{"id":"https://openalex.org/W2262607306","doi":"https://doi.org/10.1021/acs.jced.5b00724","title":"Vapor\u2013Liquid Equilibria, Excess Enthalpy, and Density of Aqueous \u03b3-Valerolactone Solutions.","display_name":"Vapor\u2013Liquid Equilibria, Excess Enthalpy, and Density of Aqueous \u03b3-Valerolactone Solutions.","publication_year":2016,"publication_date":"2016-01-26","ids":{"openalex":"https://openalex.org/W2262607306","doi":"https://doi.org/10.1021/acs.jced.5b00724","mag":"2262607306"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jced.5b00724","doi":"https://doi.org/10.1021/acs.jced.5b00724","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jced.5b00724","pdf_url":null,"source":{"id":"https://openalex.org/S204459408","display_name":"Journal of Chemical & Engineering Data","issn_l":"0021-9568","issn":["0021-9568","1520-5134"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Chemical &amp; Engineering Data","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Anna Zaitseva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I9927081","display_name":"Aalto University","ror":"https://ror.org/020hwjq30","country_code":"FI","type":"education","lineage":["https://openalex.org/I9927081"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Anna Zaitseva","raw_affiliation_strings":["Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland","institution_ids":["https://openalex.org/I9927081"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012120582","display_name":"Juha\u2010Pekka Pokki","orcid":"https://orcid.org/0000-0002-0857-6608","observed_orcids":["https://orcid.org/0000-0002-0857-6608"]},"institutions":[{"id":"https://openalex.org/I9927081","display_name":"Aalto University","ror":"https://ror.org/020hwjq30","country_code":"FI","type":"education","lineage":["https://openalex.org/I9927081"]}],"countries":["FI"],"is_corresponding":true,"raw_author_name":"Juha-Pekka Pokki","raw_affiliation_strings":["Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland","institution_ids":["https://openalex.org/I9927081"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033866191","display_name":"Huy Quang L\u00ea","orcid":"https://orcid.org/0000-0001-6290-3131","observed_orcids":["https://orcid.org/0000-0001-6290-3131"]},"institutions":[{"id":"https://openalex.org/I9927081","display_name":"Aalto University","ror":"https://ror.org/020hwjq30","country_code":"FI","type":"education","lineage":["https://openalex.org/I9927081"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Huy Quang Le","raw_affiliation_strings":["Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland","institution_ids":["https://openalex.org/I9927081"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049047616","display_name":"Ville Alopaeus","orcid":"https://orcid.org/0000-0001-9773-0998","observed_orcids":["https://orcid.org/0000-0001-9773-0998"]},"institutions":[{"id":"https://openalex.org/I9927081","display_name":"Aalto University","ror":"https://ror.org/020hwjq30","country_code":"FI","type":"education","lineage":["https://openalex.org/I9927081"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Ville Alopaeus","raw_affiliation_strings":["Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland","institution_ids":["https://openalex.org/I9927081"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5027159310","display_name":"Herbert Sixta","orcid":"https://orcid.org/0000-0002-9884-6885","observed_orcids":["https://orcid.org/0000-0002-9884-6885"]},"institutions":[{"id":"https://openalex.org/I9927081","display_name":"Aalto University","ror":"https://ror.org/020hwjq30","country_code":"FI","type":"education","lineage":["https://openalex.org/I9927081"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Herbert Sixta","raw_affiliation_strings":["Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biotechnology and Chemical Technology and \u2021Department of Forest Products Technology, School of Chemical Technology, Aalto University, Espoo, Finland","institution_ids":["https://openalex.org/I9927081"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5012120582"],"corresponding_institution_ids":["https://openalex.org/I9927081"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.8571,"has_fulltext":false,"cited_by_count":50,"citation_normalized_percentile":{"value":0.93417666,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":90,"max":99},"biblio":{"volume":"61","issue":"2","first_page":"881","last_page":"890"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.5737000107765198,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.5737000107765198,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10962","display_name":"Thermodynamic properties of mixtures","score":0.3091000020503998,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.0364999994635582,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gamma-valerolactone","display_name":"\u03b3-valerolactone","score":0.9879999756813049},{"id":"https://openalex.org/keywords/vapor-liquid-equilibrium","display_name":"vapor-liquid equilibrium","score":0.8659999966621399},{"id":"https://openalex.org/keywords/heat-of-mixing","display_name":"excess enthalpy","score":0.9539999961853027},{"id":"https://openalex.org/keywords/density","display_name":"density","score":0.6159999966621399},{"id":"https://openalex.org/keywords/vapor-pressure","display_name":"vapor pressure","score":0.9470000267028809},{"id":"https://openalex.org/keywords/delignification","display_name":"lignin removal","score":0.652999997138977},{"id":"https://openalex.org/keywords/lignocellulosic-biomass-fractionation","display_name":"lignocellulose fractionation","score":0.906000018119812},{"id":"https://openalex.org/keywords/activity-coefficient-models","display_name":"activity coefficient models","score":0.7630000114440918},{"id":"https://openalex.org/keywords/uniquac","display_name":"UNIQUAC","score":0.949999988079071},{"id":"https://openalex.org/keywords/nrtl-model","display_name":"NRTL model","score":0.9980000257492065},{"id":"https://openalex.org/keywords/cosmo-rs","display_name":"COSMO-RS","score":0.9789999723434448},{"id":"https://openalex.org/keywords/unifac-dortmund","display_name":"UNIFAC-Dortmund","score":0.9629999995231628},{"id":"https://openalex.org/keywords/positive-deviation-from-raoult-s-law","display_name":"positive deviation from Raoult's law","score":0.9179999828338623},{"id":"https://openalex.org/keywords/azeotropes","display_name":"azeotropes","score":0.7559999823570251}],"concepts":[{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7594571709632874},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.7500928640365601},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.576947033405304},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5225788354873657},{"id":"https://openalex.org/C33038907","wikidata":"https://www.wikidata.org/wiki/Q10273440","display_name":"Vapor\u2013liquid equilibrium","level":2,"score":0.47765982151031494},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.2562928795814514},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23741444945335388},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.1076713502407074}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.jced.5b00724","doi":"https://doi.org/10.1021/acs.jced.5b00724","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jced.5b00724","pdf_url":null,"source":{"id":"https://openalex.org/S204459408","display_name":"Journal of Chemical & Engineering Data","issn_l":"0021-9568","issn":["0021-9568","1520-5134"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Chemical &amp; Engineering Data","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5144604030","display_name":null,"funder_award_id":"253336","funder_id":"https://openalex.org/F4320335063","funder_display_name":"Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta"}],"funders":[{"id":"https://openalex.org/F4320335063","display_name":"Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta","ror":"https://ror.org/05k73zm37"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":45,"referenced_works":["https://openalex.org/W154885656","https://openalex.org/W243120599","https://openalex.org/W1563689801","https://openalex.org/W1969248899","https://openalex.org/W1971717954","https://openalex.org/W1975200744","https://openalex.org/W1976883040","https://openalex.org/W1979433091","https://openalex.org/W1982894666","https://openalex.org/W1989402852","https://openalex.org/W2000954749","https://openalex.org/W2001525422","https://openalex.org/W2021321463","https://openalex.org/W2021893248","https://openalex.org/W2036708818","https://openalex.org/W2040209069","https://openalex.org/W2041943225","https://openalex.org/W2047150613","https://openalex.org/W2052854384","https://openalex.org/W2053432604","https://openalex.org/W2053955315","https://openalex.org/W2055911538","https://openalex.org/W2057318307","https://openalex.org/W2057837243","https://openalex.org/W2057857147","https://openalex.org/W2066430137","https://openalex.org/W2069829322","https://openalex.org/W2075087451","https://openalex.org/W2094818470","https://openalex.org/W2123042820","https://openalex.org/W2131606843","https://openalex.org/W2137605840","https://openalex.org/W2141913911","https://openalex.org/W2159544707","https://openalex.org/W2164085459","https://openalex.org/W2171250148","https://openalex.org/W2315473912","https://openalex.org/W2317944676","https://openalex.org/W2330627679","https://openalex.org/W2330989907","https://openalex.org/W2333783525","https://openalex.org/W2510525899","https://openalex.org/W2950936553","https://openalex.org/W4237113196","https://openalex.org/W4239653023"],"related_works":["https://openalex.org/W2312076429","https://openalex.org/W3100177175","https://openalex.org/W4416094581","https://openalex.org/W7167591201","https://openalex.org/W7127053257","https://openalex.org/W7067048951","https://openalex.org/W2486118103","https://openalex.org/W3004249830","https://openalex.org/W2217820892","https://openalex.org/W4353058588"],"abstract_inverted_index":{"Thermodynamic":[0],"measurements":[1,112],"were":[2,66,92,161],"made":[3],"for":[4,14,70,127,163],"the":[5,19,22,39,75,85,125,128,164],"binary":[6,86,192],"mixture":[7,87,126,193],"of":[8,21,24,41,58,64,74,84,88,104,124,131,166],"water":[9,89,189],"+":[10,90,190],"\u03b3-valerolactone":[11],"(GVL)":[12],"and":[13,47,55,68,77,152,157,168,185],"pure":[15,59],"GVL":[16,60,91,115,191],"to":[17],"facilitate":[18],"development":[20],"technology":[23],"lignin":[25],"removal":[26],"from":[27,197],"lignocellulosic":[28],"biomass":[29],"(":[30,120],"Fang,":[31],"W.;":[32],"Sixta,":[33],"H.":[34],"Advanced":[35],"Biorefinery":[36],"based":[37],"on":[38],"Fractionation":[40],"Biomass":[42],"in":[43],"\u03b3":[44],"-":[45],"Valerolactone":[46],"Water.":[48],"ChemSusChem":[49],"2015,":[50],"8,":[51],"73\u221276).":[52],"The":[53,155,174,188],"density":[54],"vapor":[56],"pressure":[57,101],"as":[61],"a":[62,71,98,140,146],"function":[63],"temperature":[65],"measured":[67,93,138],"correlated":[69],"wide":[72],"range":[73,130],"temperatures":[76],"pressures.":[78],"Isothermal":[79],"vapor\u2013liquid":[80],"equilibrium":[81],"(VLE)":[82],"data":[83,160],"at":[94,150],"350.2":[95],"K":[96],"with":[97,113,145,180],"static":[99],"total":[100],"apparatus.":[102],"Absence":[103],"an":[105],"azeotrope":[106],"was":[107,137],"confirmed":[108],"by":[109,183],"circulation":[110],"still":[111],"diluted":[114],"solutions.":[116],"Excess":[117],"molar":[118],"enthalpy":[119],"h":[121,158],"E":[122,159],")":[123],"whole":[129],"mole":[132],"fractions":[133],"including":[134],"infinite":[135],"dilution":[136],"using":[139],"SETARAM":[141],"C80":[142],"calorimeter":[143],"equipped":[144],"flow":[147],"mixing":[148],"cell":[149],"322.6":[151],"303.2":[153],"K.":[154],"VLE":[156],"used":[162],"optimization":[165],"UNIQUAC":[167],"NRTL":[169],"activity":[170],"coefficient":[171],"model":[172],"parameters.":[173],"experimental":[175],"results":[176],"are":[177],"compared":[178],"herein":[179],"those":[181],"predicted":[182],"COSMO-RS":[184],"UNIFAC-Dortmund":[186],"models.":[187],"shows":[194],"positive":[195],"deviation":[196],"Raoult\u2019s":[198],"law.":[199]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":7},{"year":2016,"cited_by_count":3}],"updated_date":"2026-10-25T09:29:13.331239","created_date":"2016-06-24T00:00:00"}
