{"id":"https://openalex.org/W2314535687","doi":"https://doi.org/10.1021/ja3093532","title":"Anomalous Reactivity of Ceric Nitrate in Ruthenium \u201cBlue Dimer\u201d-Catalyzed Water Oxidation","display_name":"Anomalous Reactivity of Ceric Nitrate in Ruthenium \u201cBlue Dimer\u201d-Catalyzed Water Oxidation","publication_year":2012,"publication_date":"2012-11-26","ids":{"openalex":"https://openalex.org/W2314535687","doi":"https://doi.org/10.1021/ja3093532","mag":"2314535687","pmid":"https://pubmed.ncbi.nlm.nih.gov/23181743"},"language":"en","primary_location":{"id":"doi:10.1021/ja3093532","doi":"https://doi.org/10.1021/ja3093532","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja3093532","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5019706721","display_name":"Jamie A. Stull","orcid":"https://orcid.org/0000-0002-0464-7456","observed_orcids":["https://orcid.org/0000-0002-0464-7456"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jamie A. Stull","raw_affiliation_strings":["Department of Chemistry, University of California\u2014Davis, Davis, California\r95616, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California\u2014Davis, Davis, California\r95616, United States","institution_ids":["https://openalex.org/I84218800"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5086254191","display_name":"R. David Britt","orcid":"https://orcid.org/0000-0003-0889-8436","observed_orcids":["https://orcid.org/0000-0003-0889-8436"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"R. David Britt","raw_affiliation_strings":["Department of Chemistry, University of California\u2014Davis, Davis, California\r95616, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California\u2014Davis, Davis, California\r95616, United States","institution_ids":["https://openalex.org/I84218800"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069229387","display_name":"Jeanne Louise McHale","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I72951846","display_name":"Washington State University","ror":"https://ror.org/05dk0ce17","country_code":"US","type":"education","lineage":["https://openalex.org/I72951846"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jeanne L. McHale","raw_affiliation_strings":["Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States","institution_ids":["https://openalex.org/I72951846"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025912582","display_name":"Fritz J. Knorr","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I72951846","display_name":"Washington State University","ror":"https://ror.org/05dk0ce17","country_code":"US","type":"education","lineage":["https://openalex.org/I72951846"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Fritz J. Knorr","raw_affiliation_strings":["Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States","institution_ids":["https://openalex.org/I72951846"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040977195","display_name":"Sergei V. Lymar","orcid":"https://orcid.org/0000-0003-2663-6157","observed_orcids":["https://orcid.org/0000-0003-2663-6157"]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sergei V. Lymar","raw_affiliation_strings":["Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973,\rUnited States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973,\rUnited States","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054375658","display_name":"James K. Hurst","orcid":"https://orcid.org/0000-0003-1070-2690","observed_orcids":["https://orcid.org/0000-0003-1070-2690"]},"institutions":[{"id":"https://openalex.org/I72951846","display_name":"Washington State University","ror":"https://ror.org/05dk0ce17","country_code":"US","type":"education","lineage":["https://openalex.org/I72951846"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"James K. Hurst","raw_affiliation_strings":["Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Washington State University, Pullman, Washington 99164,\rUnited States","institution_ids":["https://openalex.org/I72951846"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5054375658"],"corresponding_institution_ids":["https://openalex.org/I72951846"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.4112,"has_fulltext":false,"cited_by_count":34,"citation_normalized_percentile":{"value":0.88283884,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"134","issue":"49","first_page":"19973","last_page":"19976"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.826200008392334,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.826200008392334,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.03290000185370445,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.030500000342726707,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/water-oxidation","display_name":"water oxidation","score":0.9049999713897705},{"id":"https://openalex.org/keywords/oxygen-evolution-reaction","display_name":"oxygen evolution reaction","score":0.5249999761581421},{"id":"https://openalex.org/keywords/reaction-intermediates","display_name":"reaction intermediates","score":0.6169999837875366},{"id":"https://openalex.org/keywords/resonance-raman-spectroscopy","display_name":"resonance Raman spectroscopy","score":0.8379999995231628},{"id":"https://openalex.org/keywords/oxygen-isotope-effect","display_name":"oxygen isotope effect","score":0.8029999732971191},{"id":"https://openalex.org/keywords/18o-labeling","display_name":"18O labeling","score":0.699999988079071},{"id":"https://openalex.org/keywords/15n-labeling","display_name":"15N labeling","score":0.9959999918937683},{"id":"https://openalex.org/keywords/peroxo-species","display_name":"peroxo species","score":0.7570000290870667},{"id":"https://openalex.org/keywords/o-atom-transfer","display_name":"O-atom transfer","score":0.6259999871253967},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.6489999890327454}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9389913082122803},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.8900115489959717},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.7222172021865845},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6605387926101685},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.6299436092376709},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.5407266020774841},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.487562358379364},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.4550742208957672},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.43632179498672485},{"id":"https://openalex.org/C78030364","wikidata":"https://www.wikidata.org/wiki/Q5051391","display_name":"Catalytic oxidation","level":3,"score":0.43505775928497314},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4243171811103821},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12282681465148926},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.07242897152900696},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D002384","descriptor_name":"Catalysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D002563","descriptor_name":"Cerium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009566","descriptor_name":"Nitrates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012428","descriptor_name":"Ruthenium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D019281","descriptor_name":"Dimerization","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/ja3093532","doi":"https://doi.org/10.1021/ja3093532","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja3093532","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:23181743","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23181743","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":15,"referenced_works":["https://openalex.org/W1980687876","https://openalex.org/W1982373014","https://openalex.org/W2006181983","https://openalex.org/W2022839084","https://openalex.org/W2042020139","https://openalex.org/W2052298742","https://openalex.org/W2061335423","https://openalex.org/W2078096783","https://openalex.org/W2084181800","https://openalex.org/W2086681910","https://openalex.org/W2121832548","https://openalex.org/W2313512714","https://openalex.org/W2319044418","https://openalex.org/W2322459023","https://openalex.org/W2331224612"],"related_works":["https://openalex.org/W2006181983","https://openalex.org/W2136909795","https://openalex.org/W2074759453","https://openalex.org/W2061335423","https://openalex.org/W2078096783","https://openalex.org/W2030407485","https://openalex.org/W7099464300","https://openalex.org/W2322898310","https://openalex.org/W2013492186","https://openalex.org/W2027744093"],"abstract_inverted_index":{"At":[0],"high":[1],"concentrations,":[2],"nitrate":[3,57],"ion":[4],"alters":[5],"the":[6,18,43,46,69,82,104,114,159],"dynamics":[7],"of":[8,48,73],"ruthenium":[9],"\"blue":[10,160],"dimer\"-catalyzed":[11],"water":[12,147],"oxidation":[13,19,148],"by":[14,33,150],"Ce(IV)":[15,55],"such":[16],"that":[17,80],"rate":[20],"is":[21,31,86],"enhanced":[22],"and":[23,37,56,75,112],"a":[24,49,99,109],"unique":[25],"reaction":[26],"intermediate":[27,30],"accumulates.":[28],"This":[29],"characterized":[32],"distinct":[34],"EPR,":[35],"optical,":[36],"resonance":[38],"Raman":[39],"(RR)":[40],"spectra,":[41],"with":[42,98],"appearance":[44],"in":[45],"latter":[47],"new":[50,83],"oxygen":[51],"isotope-sensitive":[52],"band.":[53],"Both":[54],"are":[58,139],"required":[59],"to":[60,108,133],"generate":[61],"this":[62],"intermediate,":[63],"which":[64],"suggests":[65],"ceric-nitrate":[66],"complexes":[67],"as":[68,94],"causative":[70],"agents.":[71],"Use":[72],"(18)O-labeled":[74],"(15)N-labeled":[76],"materials":[77],"has":[78],"established":[79],"(1)":[81],"RR":[84],"band":[85],"not":[87,118],"an":[88,120,164],"O-O":[89],"stretching":[90],"mode":[91],"(for":[92],"example,":[93],"might":[95],"be":[96],"associated":[97],"peroxo":[100],"species)":[101],"but":[102],"involves":[103],"O":[105,121],"atom":[106,122],"coordinated":[107],"Ru":[110,152],"center,":[111],"(2)":[113],"O(2)":[115],"product":[116],"does":[117],"contain":[119],"derived":[123],"from":[124],"nitrate,":[125],"eliminating":[126],"several":[127],"plausible":[128],"pathways":[129],"involving":[130],"O-atom":[131],"transfer":[132],"oxidized":[134],"dimer.":[135],"Although":[136],"these":[137],"results":[138],"surprising,":[140],"similar":[141],"phenomena":[142],"have":[143],"been":[144],"reported":[145],"for":[146,158,167],"catalyzed":[149],"monomeric":[151],"complexes.":[153],"The":[154],"dramatic":[155],"effects":[156],"observed":[157],"dimer\"":[161],"make":[162],"it":[163],"ideal":[165],"candidate":[166],"further":[168],"study.":[169]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":8},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":6},{"year":2013,"cited_by_count":5}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}