140615","https://openalex.org/W4252447417","https://openalex.org/W157370795","https://openalex.org/W2328940279","https://openalex.org/W2596086259","https://openalex.org/W4248835514","https://openalex.org/W147677515","https://openalex.org/W2328568180"],"abstract_inverted_index":{"Abstract":[0],"Chloro-2-butadiene-1,3":[1],"(chloroprene)":[2],"is":[3,52,139,216,240],"described":[4,92,126],"and":[5,19,100,179,233,253],"its":[6,13,141],"structure":[7],"established":[8],"through":[9],"reactions":[10],"leading":[11],"to":[12,63,85,221,236,244],"conversion":[14],"into":[15,20,39,153],"butane-\u03b1,":[16],"\u03b2,\u03b3,\u03b4-tetracarboxylic":[17],"acid,":[18],"\u03b2-chloroanthraquinone.":[21],"Within":[22],"ten":[23],"days":[24],"under":[25],"ordinary":[26],"conditions":[27,116],"in":[28,133,158,191],"a":[29,33,40,67,146,165,171],"closed":[30],"vessel":[31],"containing":[32],"little":[34],"air,":[35],"chloroprene":[36,91,152],"spontaneously":[37],"changes":[38,84],"transparent,":[41],"resilient,":[42],"strong,":[43],"non-plastic,":[44],"elastic":[45],"mass":[46],"resembling":[47],"vulcanized":[48],"rubber.":[49,75,207],"This":[50],"product":[51,70,163],"called":[53],"\u03bc-polychloroprene.":[54],"By":[55],"interrupting":[56],"the":[57,77,81,86,106,113,118,134,192,212],"polymerization":[58],"before":[59],"it":[60,138,180],"has":[61,170],"proceeded":[62],"completion":[64],"one":[65],"obtains":[66],"soft,":[68],"plastic":[69],"(\u03b1-polymer)":[71],"that":[72,136],"resembles":[73,130],"unvulcanized":[74],"Under":[76],"action":[78],"of":[79,90,105,115,120,151,194],"heat":[80],"\u03b1-polymer":[82],"rapidly":[83,157],"\u03bc-polymer.":[87],"Other":[88],"polymers":[89,107],"are":[93,108],"volatile":[94],"(\u03b2-)":[95],"polymer,":[96,99],"granular":[97],"(\u03c9-)":[98],"balata-like":[101],"polymer.":[102],"The":[103,149,161,199],"structures":[104],"discussed":[109],"as":[110,112],"well":[111],"effect":[114],"on":[117],"formation":[119],"each":[121],"type.":[122],"Unlike":[123],"any":[124],"previously":[125],"synthetic":[127,166,206,214],"rubbers,":[128],"\u03bc-polychloroprene":[129,154],"natural":[131,177,210],"rubber":[132,211,215],"fact":[135],"when":[137],"stretched":[140],"x-ray":[142],"diffraction":[143],"pattern":[144],"shows":[145],"point":[147],"diagram.":[148],"transformation":[150],"occurs":[155],"very":[156],"aqueous":[159],"emulsion.":[160],"resulting":[162],"constitutes":[164],"(vulcanized)":[167],"latex.":[168],"It":[169,239],"much":[172,241],"smaller":[173],"particle":[174],"size":[175],"than":[176],"latex":[178],"penetrates":[181],"porous":[182,195],"materials":[183,200],"more":[184,217,219,242],"readily.":[185],"Chloroprene":[186],"can":[187],"also":[188],"be":[189],"polymerized":[190],"pores":[193],"or":[196,223],"bibulous":[197],"materials.":[198],"thus":[201],"become":[202],"intimately":[203],"impregnated":[204],"with":[205,209],"Compared":[208],"new":[213],"dense,":[218],"resistant":[220,243],"absorption":[222],"penetration":[224],"by":[225,230,246],"water,":[226],"less":[227,234],"strongly":[228],"swelled":[229],"petroleum":[231],"hydrocarbons":[232],"permeable":[235],"many":[237,254],"gases.":[238],"attack":[245],"oxygen,":[247],"ozone,":[248],"hydrogen":[249,251],"chloride,":[250],"fluoride":[252],"other":[255],"chemicals.":[256]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-05-21T06:26:12.895304","created_date":"2016-06-24T00:00:00"}