{"id":"https://openalex.org/W2260256133","doi":"https://doi.org/10.1021/acs.organomet.5b00548","title":"Mechanistic Study on C\u2013C Bond Formation of a Nickel(I) Monocarbonyl Species with Alkyl Iodides: Experimental and Computational Investigations","display_name":"Mechanistic Study on C\u2013C Bond Formation of a Nickel(I) Monocarbonyl Species with Alkyl Iodides: Experimental and Computational Investigations","publication_year":2015,"publication_date":"2015-08-27","ids":{"openalex":"https://openalex.org/W2260256133","doi":"https://doi.org/10.1021/acs.organomet.5b00548","mag":"2260256133"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.5b00548","doi":"https://doi.org/10.1021/acs.organomet.5b00548","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.5b00548","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5077835523","display_name":"Changho Yoo","orcid":"https://orcid.org/0000-0002-2849-0078","observed_orcids":["https://orcid.org/0000-0002-2849-0078"]},"institutions":[{"id":"https://openalex.org/I157485424","display_name":"Korea Advanced Institute of Science and Technology","ror":"https://ror.org/05apxxy63","country_code":"KR","type":"education","lineage":["https://openalex.org/I157485424"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Changho Yoo","raw_affiliation_strings":["Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea","institution_ids":["https://openalex.org/I157485424"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070482744","display_name":"Manjaly J. Ajitha","orcid":"https://orcid.org/0000-0002-0613-6270","observed_orcids":["https://orcid.org/0000-0002-0613-6270"]},"institutions":[{"id":"https://openalex.org/I157485424","display_name":"Korea Advanced Institute of Science and Technology","ror":"https://ror.org/05apxxy63","country_code":"KR","type":"education","lineage":["https://openalex.org/I157485424"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Manjaly J. Ajitha","raw_affiliation_strings":["Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea","institution_ids":["https://openalex.org/I157485424"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090795969","display_name":"Yousung Jung","orcid":"https://orcid.org/0000-0003-2615-8394","observed_orcids":["https://orcid.org/0000-0003-2615-8394"]},"institutions":[{"id":"https://openalex.org/I157485424","display_name":"Korea Advanced Institute of Science and Technology","ror":"https://ror.org/05apxxy63","country_code":"KR","type":"education","lineage":["https://openalex.org/I157485424"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Yousung Jung","raw_affiliation_strings":["Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea","institution_ids":["https://openalex.org/I157485424"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5101679626","display_name":"Yunho Lee","orcid":"https://orcid.org/0000-0002-9113-9491","observed_orcids":["https://orcid.org/0000-0002-9113-9491"]},"institutions":[{"id":"https://openalex.org/I157485424","display_name":"Korea Advanced Institute of Science and Technology","ror":"https://ror.org/05apxxy63","country_code":"KR","type":"education","lineage":["https://openalex.org/I157485424"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Yunho Lee","raw_affiliation_strings":["Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and \u2021Graduate\rSchool of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea","institution_ids":["https://openalex.org/I157485424"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5090795969","https://openalex.org/A5101679626"],"corresponding_institution_ids":["https://openalex.org/I157485424"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.5528,"has_fulltext":false,"cited_by_count":37,"citation_normalized_percentile":{"value":0.79467004,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"34","issue":"17","first_page":"4305","last_page":"4311"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9320999979972839,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9320999979972839,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.05649999901652336,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.002199999988079071,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbon-carbon-bond-formation","display_name":"C\u2013C bond formation","score":0.8980000019073486},{"id":"https://openalex.org/keywords/alkyl-iodides","display_name":"alkyl iodides","score":0.9520000219345093},{"id":"https://openalex.org/keywords/alkyl-radical-generation","display_name":"alkyl radical generation","score":0.6510000228881836},{"id":"https://openalex.org/keywords/methyl-radical","display_name":"methyl radical","score":0.5009999871253967},{"id":"https://openalex.org/keywords/co-removal","display_name":"carbon monoxide removal","score":0.7609999775886536},{"id":"https://openalex.org/keywords/radical-trapping","display_name":"radical trapping","score":0.44999998807907104}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9548576474189758},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.7876697182655334},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.7614520788192749},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6298989057540894},{"id":"https://openalex.org/C137955730","wikidata":"https://www.wikidata.org/wiki/Q6844361","display_name":"Migratory insertion","level":3,"score":0.5255626440048218},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.5156837701797485},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5113012790679932},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.42091104388237},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.38890063762664795},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.17774438858032227},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.13246279954910278},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acs.organomet.5b00548","doi":"https://doi.org/10.1021/acs.organomet.5b00548","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.5b00548","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},{"id":"pmh:oai:s-space.snu.ac.kr:10371/225868","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/10371/225868","pdf_url":null,"source":{"id":"https://openalex.org/S4306401345","display_name":"Seoul National University Open Repository (Seoul National University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139264467","host_organization_name":"Seoul National University","host_organization_lineage":["https://openalex.org/I139264467"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Article"},{"id":"pmh:oai:scholarworks.unist.ac.kr:201301/65376","doi":null,"is_oa":false,"landing_page_url":"https://scholarworks.unist.ac.kr/handle/201301/65376","pdf_url":null,"source":{"id":"https://openalex.org/S4306401118","display_name":"Scholarworks@UNIST (Ulsan National Institute of Science and Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I48566637","host_organization_name":"Ulsan National Institute of Science and Technology","host_organization_lineage":["https://openalex.org/I48566637"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"ARTICLE"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1964046434","https://openalex.org/W1966345602","https://openalex.org/W1977119201","https://openalex.org/W1981706397","https://openalex.org/W1982874695","https://openalex.org/W1993773515","https://openalex.org/W1994787188","https://openalex.org/W2000461729","https://openalex.org/W2011777921","https://openalex.org/W2020160573","https://openalex.org/W2021502908","https://openalex.org/W2061939602","https://openalex.org/W2063003654","https://openalex.org/W2064299064","https://openalex.org/W2077657121","https://openalex.org/W2078401805","https://openalex.org/W2085280604","https://openalex.org/W2092157292","https://openalex.org/W2096747776","https://openalex.org/W2103018068","https://openalex.org/W2112196245","https://openalex.org/W2117893900","https://openalex.org/W2120901082","https://openalex.org/W2135346135","https://openalex.org/W2145923611","https://openalex.org/W2274366216","https://openalex.org/W2323173503","https://openalex.org/W2325950078","https://openalex.org/W2327206086","https://openalex.org/W2331001885","https://openalex.org/W2332514945","https://openalex.org/W2950678427"],"related_works":["https://openalex.org/W4399109443","https://openalex.org/W2055442662","https://openalex.org/W2145923611","https://openalex.org/W2934002192","https://openalex.org/W2010953979","https://openalex.org/W2335347229","https://openalex.org/W2898240532","https://openalex.org/W2164343517","https://openalex.org/W2274366216","https://openalex.org/W2009105926"],"abstract_inverted_index":{"An":[0],"open-shell":[1],"reaction":[2],"of":[3,47,95,142,152,187],"the":[4,39,73,105,140,165,176,185],"nickel(I)":[5,27],"carbonyl":[6,28,93,177],"species":[7,29,76,108],"(PNP)Ni-CO":[8],"(":[9,35,79,112,145],"1":[10,96],")":[11,37,81,111,114,147],"with":[12,130],"iodoalkanes":[13],"has":[14],"been":[15],"explored":[16],"experimentally":[17],"and":[18,38,97,119,175],"theoretically.":[19],"The":[20],"initial":[21],"iodine":[22],"radical":[23,57,63,174],"abstraction":[24],"by":[25,62,85],"a":[26,45,86,92,98,124,131,149,155,180],"was":[30,59],"suggested":[31,129],"to":[32,44],"produce":[33],"(PNP)Ni-I":[34],"4":[36],"concomitant":[40],"alkyl":[41,56,173],"radical,":[42],"according":[43],"series":[46],"experimental":[48],"indications":[49],"involving":[50],"stoichiometric":[51],"controls":[52],"employing":[53],"iodoalkanes.":[54],"Corresponding":[55],"generation":[58,186],"also":[60,128],"confirmed":[61],"trapping":[64],"experiments":[65],"using":[66],"Gomberg\u2019s":[67],"dimer.":[68],"Molecular":[69],"modeling":[70],"supports":[71,163],"that":[72,115,164],"nickel":[74,182],"acyl":[75,189],"(PNP)Ni-COCH":[77],"3":[78,110,121,144,146],"2":[80],"can":[82],"be":[83],"formed":[84],"direct":[87,166],"C\u2013C":[88,167],"bond":[89,168],"formation":[90,141],"between":[91,171],"ligand":[94,178],"methyl":[99],"radical.":[100],"As":[101],"an":[102,172,188],"alternative":[103],"pathway,":[104],"five-coordinate":[106],"intermediate":[107],"(PNP)Ni(CO)(CH":[109],"5":[113],"involves":[116],"both":[117],"CO":[118,153,156],"CH":[120],"binding":[122],"at":[123,179],"nickel(II)":[125],"center":[126,183],"is":[127],"comparable":[132],"activation":[133],"barrier,":[134],"although":[135],"this":[136],"pathway":[137],"energetically":[138],"favors":[139],"(PNP)Ni-CH":[143],"via":[148],"barrierless":[150],"elimination":[151],"over":[154],"migratory":[157],"insertion.":[158],"Thus,":[159],"our":[160],"present":[161],"work":[162],"coupling":[169],"occurs":[170],"monovalent":[181],"in":[184],"product.":[190]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":3}],"updated_date":"2026-09-23T05:00:35.095934","created_date":"2016-06-24T00:00:00"}
