{"id":"https://openalex.org/W2312948168","doi":"https://doi.org/10.1021/la301347t","title":"Molecular Adsorption on ZnO(1010) Single-Crystal Surfaces: Morphology and Charge Transfer","display_name":"Molecular Adsorption on ZnO(1010) Single-Crystal Surfaces: Morphology and Charge Transfer","publication_year":2012,"publication_date":"2012-06-08","ids":{"openalex":"https://openalex.org/W2312948168","doi":"https://doi.org/10.1021/la301347t","mag":"2312948168","pmid":"https://pubmed.ncbi.nlm.nih.gov/22680252"},"language":"en","primary_location":{"id":"doi:10.1021/la301347t","doi":"https://doi.org/10.1021/la301347t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la301347t","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5088937367","display_name":"Jixin Chen","orcid":"https://orcid.org/0000-0001-7381-0918","observed_orcids":["https://orcid.org/0000-0001-7381-0918","https://orcid.org/0000-0003-1763-8644"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jixin Chen","raw_affiliation_strings":["Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037603737","display_name":"Rose Emily Ruther","orcid":"https://orcid.org/0000-0002-1391-902X","observed_orcids":["https://orcid.org/0000-0002-1391-902X"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rose E. Ruther","raw_affiliation_strings":["Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003544719","display_name":"Yizheng Tan","orcid":"https://orcid.org/0000-0001-5512-1473","observed_orcids":["https://orcid.org/0000-0001-5512-1473"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yizheng Tan","raw_affiliation_strings":["Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082348670","display_name":"Lee M. Bishop","orcid":"https://orcid.org/0009-0003-5230-660X","observed_orcids":["https://orcid.org/0009-0003-5230-660X"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lee M. Bishop","raw_affiliation_strings":["Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5044102686","display_name":"Robert J. Hamers","orcid":"https://orcid.org/0000-0003-3821-9625","observed_orcids":["https://orcid.org/0000-0003-3821-9625"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Robert J. Hamers","raw_affiliation_strings":["Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Avenue, Madison,\rWisconsin 53706, United States","institution_ids":["https://openalex.org/I135310074"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5044102686"],"corresponding_institution_ids":["https://openalex.org/I135310074"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.9471,"has_fulltext":false,"cited_by_count":59,"citation_normalized_percentile":{"value":0.91086957,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":100},"biblio":{"volume":"28","issue":"28","first_page":"10437","last_page":"10445"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.4814000129699707,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.4814000129699707,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10090","display_name":"ZnO doping and properties","score":0.4794999957084656,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.005100000184029341,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zinc-oxide","display_name":"zinc oxide","score":0.7839999794960022},{"id":"https://openalex.org/keywords/zno-10-10-surface","display_name":"ZnO(10-10) surface","score":0.9419999718666077},{"id":"https://openalex.org/keywords/molecular-adsorption","display_name":"molecular adsorption","score":0.8180000185966492},{"id":"https://openalex.org/keywords/surface-passivation","display_name":"surface passivation","score":0.6190000176429749},{"id":"https://openalex.org/keywords/dye-sensitized-solar-cells","display_name":"dye-sensitized solar cells","score":0.7950000166893005},{"id":"https://openalex.org/keywords/alkanethiols","display_name":"alkanethiols","score":0.8209999799728394},{"id":"https://openalex.org/keywords/alkyl-carboxylic-acids","display_name":"alkyl carboxylic acids","score":0.8199999928474426},{"id":"https://openalex.org/keywords/alkylamines","display_name":"alkylamines","score":0.8949999809265137},{"id":"https://openalex.org/keywords/alkyl-alcohols","display_name":"alkyl alcohols","score":0.9869999885559082},{"id":"https://openalex.org/keywords/surface-etching","display_name":"surface etching","score":0.7089999914169312},{"id":"https://openalex.org/keywords/monolayer-formation","display_name":"monolayer formation","score":0.7639999985694885},{"id":"https://openalex.org/keywords/charge-transfer","display_name":"charge transfer","score":0.7950000166893005},{"id":"https://openalex.org/keywords/surface-band-bending","display_name":"surface band bending","score":0.9340000152587891}],"concepts":[{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.7768949866294861},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6332306265830994},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.6121074557304382},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5318984985351562},{"id":"https://openalex.org/C131649739","wikidata":"https://www.wikidata.org/wiki/Q1121115","display_name":"Self-assembled monolayer","level":3,"score":0.5050898194313049},{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.4662873446941376},{"id":"https://openalex.org/C2779074116","wikidata":"https://www.wikidata.org/wiki/Q134856","display_name":"Carboxylic acid","level":2,"score":0.4504464864730835},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.41580110788345337},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.41074472665786743},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.40923556685447693},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3836647570133209},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.2611408233642578},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.2490849494934082},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2468014657497406},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/la301347t","doi":"https://doi.org/10.1021/la301347t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la301347t","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:22680252","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22680252","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W258485877","https://openalex.org/W1559222007","https://openalex.org/W1967652077","https://openalex.org/W1968421400","https://openalex.org/W1970475344","https://openalex.org/W1972091231","https://openalex.org/W1979147773","https://openalex.org/W1980773287","https://openalex.org/W1983730600","https://openalex.org/W1986458731","https://openalex.org/W1986806507","https://openalex.org/W1987858784","https://openalex.org/W1990124068","https://openalex.org/W1991581634","https://openalex.org/W2001762929","https://openalex.org/W2014111101","https://openalex.org/W2018399372","https://openalex.org/W2018705268","https://openalex.org/W2021524364","https://openalex.org/W2021820606","https://openalex.org/W2024320624","https://openalex.org/W2032166764","https://openalex.org/W2036519912","https://openalex.org/W2041245006","https://openalex.org/W2042817671","https://openalex.org/W2043862025","https://openalex.org/W2044825940","https://openalex.org/W2046586002","https://openalex.org/W2046870563","https://openalex.org/W2047302526","https://openalex.org/W2065812463","https://openalex.org/W2067848545","https://openalex.org/W2068400426","https://openalex.org/W2068719575","https://openalex.org/W2069099100","https://openalex.org/W2072659900","https://openalex.org/W2072677085","https://openalex.org/W2078645034","https://openalex.org/W2087812087","https://openalex.org/W2090544387","https://openalex.org/W2090709519","https://openalex.org/W2102107615","https://openalex.org/W2103274508","https://openalex.org/W2114516433","https://openalex.org/W2132872911","https://openalex.org/W2141186037","https://openalex.org/W2159465711","https://openalex.org/W2160203846","https://openalex.org/W2165904200","https://openalex.org/W3089485186"],"related_works":["https://openalex.org/W2001762929","https://openalex.org/W2044825940","https://openalex.org/W2054012670","https://openalex.org/W2032166764","https://openalex.org/W2312309683","https://openalex.org/W2333355154","https://openalex.org/W1993444711","https://openalex.org/W1992368917","https://openalex.org/W2330456522","https://openalex.org/W2560217657"],"abstract_inverted_index":{"While":[0],"ZnO":[1,19,47,178,211,232],"has":[2,7],"excellent":[3],"electrical":[4],"properties,":[5],"it":[6],"not":[8],"been":[9],"widely":[10,25],"used":[11,26,32],"for":[12,33,37],"dye-sensitized":[13],"solar":[14],"cells,":[15],"in":[16,114,142],"part":[17],"because":[18],"is":[20],"chemically":[21],"less":[22],"stable":[23],"than":[24,197],"TiO(2).":[27],"The":[28,201],"functional":[29,70],"groups":[30,71],"typically":[31],"surface":[34,90,113,216,240,246],"passivation":[35],"and":[36,94,150,165,219,237],"attaching":[38],"dye":[39],"molecules":[40,59,106],"either":[41],"bind":[42,97,110,126],"weakly":[43,99,196],"or":[44,68],"etch":[45,88],"the":[46,52,89,101,112,128,177,181,189,198,207,227,239],"surface.":[48,103],"We":[49],"have":[50],"compared":[51],"formation":[53,182],"of":[54,120,147,183,203,229],"molecular":[55],"layers":[56],"from":[57],"alkane":[58],"with":[60,134],"terminal":[61],"carboxylic":[62,86],"acid,":[63,67],"alcohol,":[64],"amine,":[65],"phosphonic":[66,191],"thiol":[69],"on":[72,100,206],"single-crystal":[73],"zinc":[74],"oxide":[75],"(1010)":[76],"surfaces.":[77],"Atomic":[78],"force":[79],"microscopy":[80],"(AFM)":[81],"images":[82],"show":[83,225],"that":[84,171,226],"alkyl":[85,92,95],"acids":[87,192],"whereas":[91],"amine":[93],"alcohols":[96],"only":[98],"ZnO(1010)":[102],"Phosphonic":[104],"acid-terminated":[105],"were":[107,123,152,173],"found":[108,124],"to":[109,111,125,127,176,210,231,234,244],"a":[115],"heterogeneous":[116],"manner,":[117],"forming":[118,130],"clusters":[119],"molecules.":[121],"Alkanethiols":[122],"surface,":[129,179],"highly":[131],"uniform":[132],"monolayers":[133],"some":[135],"etching":[136],"detected":[137],"after":[138],"long":[139],"immersion":[140],"times":[141],"an":[143],"alkanethiol":[144],"solution.":[145],"Monolayers":[146],"hexadecylphosphonic":[148],"acid":[149],"octadecanethiol":[151],"further":[153],"analyzed":[154],"by":[155,214],"Fourier":[156],"transform":[157],"infrared":[158],"spectroscopy":[159,163],"(FTIR),":[160],"X-ray":[161],"photoelectron":[162],"(XPS),":[164],"electrochemical":[166,220],"measurements.":[167,222],"AFM":[168],"scratching":[169],"shows":[170],"thiols":[172,230],"bound":[174],"strongly":[175],"suggesting":[180],"strong":[184],"Zn-S":[185],"covalent":[186],"bonds.":[187],"Surprisingly,":[188],"tridentate":[190],"adhered":[193],"much":[194],"more":[195],"monodentate":[199],"thiol.":[200],"influence":[202],"organic":[204],"grafting":[205,228],"charge":[208],"transfer":[209],"was":[212],"studied":[213],"time-resolved":[215],"photovoltage":[217],"measurements":[218],"impedance":[221],"Our":[223],"results":[224],"leads":[233],"robust":[235],"surfaces":[236],"reduces":[238],"band":[241],"bending":[242],"due":[243],"midgap":[245],"states.":[247]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":14},{"year":2013,"cited_by_count":5}],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2016-06-24T00:00:00"}