{"id":"https://openalex.org/W2196619230","doi":null,"title":"Mechanochemical reactions in lignocellulosic materials","display_name":"Mechanochemical reactions in lignocellulosic materials","publication_year":2015,"publication_date":"2015-01-01","ids":{"openalex":"https://openalex.org/W2196619230","mag":"2196619230"},"language":"en","primary_location":{"id":"mag:2196619230","doi":null,"is_oa":false,"landing_page_url":"https://aaltodoc.aalto.fi:443/bitstream/123456789/18003/4/isbn9789526063874.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089825693","display_name":"Iina Solala","orcid":"https://orcid.org/0000-0002-8110-456X","observed_orcids":["https://orcid.org/0000-0002-8110-456X"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Iina Solala","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5089825693"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.1049,"has_fulltext":true,"cited_by_count":4,"citation_normalized_percentile":{"value":0.35100889,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":93},"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10610","display_name":"Advanced Cellulose Research Studies","score":0.8125,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10610","display_name":"Advanced Cellulose Research Studies","score":0.8125,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":0.17790000140666962,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10513","display_name":"Natural Fiber Reinforced Composites","score":0.0027000000700354576,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/mechanochemistry","display_name":"mechanochemistry","score":0.9089999794960022},{"id":"https://openalex.org/keywords/lignocellulosic-materials","display_name":"lignocellulosic materials","score":0.9810000061988831},{"id":"https://openalex.org/keywords/mechanoradicals","display_name":"mechanoradicals","score":0.9660000205039978},{"id":"https://openalex.org/keywords/cellulose-nanofibers","display_name":"cellulose nanofibers","score":0.9729999899864197},{"id":"https://openalex.org/keywords/thermomechanical-pulping","display_name":"thermomechanical pulping","score":0.9110000133514404},{"id":"https://openalex.org/keywords/ball-milling","display_name":"ball milling","score":0.925000011920929},{"id":"https://openalex.org/keywords/styrene","display_name":"styrene","score":0.6819999814033508},{"id":"https://openalex.org/keywords/cotton-fiber","display_name":"cotton fiber","score":0.7480000257492065},{"id":"https://openalex.org/keywords/biocomposites","display_name":"biocomposites","score":0.6309999823570251},{"id":"https://openalex.org/keywords/fiber-reinforcement","display_name":"fiber reinforcement","score":0.5929999947547913},{"id":"https://openalex.org/keywords/hydrophobicity","display_name":"hydrophobicity","score":0.6460000276565552}],"concepts":[{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6929342746734619},{"id":"https://openalex.org/C508816927","wikidata":"https://www.wikidata.org/wiki/Q901098","display_name":"Mechanochemistry","level":2,"score":0.6731018424034119},{"id":"https://openalex.org/C188442228","wikidata":"https://www.wikidata.org/wiki/Q48286","display_name":"Pulp (tooth)","level":2,"score":0.6232776641845703},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.5379008054733276},{"id":"https://openalex.org/C2779251873","wikidata":"https://www.wikidata.org/wiki/Q80294","display_name":"Cellulose","level":2,"score":0.5287696123123169},{"id":"https://openalex.org/C112950240","wikidata":"https://www.wikidata.org/wiki/Q76005","display_name":"Ultimate tensile strength","level":2,"score":0.4869600236415863},{"id":"https://openalex.org/C132186339","wikidata":"https://www.wikidata.org/wiki/Q781139","display_name":"Ball mill","level":2,"score":0.4709010422229767},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.44168969988822937},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.13092505931854248},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:2196619230","doi":null,"is_oa":false,"landing_page_url":"https://aaltodoc.aalto.fi:443/bitstream/123456789/18003/4/isbn9789526063874.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321394","display_name":"Aalto-Yliopisto","ror":"https://ror.org/020hwjq30"},{"id":"https://openalex.org/F4320321855","display_name":"Tekes","ror":"https://ror.org/02ag8cq23"},{"id":"https://openalex.org/F4320327732","display_name":"Walter Ahlstr\u00f6min S\u00e4\u00e4ti\u00f6","ror":"https://ror.org/00vdff906"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":175,"referenced_works":["https://openalex.org/W13851674","https://openalex.org/W47292792","https://openalex.org/W87334710","https://openalex.org/W204128722","https://openalex.org/W204782181","https://openalex.org/W350571652","https://openalex.org/W595008318","https://openalex.org/W609664305","https://openalex.org/W1484347333","https://openalex.org/W1519045032","https://openalex.org/W1545775688","https://openalex.org/W1557681670","https://openalex.org/W1565082402","https://openalex.org/W1570065020","https://openalex.org/W1599410403","https://openalex.org/W1603086062","https://openalex.org/W1606603686","https://openalex.org/W1608906368","https://openalex.org/W1655673653","https://openalex.org/W1666441900","https://openalex.org/W1919863835","https://openalex.org/W1932277571","https://openalex.org/W1963961003","https://openalex.org/W1966262614","https://openalex.org/W1967183757","https://openalex.org/W1967197063","https://openalex.org/W1967212062","https://openalex.org/W1967631989","https://openalex.org/W1967935126","https://openalex.org/W1968371747","https://openalex.org/W1969889120","https://openalex.org/W1970456511","https://openalex.org/W1970978861","https://openalex.org/W1974664624","https://openalex.org/W1975220168","https://openalex.org/W1976712152","https://openalex.org/W1976745823","https://openalex.org/W1979920548","https://openalex.org/W1982503302","https://openalex.org/W1983375774","https://openalex.org/W1983844422","https://openalex.org/W1984229846","https://openalex.org/W1984484226","https://openalex.org/W1985570667","https://openalex.org/W1988147327","https://openalex.org/W1989173575","https://openalex.org/W1989181295","https://openalex.org/W1990826350","https://openalex.org/W1991509281","https://openalex.org/W1991794932","https://openalex.org/W1991976588","https://openalex.org/W1993430734","https://openalex.org/W1996441425","https://openalex.org/W1996538335","https://openalex.org/W1997429178","https://openalex.org/W1998221419","https://openalex.org/W1998875382","https://openalex.org/W1998893177","https://openalex.org/W2000213969","https://openalex.org/W2000282053","https://openalex.org/W2003153091","https://openalex.org/W2005003934","https://openalex.org/W2006143868","https://openalex.org/W2009388318","https://openalex.org/W2013529447","https://openalex.org/W2013804218","https://openalex.org/W2013848006","https://openalex.org/W2013866855","https://openalex.org/W2013878448","https://openalex.org/W2014339248","https://openalex.org/W2014734348","https://openalex.org/W2017428399","https://openalex.org/W2020372201","https://openalex.org/W2020375047","https://openalex.org/W2020572713","https://openalex.org/W2021745448","https://openalex.org/W2024646663","https://openalex.org/W2025089122","https://openalex.org/W2026959362","https://openalex.org/W2027315206","https://openalex.org/W2027671905","https://openalex.org/W2027693000","https://openalex.org/W2030477882","https://openalex.org/W2035200786","https://openalex.org/W2036118979","https://openalex.org/W2037291691","https://openalex.org/W2037409439","https://openalex.org/W2037594404","https://openalex.org/W2038595688","https://openalex.org/W2044684433","https://openalex.org/W2045463805","https://openalex.org/W2050637435","https://openalex.org/W2052997649","https://openalex.org/W2053460754","https://openalex.org/W2054880093","https://openalex.org/W2056883181","https://openalex.org/W2057777598","https://openalex.org/W2061538061","https://openalex.org/W2063373353","https://openalex.org/W2066948093","https://openalex.org/W2067017156","https://openalex.org/W2067104802","https://openalex.org/W2067416068","https://openalex.org/W2068126480","https://openalex.org/W2068880713","https://openalex.org/W2073709649","https://openalex.org/W2074591666","https://openalex.org/W2075153064","https://openalex.org/W2075534868","https://openalex.org/W2075887236","https://openalex.org/W2079731402","https://openalex.org/W2079896377","https://openalex.org/W2082488084","https://openalex.org/W2082540253","https://openalex.org/W2082895643","https://openalex.org/W2083427835","https://openalex.org/W2083703732","https://openalex.org/W2083827540","https://openalex.org/W2084525246","https://openalex.org/W2084982444","https://openalex.org/W2085268570","https://openalex.org/W2085835442","https://openalex.org/W2087512586","https://openalex.org/W2089320091","https://openalex.org/W2089338903","https://openalex.org/W2090387570","https://openalex.org/W2091218781","https://openalex.org/W2092975116","https://openalex.org/W2094090185","https://openalex.org/W2094579672","https://openalex.org/W2099805390","https://openalex.org/W2104191262","https://openalex.org/W2105760098","https://openalex.org/W2106789605","https://openalex.org/W2111954830","https://openalex.org/W2112084791","https://openalex.org/W2113087660","https://openalex.org/W2115498507","https://openalex.org/W2123760410","https://openalex.org/W2130689264","https://openalex.org/W2134398348","https://openalex.org/W2140889785","https://openalex.org/W2144866800","https://openalex.org/W2144965973","https://openalex.org/W2148383052","https://openalex.org/W2150178045","https://openalex.org/W2150583871","https://openalex.org/W2153347181","https://openalex.org/W2164202754","https://openalex.org/W2170270390","https://openalex.org/W2172345708","https://openalex.org/W2177168770","https://openalex.org/W2235059321","https://openalex.org/W2285424332","https://openalex.org/W2288621753","https://openalex.org/W2299465820","https://openalex.org/W2312624742","https://openalex.org/W2319610208","https://openalex.org/W2320087821","https://openalex.org/W2324935237","https://openalex.org/W2327099720","https://openalex.org/W2330603149","https://openalex.org/W2331468806","https://openalex.org/W2335569465","https://openalex.org/W2362867671","https://openalex.org/W2417032412","https://openalex.org/W2470070869","https://openalex.org/W2499710109","https://openalex.org/W2502441172","https://openalex.org/W2514297041","https://openalex.org/W2524510238","https://openalex.org/W2531184456","https://openalex.org/W3021566866","https://openalex.org/W3109586669","https://openalex.org/W3189617131"],"related_works":["https://openalex.org/W7154659119","https://openalex.org/W71829738","https://openalex.org/W183637771","https://openalex.org/W2969707100","https://openalex.org/W4417222709","https://openalex.org/W2164694432","https://openalex.org/W2353465952","https://openalex.org/W4292265091","https://openalex.org/W2907828784","https://openalex.org/W4416026532"],"abstract_inverted_index":{"In":[0],"this":[1,13],"work,":[2],"industrially":[3],"relevant":[4],"mechanochemical":[5],"processes":[6,36,265],"of":[7,37,48,55,68,87,126,138,163,217,226,246,261],"lignocellulosic":[8],"materials":[9,57],"were":[10,63,108,201,232],"investigated.":[11],"To":[12],"day,":[14],"mechanochemistry":[15],"remains":[16],"unknown":[17],"even":[18],"to":[19,182,203,206,234,242],"most":[20],"chemists,":[21],"and":[22,40,81,118,131,159,174,179,196,228,252],"reports":[23],"on":[24,51,306],"its":[25],"effects":[26,176],"in":[27,84,104,237,248,263,272],"the":[28,38,46,52,56,85,139,168,215,224,249,259,283],"forest":[29],"products":[30],"industry":[31],"are":[32,144,177,199],"scarce.":[33],"As":[34],"many":[35],"pulp":[39,155],"paper":[41],"sector":[42],"include":[43],"mechanical":[44,148,166,175,286],"treatments,":[45],"effect":[47],"such":[49,112,276],"treatments":[50,61],"chemical":[53],"properties":[54,107],"should":[58],"be":[59,204],"known.\u00a0\n\nThe":[60],"that":[62,142],"studied":[64,98],"herein":[65],"were:":[66],"preparation":[67,190],"nanofibrillated":[69],"cellulose":[70,212],"(NFC)":[71,336],"by":[72,191,223],"Masuko":[73],"refining,":[74],"thermomechanical":[75],"pulping":[76],"at":[77],"high":[78],"temperatures":[79],"(HT-TMP)":[80,343],"ball":[82,161],"milling":[83,162],"presence":[86,225],"a":[88,100],"reactive":[89,160],"vinyl":[90],"monomer,":[91],"namely,":[92],"styrene.":[93],"The":[94,184],"HT-TMP":[95,230],"was":[96,141,151,220],"also":[97],"as":[99,113,208,277],"potential":[101,236],"reinforcing":[102],"agent":[103],"biocomposites.":[105],"Material":[106],"characterized":[109],"with":[110],"techniques":[111],"electron":[114,133],"paramagnetic":[115],"resonance":[116,120],"(EPR)":[117,363],"ultraviolet":[119],"Raman":[121],"(UVRR)":[122,366],"spectroscopies,":[123],"optical":[124],"analysis":[125],"fiber":[127,293],"dimensions,":[128],"tensile":[129],"testing,":[130],"scanning":[132],"microscopy":[134],"(SEM).\u00a0\n\nThe":[135],"main":[136],"hypothesis":[137],"work":[140],"mechanoradicals":[143,262],"formed":[145],"upon":[146],"various":[147],"treatments.":[149],"This":[150],"confirmed":[152],"for":[153,188,211,292],"kraft":[154],"homogenization":[156],"into":[157],"NFC":[158],"cotton.":[164],"With":[165],"pulping,":[167],"situation":[169],"is":[170,266],"more":[171],"complex:":[172],"thermal":[173],"simultaneous":[178],"therefore":[180],"difficult":[181],"distinguish.":[183],"same":[185],"holds":[186],"true":[187],"composite":[189,239],"extrusion,":[192],"where":[193],"both":[194],"heating":[195],"shear":[197],"forces":[198],"present.\u00a0\n\nMechanoradicals":[200],"shown":[202,233],"able":[205],"act":[207],"starting":[209],"points":[210],"copolymerization":[213],"but":[214],"efficacy":[216],"these":[218],"reactions":[219],"greatly":[221],"affected":[222],"oxygen":[227],"water.":[229],"fibers":[231],"have":[235],"industrial":[238,264],"reinforcement":[240],"due":[241],"their":[243],"hydrophobicity,":[244],"ease":[245],"dispersion":[247],"PLA":[250],"matrix,":[251],"low":[253],"specific":[254],"energy":[255],"consumption.\u00a0\n\nIn":[256],"conclusion,":[257],"acknowledging":[258],"formation":[260],"crucial.":[267],"These":[268],"radicals":[269],"may":[270,288],"participate":[271],"unwanted":[273],"side":[274],"reactions,":[275],"oxidation":[278],"or":[279],"polymer":[280],"degradation.":[281],"On":[282],"other":[284],"hand,":[285],"processing":[287],"yield":[289],"new":[290],"avenues":[291],"modification.;":[294],"Tassa":[295],"tyossa":[296],"tarkasteltiin":[297],"teollisia":[298],"prosesseja,":[299],"joissa":[300],"lignoselluloosamateriaalit":[301],"altistuvat":[302],"mekaaniselle":[303],"rasitukselle.":[304],"Mekanokemia":[305],"viela":[307],"varsin":[308],"huonosti":[309],"tunnettu":[310],"tieteenala,":[311],"joka":[312],"tutkii":[313],"mekaanisesti":[314],"aiheutettuja":[315],"kemiallisia":[316],"muutoksia.":[317],"Koska":[318],"monet":[319],"puunjalostustekniikan":[320],"prosessit":[321],"sisaltavat":[322],"mekaanisia":[323],"kasittelyita,":[324],"niiden":[325],"vaikutukset":[326],"materiaaliominaisuuksiin":[327],"olisi":[328],"tarkeaa":[329],"tuntea.\u00a0\n\nTyossa":[330],"tutkitut":[331],"kasittelyt":[332],"olivat:":[333],"nanofibrilloidun":[334],"selluloosan":[335],"valmistaminen":[337],"Masuko-jauhatuksen":[338],"avulla,":[339],"hierteenvalmistus":[340],"korkeassa":[341],"lampotilassa":[342],"ja":[344,364],"kuulamyllyjauhatus":[345],"reaktiivisen":[346],"monomeerin":[347],"lasna":[348],"ollessa.":[349],"Myos":[350],"HT-TMP:n":[351],"potentiaalia":[352],"biokomposiittilujitteena":[353],"selvitettiin.":[354],"Tyon":[355],"keskeisia":[356],"analyysimenetelmia":[357],"olivat":[358],"muun":[359],"muassa":[360],"elektroniparamagneettinen":[361],"resonanssi":[362],"ultraviolettiresonanssiraman":[365],"-spektroskopiat,":[367],"kuitudimensioiden":[368],"optinen":[369],"analyysi,":[370],"vetokokeet":[371],"seka":[372],"pyyhkaisyelektronimikroskopia":[373],"(SEM).\u00a0\n\nKeskeisena\u2026":[374]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}