{"id":"https://openalex.org/W2166139511","doi":"https://doi.org/10.1021/es404453v","title":"Kinetics and Mechanism of \u2022OH Mediated Degradation of Dimethyl Phthalate in Aqueous Solution: Experimental and Theoretical Studies","display_name":"Kinetics and Mechanism of \u2022OH Mediated Degradation of Dimethyl Phthalate in Aqueous Solution: Experimental and Theoretical Studies","publication_year":2013,"publication_date":"2013-12-10","ids":{"openalex":"https://openalex.org/W2166139511","doi":"https://doi.org/10.1021/es404453v","mag":"2166139511","pmid":"https://pubmed.ncbi.nlm.nih.gov/24364419"},"language":"en","primary_location":{"id":"doi:10.1021/es404453v","doi":"https://doi.org/10.1021/es404453v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/es404453v","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science & Technology","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2166139511"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5062231268","display_name":"Taicheng An","orcid":"https://orcid.org/0000-0001-6918-8070","observed_orcids":["https://orcid.org/0000-0001-6918-8070"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I3018690959","display_name":"Guangzhou Institute of Geochemistry","ror":"https://ror.org/0356cst02","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959"]},{"id":"https://openalex.org/I4391768186","display_name":"State Key Laboratory of Organic Geochemistry","ror":"https://ror.org/00x9tpk83","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Taicheng An","raw_affiliation_strings":["State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058149622","display_name":"Yanpeng Gao","orcid":"https://orcid.org/0000-0003-2156-8167","observed_orcids":["https://orcid.org/0000-0003-2156-8167"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I3018690959","display_name":"Guangzhou Institute of Geochemistry","ror":"https://ror.org/0356cst02","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]},{"id":"https://openalex.org/I4391768186","display_name":"State Key Laboratory of Organic Geochemistry","ror":"https://ror.org/00x9tpk83","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yanpeng Gao","raw_affiliation_strings":["State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China","University of Chinese Academy of Sciences, Beijing 100049, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences, Beijing 100049, People\u2019s Republic of China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057631131","display_name":"Guiying Li","orcid":"https://orcid.org/0000-0002-6777-4786","observed_orcids":["https://orcid.org/0000-0002-6777-4786","https://orcid.org/0000-0003-0299-1349"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I3018690959","display_name":"Guangzhou Institute of Geochemistry","ror":"https://ror.org/0356cst02","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959"]},{"id":"https://openalex.org/I4391768186","display_name":"State Key Laboratory of Organic Geochemistry","ror":"https://ror.org/00x9tpk83","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Guiying Li","raw_affiliation_strings":["State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State\rKey Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People\u2019s Republic of China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061425161","display_name":"Prashant V. Kamat","orcid":"https://orcid.org/0000-0002-2465-6819","observed_orcids":["https://orcid.org/0000-0002-2465-6819","https://orcid.org/0000-0001-7715-3396"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Prashant V. Kamat","raw_affiliation_strings":["\u00a7 Radiation Laboratory and \u2225 Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u00a7 Radiation Laboratory and \u2225 Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001157449","display_name":"Julie R. Peller","orcid":"https://orcid.org/0000-0002-0884-3825","observed_orcids":["https://orcid.org/0000-0002-0884-3825"]},"institutions":[{"id":"https://openalex.org/I4210093298","display_name":"Indiana University Northwest","ror":"https://ror.org/00n9fkm63","country_code":"US","type":"education","lineage":["https://openalex.org/I4210093298","https://openalex.org/I592451"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Julie Peller","raw_affiliation_strings":["Department\rof Chemistry, Indiana University-Northwest, Gary, Indiana 46408, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Indiana University-Northwest, Gary, Indiana 46408, United States","institution_ids":["https://openalex.org/I4210093298"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5046217936","display_name":"Michelle V. Joyce","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michelle V. Joyce","raw_affiliation_strings":["\u00a7 Radiation Laboratory and \u2225 Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u00a7 Radiation Laboratory and \u2225 Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556","institution_ids":["https://openalex.org/I107639228"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5061425161","https://openalex.org/A5062231268"],"corresponding_institution_ids":["https://openalex.org/I107639228","https://openalex.org/I19820366","https://openalex.org/I3018690959","https://openalex.org/I4391768186"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":6.3056,"has_fulltext":false,"cited_by_count":188,"citation_normalized_percentile":{"value":0.96029858,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"48","issue":"1","first_page":"641","last_page":"648"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydroxyl-radicals","display_name":"hydroxyl radicals","score":0.9369999766349792},{"id":"https://openalex.org/keywords/dimethyl-phthalate","display_name":"dimethyl phthalate","score":0.9990000128746033},{"id":"https://openalex.org/keywords/advanced-oxidation-processes","display_name":"advanced oxidation processes","score":0.8859999775886536},{"id":"https://openalex.org/keywords/endocrine-disruptors","display_name":"endocrine disruptors","score":0.7960000038146973},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.6460000276565552},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7950000166893005},{"id":"https://openalex.org/keywords/hydrogen-atom-transfer","display_name":"hydrogen atom transfer","score":0.8059999942779541},{"id":"https://openalex.org/keywords/single-electron-transfer","display_name":"single electron transfer","score":0.875},{"id":"https://openalex.org/keywords/radical-adduct-formation","display_name":"radical adduct formation","score":0.9440000057220459},{"id":"https://openalex.org/keywords/radical-intermediates","display_name":"radical intermediates","score":0.7739999890327454},{"id":"https://openalex.org/keywords/radiolysis","display_name":"radiolysis","score":0.699999988079071},{"id":"https://openalex.org/keywords/aqueous-degradation","display_name":"aqueous degradation","score":0.4950000047683716},{"id":"https://openalex.org/keywords/phthalate-metabolites","display_name":"phthalate metabolites","score":0.5820000171661377}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8637434244155884},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.7353873252868652},{"id":"https://openalex.org/C2779217394","wikidata":"https://www.wikidata.org/wiki/Q423551","display_name":"Dimethyl phthalate","level":3,"score":0.7217307090759277},{"id":"https://openalex.org/C66887884","wikidata":"https://www.wikidata.org/wiki/Q2126498","display_name":"Radiolysis","level":3,"score":0.7101994156837463},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.6920742392539978},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.6510095596313477},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6463462114334106},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.6144134402275085},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5570110082626343},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.5454457998275757},{"id":"https://openalex.org/C2776778087","wikidata":"https://www.wikidata.org/wiki/Q427071","display_name":"Hydroxyl radical","level":3,"score":0.5187516212463379},{"id":"https://openalex.org/C36663273","wikidata":"https://www.wikidata.org/wiki/Q209082","display_name":"Chemical kinetics","level":3,"score":0.5050557255744934},{"id":"https://openalex.org/C2776640939","wikidata":"https://www.wikidata.org/wiki/Q6643508","display_name":"Hydrogen atom","level":3,"score":0.49816441535949707},{"id":"https://openalex.org/C192937433","wikidata":"https://www.wikidata.org/wiki/Q2134627","display_name":"Reactive intermediate","level":3,"score":0.4700153172016144},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.46595320105552673},{"id":"https://openalex.org/C2781005124","wikidata":"https://www.wikidata.org/wiki/Q84483575","display_name":"Phthalate","level":2,"score":0.4449477195739746},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.42495328187942505},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.20800074934959412},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.20055308938026428},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.14907047152519226},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.09505176544189453},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D004579","descriptor_name":"Electron Transport","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D006859","descriptor_name":"Hydrogen","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D006863","descriptor_name":"Hydrogen-Ion Concentration","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008962","descriptor_name":"Models, Theoretical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010795","descriptor_name":"Phthalic Acids","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D011789","descriptor_name":"Quantum Theory","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012996","descriptor_name":"Solutions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D017665","descriptor_name":"Hydroxyl Radical","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":3,"locations":[{"id":"doi:10.1021/es404453v","doi":"https://doi.org/10.1021/es404453v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/es404453v","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science & Technology","raw_type":"journal-article"},{"id":"pmid:24364419","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24364419","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental science & technology","raw_type":"Journal Article"},{"id":"pmh:oai:ir.gig.ac.cn:344008/29498","doi":null,"is_oa":false,"landing_page_url":"http://ir.gig.ac.cn:8080/handle/344008/29498","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"\u671f\u520a\u8bba\u6587"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W1926950498","https://openalex.org/W1968510197","https://openalex.org/W1972649476","https://openalex.org/W1979424160","https://openalex.org/W1980590990","https://openalex.org/W1983228601","https://openalex.org/W1984045894","https://openalex.org/W1985081214","https://openalex.org/W1987695378","https://openalex.org/W1997004166","https://openalex.org/W1997151511","https://openalex.org/W1998607250","https://openalex.org/W2000485664","https://openalex.org/W2000930279","https://openalex.org/W2006032905","https://openalex.org/W2006601958","https://openalex.org/W2007109646","https://openalex.org/W2007748053","https://openalex.org/W2007937449","https://openalex.org/W2011684291","https://openalex.org/W2014925765","https://openalex.org/W2015806352","https://openalex.org/W2020716716","https://openalex.org/W2035933212","https://openalex.org/W2038260821","https://openalex.org/W2038797702","https://openalex.org/W2040631744","https://openalex.org/W2045721059","https://openalex.org/W2046241019","https://openalex.org/W2046671197","https://openalex.org/W2047372422","https://openalex.org/W2050217899","https://openalex.org/W2058121027","https://openalex.org/W2058848030","https://openalex.org/W2060931675","https://openalex.org/W2062589868","https://openalex.org/W2065576664","https://openalex.org/W2067074619","https://openalex.org/W2068119928","https://openalex.org/W2070464377","https://openalex.org/W2072513400","https://openalex.org/W2072786805","https://openalex.org/W2073138845","https://openalex.org/W2087644524","https://openalex.org/W2094575727","https://openalex.org/W2169829476","https://openalex.org/W2315008872","https://openalex.org/W2327783583","https://openalex.org/W2334628748","https://openalex.org/W2569960672","https://openalex.org/W2949633926","https://openalex.org/W3024591562","https://openalex.org/W4248195393"],"related_works":["https://openalex.org/W2016439750","https://openalex.org/W2047372422","https://openalex.org/W7204526404","https://openalex.org/W1982159718","https://openalex.org/W2777209426","https://openalex.org/W2061724932","https://openalex.org/W2020613347","https://openalex.org/W2887835217","https://openalex.org/W1968510197"],"abstract_inverted_index":{"The":[0,65,85],"hydroxyl":[1],"radical":[2,90,162],"((\u2022)OH)":[3],"is":[4],"one":[5],"of":[6,32,43,47,89,147,181,184],"the":[7,28,39,48,70,107,112,119,124,145,179],"main":[8],"oxidative":[9],"species":[10,149],"in":[11,34,188],"aqueous":[12],"phase":[13],"advanced":[14],"oxidation":[15],"processes,":[16],"and":[17,30,41,62,98,121,128,132,158,160,170,174],"its":[18],"initial":[19],"reactions":[20],"with":[21,73,111,150],"organic":[22],"pollutants":[23],"are":[24,186],"important":[25],"to":[26,77,166],"understand":[27],"transformation":[29],"fate":[31],"organics":[33],"water":[35],"environments.":[36],"Insights":[37],"into":[38],"kinetics":[40],"mechanism":[42,180],"(\u2022)OH":[44,71],"mediated":[45],"degradation":[46,183],"model":[49],"environmental":[50],"endocrine":[51],"disruptor,":[52],"dimethyl":[53,168],"phthalate":[54],"(DMP),":[55],"have":[56],"been":[57],"obtained":[58],"using":[59],"radiolysis":[60],"experiments":[61],"computational":[63,113,175],"methods.":[64],"bimolecular":[66],"rate":[67],"constant":[68],"for":[69],"reaction":[72,87,126],"DMP":[74,185],"was":[75,116],"determined":[76],"be":[78],"(3.2":[79],"\u00b1":[80],"0.1)":[81],"\u00d7":[82],"10(9)":[83],"M(-1)s(-1).":[84],"possible":[86],"mechanisms":[88],"adduct":[91],"formation":[92],"(RAF),":[93],"hydrogen":[94],"atom":[95],"transfer":[96,101],"(HAT),":[97],"single":[99],"electron":[100],"(SET)":[102],"were":[103,123,137],"considered.":[104],"By":[105],"comparing":[106],"experimental":[108],"absorption":[109,152],"spectra":[110],"results,":[114],"it":[115],"concluded":[117],"that":[118],"RAF":[120],"HAT":[122],"dominant":[125],"pathways,":[127],"OH-adducts":[129],"((\u2022)DMPOH1,":[130],"(\u2022)DMPOH2)":[131],"methyl":[133],"type":[134],"radicals":[135],"(\u2022)DMP(-H)\u03b1":[136],"identified":[138],"as":[139,156],"dominated":[140],"intermediates.":[141],"Computational":[142],"results":[143],"confirmed":[144],"identification":[146],"transient":[148],"maximum":[151],"around":[153],"260":[154],"nm":[155],"(\u2022)DMPOH1":[157],"(\u2022)DMP(-H)\u03b1,":[159],"these":[161],"intermediates":[163],"then":[164],"converted":[165],"monohydroxylated":[167],"phthalates":[169],"monomethyl":[171],"phthalates.":[172],"Experimental":[173],"analyses":[176],"which":[177],"elucidated":[178],"(\u2022)OH-mediated":[182],"discussed":[187],"detail.":[189]},"counts_by_year":[{"year":2026,"cited_by_count":8},{"year":2025,"cited_by_count":20},{"year":2024,"cited_by_count":18},{"year":2023,"cited_by_count":9},{"year":2022,"cited_by_count":19},{"year":2021,"cited_by_count":23},{"year":2020,"cited_by_count":14},{"year":2019,"cited_by_count":19},{"year":2018,"cited_by_count":20},{"year":2017,"cited_by_count":13},{"year":2016,"cited_by_count":13},{"year":2015,"cited_by_count":9},{"year":2014,"cited_by_count":3}],"updated_date":"2026-11-14T11:04:58.165337","created_date":"2016-06-24T00:00:00"}