{"id":"https://openalex.org/W2282095800","doi":null,"title":"VIBRATIONAL AND ROTATIONAL LASER SPECTROSCOPY OF SUPERSONICALLY COOLED ALKOXY AND ALKYLTHIO $RADICALS^{*}$","display_name":"VIBRATIONAL AND ROTATIONAL LASER SPECTROSCOPY OF SUPERSONICALLY COOLED ALKOXY AND ALKYLTHIO $RADICALS^{*}$","publication_year":1994,"publication_date":"1994-01-01","ids":{"openalex":"https://openalex.org/W2282095800","mag":"2282095800"},"language":"en","primary_location":{"id":"pmh:oai:kb.osu.edu:1811/13077","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/1811/13077","pdf_url":null,"source":{"id":"https://openalex.org/S4306402304","display_name":"The Knowledge Bank (The Ohio State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52357470","host_organization_name":"The Ohio State University","host_organization_lineage":["https://openalex.org/I52357470"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5113478864","display_name":"P. Misra","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"P. Misra","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111335447","display_name":"X.W. Zhu","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"X.W. Zhu","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111502488","display_name":"Mohammed M. Kamal","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Mohammed M. Kamal","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047597444","display_name":"Abdullahi H. Nur","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Abdullahi H. Nur","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5036715799","display_name":"Hosie L. Bryant","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Hosie L. Bryant","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.2547,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.37046038,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9678000211715698,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9678000211715698,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11111","display_name":"Spectroscopy and Laser Applications","score":0.029999999329447746,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alkoxy-radicals","display_name":"alkoxy radicals","score":0.9909999966621399},{"id":"https://openalex.org/keywords/supersonic-jet-cooling","display_name":"supersonic jet cooling","score":0.7350000143051147},{"id":"https://openalex.org/keywords/laser-induced-fluorescence","display_name":"laser-induced fluorescence","score":0.7649999856948853},{"id":"https://openalex.org/keywords/rotational-spectroscopy","display_name":"rotational spectroscopy","score":0.7089999914169312},{"id":"https://openalex.org/keywords/vibrational-spectroscopy","display_name":"vibrational spectroscopy","score":0.9900000095367432},{"id":"https://openalex.org/keywords/electronic-transitions","display_name":"electronic transitions","score":0.656000018119812},{"id":"https://openalex.org/keywords/excimer-laser-photolysis","display_name":"excimer laser photolysis","score":0.7250000238418579},{"id":"https://openalex.org/keywords/rotational-constants","display_name":"rotational constants","score":0.49399998784065247},{"id":"https://openalex.org/keywords/vibrational-frequencies","display_name":"vibrational frequencies","score":0.7160000205039978},{"id":"https://openalex.org/keywords/atmospheric-chemistry","display_name":"atmospheric chemistry","score":0.460999995470047},{"id":"https://openalex.org/keywords/combustion-chemistry","display_name":"combustion chemistry","score":0.9860000014305115}],"concepts":[{"id":"https://openalex.org/C108170787","wikidata":"https://www.wikidata.org/wiki/Q3951828","display_name":"Agency (philosophy)","level":2,"score":0.4958222806453705},{"id":"https://openalex.org/C90150868","wikidata":"https://www.wikidata.org/wiki/Q39513","display_name":"Alkoxy group","level":3,"score":0.49076780676841736},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.47523263096809387},{"id":"https://openalex.org/C17744445","wikidata":"https://www.wikidata.org/wiki/Q36442","display_name":"Political science","level":0,"score":0.350807249546051},{"id":"https://openalex.org/C87355193","wikidata":"https://www.wikidata.org/wiki/Q411","display_name":"Astrobiology","level":1,"score":0.34291183948516846},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.3222918212413788},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.30413877964019775},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.29629820585250854},{"id":"https://openalex.org/C144024400","wikidata":"https://www.wikidata.org/wiki/Q21201","display_name":"Sociology","level":0,"score":0.21643435955047607},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.1453101933002472},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11442676186561584},{"id":"https://openalex.org/C36289849","wikidata":"https://www.wikidata.org/wiki/Q34749","display_name":"Social science","level":1,"score":0.09617754817008972},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:kb.osu.edu:1811/13077","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/1811/13077","pdf_url":null,"source":{"id":"https://openalex.org/S4306402304","display_name":"The Knowledge Bank (The Ohio State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52357470","host_organization_name":"The Ohio State University","host_organization_lineage":["https://openalex.org/I52357470"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"article"},{"id":"mag:2282095800","doi":null,"is_oa":false,"landing_page_url":"http://kb.osu.edu/dspace/handle/1811/13077","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W1491576516","https://openalex.org/W2267271445","https://openalex.org/W1625145901","https://openalex.org/W433858535","https://openalex.org/W1497601890","https://openalex.org/W2376329301","https://openalex.org/W7039129921","https://openalex.org/W7000852193","https://openalex.org/W2066239359","https://openalex.org/W2084180279"],"abstract_inverted_index":{"The":[0],"alkoxy":[1],"$(RO":[2],"R=CH_{3},":[3],"C_{2}H_{5},":[4],"i-C_{3}H_{2})$":[5],"and":[6,18,38,82,100,108,129,132,138,155],"alkylthio":[7],"(RS)":[8],"free":[9],"radicals":[10,49],"are":[11],"important":[12],"chemical":[13],"intermediates":[14],"in":[15,24,54,144],"gas-phase":[16],"atmospheric":[17],"combustion":[19],"chemistry.":[20],"Laser-induced":[21],"fluorescence":[22],"(LIF),":[23],"conjunction":[25],"with":[26,42],"a":[27,124],"supersonic":[28,56],"jet":[29],"environment,":[30],"has":[31],"been":[32],"used":[33,89],"to":[34,90],"study":[35],"the":[36,55,97,114,117,136,145,148,153],"vibrational":[37,130],"rotational":[39,121,128],"spectroscopy":[40,151],"associated":[41],"electronic":[43],"transitions":[44],"involving":[45],"these":[46],"radicals.":[47,102,157],"RO":[48,99,154],"were":[50,72,88,110],"generated":[51],"{in":[52],"situ}":[53],"expansion":[57],"by":[58,112],"excimer":[59],"laser":[60,86,93],"(KrF":[61],"@":[62],"248":[63],"nm)":[64],"photolysis":[65],"of":[66,77,96,106,119,147,152],"RONO,":[67],"while":[68],"RS":[69,101,156],"molecular":[70,150],"fragments":[71],"produced":[73],"form":[74],"similar":[75],"photodissociation":[76],"$R_{2}S_{2}$.":[78],"Both":[79],"Nd;":[80],"YAG-pumped":[81],"excimer-pumped":[83],"tunable":[84],"dye":[85],"systems":[87],"record":[91],"rotationally-resolved":[92],"excitation":[94],"spectra":[95,105],"jet-cooled":[98],"Wavelength-resolved":[103],"emission":[104],"$CH_{3}O$":[107],"$CH_{3}S$":[109],"obtained":[111,134],"exciting":[113],"molecules":[115],"at":[116],"wavelength":[118],"strong":[120],"transition":[122],"within":[123],"vibronic":[125],"band.":[126],"Several":[127],"frequencies":[131],"parameters":[133],"from":[135],"assignments":[137],"leastsquares":[139],"fits":[140],"will":[141],"be":[142],"discussed":[143],"context":[146],"involved":[149]},"counts_by_year":[],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}