{"id":"https://openalex.org/W2167327772","doi":"https://doi.org/10.1080/00397911.2013.839796","title":"Synthesis of N,N-Diethylbenzamides via a Nonclassical Mitsunobu Reaction","display_name":"Synthesis of N,N-Diethylbenzamides via a Nonclassical Mitsunobu Reaction","publication_year":2013,"publication_date":"2013-11-08","ids":{"openalex":"https://openalex.org/W2167327772","doi":"https://doi.org/10.1080/00397911.2013.839796","mag":"2167327772","pmid":"https://pubmed.ncbi.nlm.nih.gov/25221359","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/4159177"},"language":"en","primary_location":{"id":"doi:10.1080/00397911.2013.839796","doi":"https://doi.org/10.1080/00397911.2013.839796","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00397911.2013.839796","pdf_url":null,"source":{"id":"https://openalex.org/S114976158","display_name":"Synthetic Communications","issn_l":"0039-7911","issn":["0039-7911","1532-2432"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthetic Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4159177","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"J. Mason Hoffman","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145423581","display_name":"Sewanee: The University of the South","ror":"https://ror.org/05r5k8873","country_code":"US","type":"education","lineage":["https://openalex.org/I145423581"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"J. Mason Hoffman","raw_affiliation_strings":["a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","institution_ids":["https://openalex.org/I145423581"]},{"raw_affiliation_string":"Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA","institution_ids":["https://openalex.org/I145423581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038817457","display_name":"Justin N. Miller","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145423581","display_name":"Sewanee: The University of the South","ror":"https://ror.org/05r5k8873","country_code":"US","type":"education","lineage":["https://openalex.org/I145423581"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Justin N. Miller","raw_affiliation_strings":["a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","institution_ids":["https://openalex.org/I145423581"]},{"raw_affiliation_string":"Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA","institution_ids":["https://openalex.org/I145423581"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Margaret E. Gardner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145423581","display_name":"Sewanee: The University of the South","ror":"https://ror.org/05r5k8873","country_code":"US","type":"education","lineage":["https://openalex.org/I145423581"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Margaret E. Gardner","raw_affiliation_strings":["a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","institution_ids":["https://openalex.org/I145423581"]},{"raw_affiliation_string":"Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA","institution_ids":["https://openalex.org/I145423581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046981271","display_name":"Danielle R. LePar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189774192","display_name":"Colorado College","ror":"https://ror.org/03tg3h819","country_code":"US","type":"education","lineage":["https://openalex.org/I189774192"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Danielle R. LePar","raw_affiliation_strings":["b   Department of Chemistry and Biochemistry , Colorado College ,  Colorado Springs ,  Colorado ,  USA","Department of Chemistry and Biochemistry , Colorado College , Colorado Springs , Colorado , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"b   Department of Chemistry and Biochemistry , Colorado College ,  Colorado Springs ,  Colorado ,  USA","institution_ids":["https://openalex.org/I189774192"]},{"raw_affiliation_string":"Department of Chemistry and Biochemistry , Colorado College , Colorado Springs , Colorado , USA","institution_ids":["https://openalex.org/I189774192"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010014073","display_name":"Rongson Pongdee","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145423581","display_name":"Sewanee: The University of the South","ror":"https://ror.org/05r5k8873","country_code":"US","type":"education","lineage":["https://openalex.org/I145423581"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Rongson Pongdee","raw_affiliation_strings":["a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Chemistry , Sewanee: The University of the South ,  Sewanee ,  Tennessee ,  USA","institution_ids":["https://openalex.org/I145423581"]},{"raw_affiliation_string":"Department of Chemistry , Sewanee: The University of the South , Sewanee , Tennessee , USA","institution_ids":["https://openalex.org/I145423581"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5010014073"],"corresponding_institution_ids":["https://openalex.org/I145423581"],"apc_list":null,"apc_paid":null,"fwci":0.281,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.5307718,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"44","issue":"7","first_page":"976","last_page":"980"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.6205999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.6205999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.10459999740123749,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.07039999961853027,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/mitsunobu-reaction","display_name":"Mitsunobu reaction","score":0.9800000190734863},{"id":"https://openalex.org/keywords/benzamide-synthesis","display_name":"benzamide synthesis","score":0.8610000014305115},{"id":"https://openalex.org/keywords/benzoic-acid","display_name":"benzoic acid","score":0.890999972820282},{"id":"https://openalex.org/keywords/amines","display_name":"amines","score":0.828000009059906},{"id":"https://openalex.org/keywords/electron-donating-and-electron-withdrawing-substituents","display_name":"electron-donating and electron-withdrawing substituents","score":0.9070000052452087}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9361216425895691},{"id":"https://openalex.org/C2779377163","wikidata":"https://www.wikidata.org/wiki/Q899062","display_name":"Mitsunobu reaction","level":2,"score":0.9321150779724121},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.6583887338638306},{"id":"https://openalex.org/C2778844314","wikidata":"https://www.wikidata.org/wiki/Q191700","display_name":"Benzoic acid","level":2,"score":0.6546845436096191},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5885820388793945},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.38028979301452637}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1080/00397911.2013.839796","doi":"https://doi.org/10.1080/00397911.2013.839796","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00397911.2013.839796","pdf_url":null,"source":{"id":"https://openalex.org/S114976158","display_name":"Synthetic Communications","issn_l":"0039-7911","issn":["0039-7911","1532-2432"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthetic Communications","raw_type":"journal-article"},{"id":"pmid:25221359","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/25221359","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthetic communications","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:4159177","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4159177","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Synth Commun","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:4159177","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4159177","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Synth Commun","raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6262958996","display_name":"Glycodiversification of Angucycline Antibiotics","funder_award_id":"R15AI084075","funder_id":"https://openalex.org/F4320337355","funder_display_name":"National Institute of Allergy and Infectious Diseases"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320310260","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43"},{"id":"https://openalex.org/F4320332454","display_name":"American Chemical Society Petroleum Research Fund","ror":"https://ror.org/059dqb057"},{"id":"https://openalex.org/F4320337355","display_name":"National Institute of Allergy and Infectious Diseases","ror":"https://ror.org/043z4tv69"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":5,"referenced_works":["https://openalex.org/W1983357954","https://openalex.org/W1988255962","https://openalex.org/W2066853713","https://openalex.org/W2081373871","https://openalex.org/W2952911490"],"related_works":["https://openalex.org/W2952085351","https://openalex.org/W2949274746","https://openalex.org/W2950962332","https://openalex.org/W2127530461","https://openalex.org/W2046713991","https://openalex.org/W2030340541","https://openalex.org/W2004063976","https://openalex.org/W2332402159","https://openalex.org/W2951787413","https://openalex.org/W2951016465"],"abstract_inverted_index":{"The":[0],"use":[1],"of":[2,9,26,44,51,75,92],"the":[3,7,24,35,41,45,49,73,88,96],"Mitsunobu":[4,36,46],"reaction":[5,47],"for":[6,48,83,95],"synthesis":[8],"N,N-diethylbenzamides":[10],"affords":[11],"ortho-,":[12],"meta-,":[13],"and":[14,20,56,103],"para-substituted":[15],"benzamides":[16,52],"containing":[17],"both":[18],"electron-donating":[19],"electron-withdrawing":[21],"groups.":[22],"While":[23],"preparation":[25],"numerous":[27],"functional":[28],"groups":[29],"has":[30],"been":[31],"efficiently":[32],"demonstrated":[33],"employing":[34],"reaction,":[37],"our":[38],"methodology":[39],"represents":[40],"first":[42],"application":[43],"construction":[50],"using":[53],"benzoic":[54],"acid":[55],"amine":[57],"starting":[58],"materials.":[59],"Moreover,":[60],"this":[61,84],"synthetic":[62],"transformation":[63],"is":[64],"believed":[65],"to":[66,87],"proceed":[67],"via":[68],"a":[69],"nonclassical":[70],"mechanism":[71],"involving":[72],"existence":[74],"an":[76],"acyloxyphosphonium":[77],"ion.":[78],"[Supplementary":[79],"materials":[80],"are":[81],"available":[82],"article.":[85],"Go":[86],"publisher's":[89],"online":[90],"edition":[91],"Synthetic":[93],"Communications\u00ae":[94],"following":[97],"free":[98],"supplemental":[99],"resource(s):":[100],"Full":[101],"experimental":[102],"spectral":[104],"details.]":[105]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}
