{"id":"https://openalex.org/W221735","doi":null,"title":"The characterization and chemistry of {\\it mono/}- and {\\it bis/}-cyclopentadienyl titanium thiolates.","display_name":"The characterization and chemistry of {\\it mono/}- and {\\it bis/}-cyclopentadienyl titanium thiolates.","publication_year":1993,"publication_date":"1993-01-01","ids":{"openalex":"https://openalex.org/W221735","mag":"221735"},"language":"en","primary_location":{"id":"pmh:oai:scholar.uwindsor.ca:etd-4785","doi":null,"is_oa":true,"landing_page_url":"https://scholar.uwindsor.ca/etd/3786","pdf_url":"https://scholar.uwindsor.ca/etd/3786","source":{"id":"https://openalex.org/S4306400430","display_name":"Scholarship at UWindsor (University of Windsor)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I74413500","host_organization_name":"University of Windsor","host_organization_lineage":["https://openalex.org/I74413500"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Electronic Theses and Dissertations","raw_type":"info:eu-repo/semantics/doctoralThesis"},"volume":null,"type":"dissertation","indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://scholar.uwindsor.ca/etd/3786","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5015140543","display_name":"T. Timothy Nadasdi","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"T. Timothy Nadasdi","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5015140543"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9150000214576721,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9150000214576721,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.04360000044107437,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.027300000190734863,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/titanocene-dichloride","display_name":"titanocene dichloride","score":0.7929999828338623},{"id":"https://openalex.org/keywords/dithiols","display_name":"dithiols","score":0.9409999847412109},{"id":"https://openalex.org/keywords/imidazole","display_name":"imidazole","score":0.6539999842643738},{"id":"https://openalex.org/keywords/bimetallic-compounds","display_name":"bimetallic compounds","score":0.6740000247955322},{"id":"https://openalex.org/keywords/bridging-disulfide-ligand","display_name":"bridging disulfide ligand","score":0.7390000224113464},{"id":"https://openalex.org/keywords/organotitanium-chemistry","display_name":"organotitanium chemistry","score":0.8040000200271606}],"concepts":[{"id":"https://openalex.org/C181458950","wikidata":"https://www.wikidata.org/wiki/Q2855060","display_name":"Cyclopentadienyl complex","level":3,"score":0.6939470767974854},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6502512693405151},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.6319743394851685},{"id":"https://openalex.org/C506065880","wikidata":"https://www.wikidata.org/wiki/Q716","display_name":"Titanium","level":2,"score":0.5761994123458862},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3323129415512085},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.24247878789901733},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.1800876259803772},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.17964521050453186},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.16140684485435486}],"mesh":[],"locations_count":3,"locations":[{"id":"pmh:oai:scholar.uwindsor.ca:etd-4785","doi":null,"is_oa":true,"landing_page_url":"https://scholar.uwindsor.ca/etd/3786","pdf_url":"https://scholar.uwindsor.ca/etd/3786","source":{"id":"https://openalex.org/S4306400430","display_name":"Scholarship at UWindsor (University of Windsor)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I74413500","host_organization_name":"University of Windsor","host_organization_lineage":["https://openalex.org/I74413500"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Electronic Theses and Dissertations","raw_type":"info:eu-repo/semantics/doctoralThesis"},{"id":"pmh:oai:uwindsor.scholaris.ca:20.500.14776/3410","doi":null,"is_oa":true,"landing_page_url":"https://hdl.handle.net/20.500.14776/3410","pdf_url":null,"source":{"id":"https://openalex.org/S4306400430","display_name":"Scholarship at UWindsor (University of Windsor)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I74413500","host_organization_name":"University of Windsor","host_organization_lineage":["https://openalex.org/I74413500"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/doctoralThesis"},{"id":"mag:221735","doi":null,"is_oa":false,"landing_page_url":"https://scholar.uwindsor.ca/etd/3786/","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:scholar.uwindsor.ca:etd-4785","doi":null,"is_oa":true,"landing_page_url":"https://scholar.uwindsor.ca/etd/3786","pdf_url":"https://scholar.uwindsor.ca/etd/3786","source":{"id":"https://openalex.org/S4306400430","display_name":"Scholarship at UWindsor (University of Windsor)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I74413500","host_organization_name":"University of Windsor","host_organization_lineage":["https://openalex.org/I74413500"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Electronic Theses and Dissertations","raw_type":"info:eu-repo/semantics/doctoralThesis"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W221735.pdf"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2313446138","https://openalex.org/W2028383224","https://openalex.org/W2319528046","https://openalex.org/W2321291013","https://openalex.org/W110252347","https://openalex.org/W2524712889","https://openalex.org/W1985573539","https://openalex.org/W2795508569","https://openalex.org/W2107675065","https://openalex.org/W2036387527"],"abstract_inverted_index":{"The":[0,45],"reactions":[1],"of":[2,16,21,41,55,90],"Cp$\\\\rm\\\\sb2TiCl\\\\sb2$":[3],"with":[4,19,43,52],"the":[5,14,39,53,60],"dithiols,":[6],"HS(CH$\\\\sb2)\\\\sb{\\\\rm":[7],"n}$SH":[8],"(n":[9,66],"=":[10,67,71],"2,":[11],"3)":[12],"in":[13],"presence":[15],"imidazole":[17],"proceed":[18],"formation":[20],"imidazole$\\\\cdot$HCl":[22],"affording":[23],"relatively":[24],"insoluble":[25],"titanocene":[26],"dithiolate":[27],"derivatives":[28],"2.1":[29,56],"and":[30,47,57],"2.2":[31,34,58],"respectively.":[32],"Alternatively,":[33],"can":[35],"be":[36],"prepared":[37],"by":[38],"reaction":[40],"Cp$\\\\rm\\\\sb2TiPh\\\\sb2$":[42],"dithiol.":[44],"spectroscopic":[46],"analytical":[48],"data":[49],"are":[50],"consistent":[51],"formulation":[54],"as":[59],"bimetallic":[61],"compounds":[62],"Cp$\\\\rm\\\\sb2Ti(\\\\mu$-S(CH$\\\\sb2)\\\\sb{\\\\rm":[63],"n}\\\\rm":[64],"S)\\\\sb2TiCp\\\\sb2$":[65],"2":[68],"2.1,":[69],"n":[70],"3":[72],"2.2).":[73],"Source:":[74],"Dissertation":[75],"Abstracts":[76],"International,":[77],"Volume:":[78],"55-05,":[79],"Section:":[80],"B,":[81],"page:":[82],"1842.":[83],"Adviser:":[84],"D.":[85],"W.":[86],"Stephan.":[87],"Thesis":[88],"(Ph.D.)--University":[89],"Windsor":[91],"(Canada),":[92],"1993.":[93]},"counts_by_year":[],"updated_date":"2026-09-11T09:22:31.653822","created_date":"2016-06-24T00:00:00"}