{"id":"https://openalex.org/W2278701092","doi":"https://doi.org/10.1149/ma2015-01/32/1812","title":"Study of the Supported Catalysts Core-Shell Type of Gold and Palladium: Analysis of the Reaction Products and Mechanism for the Electrooxidation of Ethanol in Alkaline Medium","display_name":"Study of the Supported Catalysts Core-Shell Type of Gold and Palladium: Analysis of the Reaction Products and Mechanism for the Electrooxidation of Ethanol in Alkaline Medium","publication_year":2015,"publication_date":"2015-04-29","ids":{"openalex":"https://openalex.org/W2278701092","doi":"https://doi.org/10.1149/ma2015-01/32/1812","mag":"2278701092"},"language":"en","primary_location":{"id":"doi:10.1149/ma2015-01/32/1812","doi":"https://doi.org/10.1149/ma2015-01/32/1812","is_oa":false,"landing_page_url":"https://doi.org/10.1149/ma2015-01/32/1812","pdf_url":null,"source":{"id":"https://openalex.org/S4210168594","display_name":"ECS Meeting Abstracts","issn_l":"1091-8213","issn":["1091-8213","2151-2035","2151-2043","2152-8365"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ECS Meeting Abstracts","raw_type":"journal-article"},"volume":null,"type":"conference-abstract","is_traditional":false,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5044397627","display_name":"Jos\u00e9 G. Ruiz-Montoya","orcid":"https://orcid.org/0000-0001-9586-9152","observed_orcids":["https://orcid.org/0000-0001-9586-9152"]},"institutions":[{"id":"https://openalex.org/I4210091878","display_name":"National University of Engineering","ror":"https://ror.org/00brc6r59","country_code":"NI","type":"education","lineage":["https://openalex.org/I4210091878"]},{"id":"https://openalex.org/I62520931","display_name":"National University of Engineering","ror":"https://ror.org/006v63s16","country_code":"PE","type":"education","lineage":["https://openalex.org/I62520931"]}],"countries":["NI","PE"],"is_corresponding":false,"raw_author_name":"Jos\u00e9 Gabriel Ruiz Montoya","raw_affiliation_strings":["Facultad de Ciencias, Universidad Nacional de Ingenier\u00eda"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Facultad de Ciencias, Universidad Nacional de Ingenier\u00eda","institution_ids":["https://openalex.org/I4210091878","https://openalex.org/I62520931"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062295900","display_name":"Violeta Herminia Ch\u00e1varri Mar\u00edn","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I192703252","display_name":"Universidad de Lima","ror":"https://ror.org/01751w114","country_code":"PE","type":"education","lineage":["https://openalex.org/I192703252"]},{"id":"https://openalex.org/I4210091878","display_name":"National University of Engineering","ror":"https://ror.org/00brc6r59","country_code":"NI","type":"education","lineage":["https://openalex.org/I4210091878"]},{"id":"https://openalex.org/I62520931","display_name":"National University of Engineering","ror":"https://ror.org/006v63s16","country_code":"PE","type":"education","lineage":["https://openalex.org/I62520931"]}],"countries":["NI","PE"],"is_corresponding":false,"raw_author_name":"Violeta Herminia Ch\u00e1varri Mar\u00edn","raw_affiliation_strings":["FIQT, Universidad Nacional de Ingenier\u00eda","Facultad de Ingenier\u00eda Industrial, Universidad de Lima"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"FIQT, Universidad Nacional de Ingenier\u00eda","institution_ids":["https://openalex.org/I4210091878","https://openalex.org/I62520931"]},{"raw_affiliation_string":"Facultad de Ingenier\u00eda Industrial, Universidad de Lima","institution_ids":["https://openalex.org/I192703252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027293163","display_name":"Ocon Pilar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63634437","display_name":"Universidad Aut\u00f3noma de Madrid","ror":"https://ror.org/01cby8j38","country_code":"ES","type":"education","lineage":["https://openalex.org/I63634437"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Pilar Oc\u00f3n Esteban","raw_affiliation_strings":["Facultad de Ciencias, Universidad Aut\u00f3noma de Madrid"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Facultad de Ciencias, Universidad Aut\u00f3noma de Madrid","institution_ids":["https://openalex.org/I63634437"]}]},{"author_position":"last","author":{"id":null,"display_name":"Juan Carlos Morales Gomero","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I192703252","display_name":"Universidad de Lima","ror":"https://ror.org/01751w114","country_code":"PE","type":"education","lineage":["https://openalex.org/I192703252"]},{"id":"https://openalex.org/I4210091878","display_name":"National University of Engineering","ror":"https://ror.org/00brc6r59","country_code":"NI","type":"education","lineage":["https://openalex.org/I4210091878"]},{"id":"https://openalex.org/I62520931","display_name":"National University of Engineering","ror":"https://ror.org/006v63s16","country_code":"PE","type":"education","lineage":["https://openalex.org/I62520931"]}],"countries":["NI","PE"],"is_corresponding":false,"raw_author_name":"Juan Carlos Morales Gomero","raw_affiliation_strings":["Facultad de Ciencias, Universidad Nacional de Ingenier\u00eda","Facultad de Ingenier\u00eda Industrial, Universidad de Lima"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Facultad de Ciencias, Universidad Nacional de Ingenier\u00eda","institution_ids":["https://openalex.org/I4210091878","https://openalex.org/I62520931"]},{"raw_affiliation_string":"Facultad de Ingenier\u00eda Industrial, Universidad de Lima","institution_ids":["https://openalex.org/I192703252"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":"MA2015-01","issue":"32","first_page":"1812","last_page":"1812"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10409","display_name":"Fuel Cells and Related Materials","score":0.0020000000949949026,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ethanol-electro-oxidation","display_name":"ethanol electrooxidation","score":0.8740000128746033},{"id":"https://openalex.org/keywords/direct-ethanol-fuel-cells","display_name":"direct ethanol fuel cells","score":0.8870000243186951},{"id":"https://openalex.org/keywords/palladium-nanoparticles","display_name":"palladium nanoparticles","score":0.6230000257492065},{"id":"https://openalex.org/keywords/gold-nanoparticles","display_name":"gold nanoparticles","score":0.703000009059906},{"id":"https://openalex.org/keywords/supported-catalysts","display_name":"supported catalysts","score":0.6539999842643738},{"id":"https://openalex.org/keywords/alkaline-media","display_name":"alkaline solution","score":0.8009999990463257},{"id":"https://openalex.org/keywords/acetate","display_name":"acetate","score":0.5709999799728394},{"id":"https://openalex.org/keywords/in-situ-ftir-spectroscopy","display_name":"in situ FTIR spectroscopy","score":0.8519999980926514},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7710000276565552},{"id":"https://openalex.org/keywords/c-c-bond-cleavage","display_name":"C\u2013C bond cleavage","score":0.7770000100135803},{"id":"https://openalex.org/keywords/electroactive-area","display_name":"electroactive area","score":0.4909999966621399},{"id":"https://openalex.org/keywords/anode-catalysts","display_name":"anode catalysts","score":0.6690000295639038},{"id":"https://openalex.org/keywords/platinum-free-catalysts","display_name":"platinum-free catalysts","score":0.574999988079071},{"id":"https://openalex.org/keywords/catalyst-loading-reduction","display_name":"catalyst loading reduction","score":0.46399998664855957},{"id":"https://openalex.org/keywords/carbon-support","display_name":"carbon support","score":0.4090000092983246},{"id":"https://openalex.org/keywords/ethanol-adsorption","display_name":"ethanol adsorption","score":0.4690000116825104}],"concepts":[{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.8994526863098145},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7932983636856079},{"id":"https://openalex.org/C518104683","wikidata":"https://www.wikidata.org/wiki/Q880","display_name":"Platinum","level":3,"score":0.6297661066055298},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6082589030265808},{"id":"https://openalex.org/C160331763","wikidata":"https://www.wikidata.org/wiki/Q282799","display_name":"Direct-ethanol fuel cell","level":4,"score":0.5814028978347778},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.5421321392059326},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5241001844406128},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5126590132713318},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.4663274586200714},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4483889937400818},{"id":"https://openalex.org/C2779343474","wikidata":"https://www.wikidata.org/wiki/Q3109175","display_name":"Context (archaeology)","level":2,"score":0.4210279881954193},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.41248324513435364},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.20108237862586975},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.13298705220222473},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.12883156538009644},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11107578873634338},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C151730666","wikidata":"https://www.wikidata.org/wiki/Q7205","display_name":"Paleontology","level":1,"score":0.0},{"id":"https://openalex.org/C132319479","wikidata":"https://www.wikidata.org/wiki/Q899619","display_name":"Proton exchange membrane fuel cell","level":3,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1149/ma2015-01/32/1812","doi":"https://doi.org/10.1149/ma2015-01/32/1812","is_oa":false,"landing_page_url":"https://doi.org/10.1149/ma2015-01/32/1812","pdf_url":null,"source":{"id":"https://openalex.org/S4210168594","display_name":"ECS Meeting Abstracts","issn_l":"1091-8213","issn":["1091-8213","2151-2035","2151-2043","2152-8365"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ECS Meeting Abstracts","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.75,"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W3165427507","https://openalex.org/W7037629847","https://openalex.org/W2915466978","https://openalex.org/W2007083266","https://openalex.org/W2315987709","https://openalex.org/W4409855088","https://openalex.org/W7018862683","https://openalex.org/W3133027836","https://openalex.org/W2231746209","https://openalex.org/W2289110013"],"abstract_inverted_index":{"One":[0,80],"of":[1,8,17,30,41,57,111,130,150,166,177,210,221,263,287,305,335,341,379,384,391,406,408],"the":[2,6,15,24,28,39,55,71,78,84,126,148,164,178,198,208,213,237,251,254,283,288,316,344,385],"main":[3,275],"disadvantages":[4],"to":[5,22,63,68,82,196,227,236,293,330],"development":[7],"fuel":[9],"cells":[10],"direct":[11],"ethanol":[12,46,58,112,131,141,222,301,355,380,409],"(DEFCs)":[13],"is":[14,75,95,137,233],"synthesis":[16],"catalysts":[18,168,179,318],"which":[19],"are":[20,279],"able":[21],"break":[23],"C-C":[25],"bond":[26,299],"in":[27,50,97,118,145,156,171,225,255,267,282,309,343,365,413],"molecule":[29],"ethanol.":[31],"In":[32,161,307],"this":[33,146,162,291,310],"context,":[34],"Xu":[35],"et":[36,104,122,351,376,399],"al.,[1]":[37],"compares":[38],"activity":[40],"palladium":[42,61,136,230,326],"and":[43,70,86,128,193,217,229,265,285,302,325,337,354,359,388],"platinum":[44],"for":[45,77,91,140,207],"oxidation":[47,59,72,113,129,220,262,334],"reaction":[48,85,89,386],"(EOR)":[49],"alkaline":[51,269,366,414],"medium,":[52],"showing":[53],"that":[54,206,315,323],"onset":[56,216,304],"on":[60,114,132,357,362,381,410],"occurs":[62],"potential":[64],"more":[65,138,332],"negative":[66],"compared":[67],"platinum,":[69],"current":[73,219],"density":[74,218],"higher":[76],"palladium.":[79],"way":[81],"study":[83,311],"propose":[87,107],"a":[88,151,240,331],"mechanism":[90,110],"an":[92,108,260,268],"electrochemical":[93,194],"process":[94],"using":[96,182],"situ":[98,256,402],"FTIR":[99,117,257,403],"spectroscopy.":[100],"For":[101],"example":[102],"Tremiliosi-Filho":[103],"al.,":[105,123],"[2]":[106,373],"accepted":[109],"gold":[115,228,238,324],"by":[116],"situ,":[119],"while":[120],"Zhou":[121],"[3]":[124,396],"studied":[125],"adsorption":[127],"polycrystalline":[133],"Pd.":[134],"Since,":[135],"electroactive":[139,200],"electrooxidation":[142,356,407],"than":[143],"gold,":[144],"work,":[147,163],"effect":[149],"supported":[152,169,361],"catalyst":[153],"core-shell":[154,167],"Au-Pd,":[155],"different":[157,172,297],"proportions":[158],"were":[159,223],"studied.":[160],"preparation":[165],"Au-Pd/C,":[170],"ratios":[173],"detailed.":[174],"The":[175],"characterization":[176],"was":[180,313],"performed":[181],"X-ray":[183],"diffraction,":[184],"Energy":[185],"Dispersive":[186],"Spectrometer":[187],"(EDS),":[188],"transmission":[189],"electron":[190],"microscopy":[191],"(TEM),":[192],"tests,":[195],"calculate":[197],"real":[199],"area.":[201],"Cyclic":[202],"voltammetry":[203],"tests":[204],"showed":[205,259],"case":[209],"Au-Pd":[211,317],"catalysts,":[212],"parameters":[214],"like":[215],"better":[224,320],"relation":[226],"alone.":[231],"This":[232,328],"due":[234],"largely":[235],"produces":[239],"stable":[241],"nucleus":[242],"where":[243],"Pd":[244,266,303,342,360,411],"nanoparticles":[245],"can":[246],"be":[247],"dispersed":[248],"better.":[249],"On":[250],"other":[252],"hand,":[253],"studies":[258,405],"identical":[261],"Au":[264],"medium":[270],"with":[271,274,296],"acetate":[272],"ion":[273],"product,":[276],"but":[277],"variations":[278],"also":[280],"observed":[281],"symmetry":[284],"intensity":[286],"collected":[289],"peaks,":[290],"has":[292],"see":[294],"strongly":[295],"intensities":[298],"between":[300],"oxidation.":[306],"conclusion,":[308],"it":[312],"found":[314],"show":[319],"electrocatalytic":[321],"properties":[322],"catalysts.":[327,346],"leads":[329],"efficient":[333],"ethanol,":[336],"use":[338],"less":[339],"amount":[340],"anode":[345],"References:":[347],"[1]":[348],"Xu,":[349],"Changwei,":[350],"al.":[352,377,400],"\"Methanol":[353],"Pt":[358],"carbon":[363],"microspheres":[364],"media.\"":[367,415],"Electrochemistry":[368],"Communications":[369],"9.5":[370],"(2007):":[371],"997-1001.":[372],"Tremiliosi-Filho,":[374],"G.,":[375],"\"Electro-oxidation":[378],"gold:":[382],"analysis":[383],"products":[387],"mechanism.\"":[389],"Journal":[390],"Electroanalytical":[392],"Chemistry444.1":[393],"(1998):":[394],"31-39.":[395],"Zhou,":[397],"Zhi-You,":[398],"\"In":[401],"spectroscopic":[404],"electrode":[412],"Electrochimica":[416],"Acta":[417],"55.27":[418],"(2010):":[419],"7995-7999.":[420],"Figure":[421],"1":[422]},"counts_by_year":[],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2016-06-24T00:00:00"}