{"id":"https://openalex.org/W2166079748","doi":null,"title":"Biochemical Control Aspects in Lignin Polymerization","display_name":"Biochemical Control Aspects in Lignin Polymerization","publication_year":2008,"publication_date":"2008-01-01","ids":{"openalex":"https://openalex.org/W2166079748","mag":"2166079748"},"language":"en","primary_location":{"id":"pmh:oai:DiVA.org:kth-4632","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4632","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4632","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089369914","display_name":"Anders Holmgren","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Anders Holmgren","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5089369914"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12360","display_name":"Plant-derived Lignans Synthesis and Bioactivity","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10869","display_name":"Polysaccharides and Plant Cell Walls","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1110","display_name":"Plant Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lignin-polymerization","display_name":"lignin polymerization","score":0.9660000205039978},{"id":"https://openalex.org/keywords/coniferyl-alcohol","display_name":"coniferyl alcohol","score":0.9190000295639038},{"id":"https://openalex.org/keywords/nadh-reduction","display_name":"NADH reduction","score":0.8569999933242798},{"id":"https://openalex.org/keywords/quinone-methides","display_name":"quinone methides","score":0.9049999713897705},{"id":"https://openalex.org/keywords/vitamin-c","display_name":"vitamin C","score":0.9300000071525574},{"id":"https://openalex.org/keywords/template-replication","display_name":"template replication","score":0.8629999756813049},{"id":"https://openalex.org/keywords/oxidative-polymerization","display_name":"oxidative polymerization","score":0.6919999718666077},{"id":"https://openalex.org/keywords/plant-cell-wall","display_name":"plant cell wall","score":0.6610000133514404}],"concepts":[{"id":"https://openalex.org/C2781052789","wikidata":"https://www.wikidata.org/wiki/Q184817","display_name":"Lignin","level":2,"score":0.8985722064971924},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.6388053297996521},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5785676836967468},{"id":"https://openalex.org/C126348684","wikidata":"https://www.wikidata.org/wiki/Q3456979","display_name":"Polymer science","level":1,"score":0.48504871129989624},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4737432897090912},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.4233849346637726},{"id":"https://openalex.org/C528095902","wikidata":"https://www.wikidata.org/wiki/Q2283886","display_name":"Pulp and paper industry","level":1,"score":0.3270958662033081},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.10205510258674622}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:DiVA.org:kth-4632","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4632","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},{"id":"mag:2166079748","doi":null,"is_oa":false,"landing_page_url":"http://kth.diva-portal.org/smash/get/diva2:13165/FULLTEXT01","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:DiVA.org:kth-4632","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4632","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":176,"referenced_works":["https://openalex.org/W10906115","https://openalex.org/W88383001","https://openalex.org/W120142031","https://openalex.org/W187300608","https://openalex.org/W202755166","https://openalex.org/W253999417","https://openalex.org/W288019165","https://openalex.org/W317341159","https://openalex.org/W567794605","https://openalex.org/W572029945","https://openalex.org/W588726511","https://openalex.org/W590819320","https://openalex.org/W616561675","https://openalex.org/W644108408","https://openalex.org/W1518419994","https://openalex.org/W1520579393","https://openalex.org/W1528433521","https://openalex.org/W1535216236","https://openalex.org/W1544972362","https://openalex.org/W1586033428","https://openalex.org/W1601236454","https://openalex.org/W1604444688","https://openalex.org/W1663995113","https://openalex.org/W1764124879","https://openalex.org/W1856292497","https://openalex.org/W1905439276","https://openalex.org/W1923798867","https://openalex.org/W1963589524","https://openalex.org/W1964203538","https://openalex.org/W1970096582","https://openalex.org/W1970657129","https://openalex.org/W1971840412","https://openalex.org/W1972490143","https://openalex.org/W1976693180","https://openalex.org/W1977005480","https://openalex.org/W1977547028","https://openalex.org/W1978113247","https://openalex.org/W1979276428","https://openalex.org/W1979714796","https://openalex.org/W1979846873","https://openalex.org/W1980887888","https://openalex.org/W1981688539","https://openalex.org/W1982462050","https://openalex.org/W1989692903","https://openalex.org/W1991509281","https://openalex.org/W1992018680","https://openalex.org/W1992152869","https://openalex.org/W1994454569","https://openalex.org/W1994608297","https://openalex.org/W1996545111","https://openalex.org/W1997065261","https://openalex.org/W1997429178","https://openalex.org/W1997595207","https://openalex.org/W1998221419","https://openalex.org/W2000213969","https://openalex.org/W2000382572","https://openalex.org/W2000895924","https://openalex.org/W2001837563","https://openalex.org/W2002422457","https://openalex.org/W2003153091","https://openalex.org/W2005095742","https://openalex.org/W2006344126","https://openalex.org/W2007843757","https://openalex.org/W2007945940","https://openalex.org/W2009400851","https://openalex.org/W2011598521","https://openalex.org/W2011908511","https://openalex.org/W2012622798","https://openalex.org/W2015611405","https://openalex.org/W2015766955","https://openalex.org/W2016487370","https://openalex.org/W2017971648","https://openalex.org/W2018342353","https://openalex.org/W2018863705","https://openalex.org/W2022168386","https://openalex.org/W2023343774","https://openalex.org/W2025889679","https://openalex.org/W2026912030","https://openalex.org/W2028722917","https://openalex.org/W2030477882","https://openalex.org/W2032838022","https://openalex.org/W2034560292","https://openalex.org/W2035332838","https://openalex.org/W2036120920","https://openalex.org/W2037683681","https://openalex.org/W2039729590","https://openalex.org/W2039945299","https://openalex.org/W2040777717","https://openalex.org/W2040891760","https://openalex.org/W2041541259","https://openalex.org/W2041751395","https://openalex.org/W2043236213","https://openalex.org/W2045106068","https://openalex.org/W2045386005","https://openalex.org/W2046379393","https://openalex.org/W2047402380","https://openalex.org/W2047450650","https://openalex.org/W2047956990","https://openalex.org/W2048777315","https://openalex.org/W2049657685","https://openalex.org/W2049886417","https://openalex.org/W2050898579","https://openalex.org/W2051263055","https://openalex.org/W2051731525","https://openalex.org/W2054216679","https://openalex.org/W2055570394","https://openalex.org/W2058234135","https://openalex.org/W2060496678","https://openalex.org/W2061896876","https://openalex.org/W2062759615","https://openalex.org/W2063907872","https://openalex.org/W2065089449","https://openalex.org/W2066086770","https://openalex.org/W2068429429","https://openalex.org/W2068499174","https://openalex.org/W2068780447","https://openalex.org/W2068892033","https://openalex.org/W2069044861","https://openalex.org/W2069646624","https://openalex.org/W2069885948","https://openalex.org/W2071237233","https://openalex.org/W2071268213","https://openalex.org/W2073306116","https://openalex.org/W2073335323","https://openalex.org/W2075132729","https://openalex.org/W2076930894","https://openalex.org/W2078184188","https://openalex.org/W2079202153","https://openalex.org/W2084262561","https://openalex.org/W2089703720","https://openalex.org/W2091757437","https://openalex.org/W2092005716","https://openalex.org/W2093869538","https://openalex.org/W2097201336","https://openalex.org/W2103817355","https://openalex.org/W2111869260","https://openalex.org/W2115584603","https://openalex.org/W2116483693","https://openalex.org/W2117802513","https://openalex.org/W2117863422","https://openalex.org/W2118255900","https://openalex.org/W2119273703","https://openalex.org/W2119627204","https://openalex.org/W2124336201","https://openalex.org/W2124794412","https://openalex.org/W2126362663","https://openalex.org/W2142141193","https://openalex.org/W2143714047","https://openalex.org/W2144054096","https://openalex.org/W2145259682","https://openalex.org/W2151224126","https://openalex.org/W2151335336","https://openalex.org/W2151689745","https://openalex.org/W2156191061","https://openalex.org/W2157827172","https://openalex.org/W2159806517","https://openalex.org/W2159877029","https://openalex.org/W2164189900","https://openalex.org/W2164970044","https://openalex.org/W2166258467","https://openalex.org/W2167917952","https://openalex.org/W2170535676","https://openalex.org/W2172180830","https://openalex.org/W2295484071","https://openalex.org/W2314820192","https://openalex.org/W2386651037","https://openalex.org/W2419040201","https://openalex.org/W2477337669","https://openalex.org/W2477418214","https://openalex.org/W2500784508","https://openalex.org/W2503858660","https://openalex.org/W2781334083","https://openalex.org/W2797816625","https://openalex.org/W2883522783","https://openalex.org/W2949066018","https://openalex.org/W2974878106"],"related_works":["https://openalex.org/W223146408","https://openalex.org/W7099784896","https://openalex.org/W2085597750","https://openalex.org/W4377600383","https://openalex.org/W1927036866","https://openalex.org/W2122393773","https://openalex.org/W1995862181","https://openalex.org/W7100938477","https://openalex.org/W2012512188","https://openalex.org/W4414151020"],"abstract_inverted_index":{"Lignins":[0],"are":[1,93,247,295,440,488,493],"produced":[2,149,221,335,376,400],"by":[3,38,137,280,321,377],"all":[4,485,498],"vascular":[5],"plants":[6],"and":[7,44,109,134,405,416,423,432,448,490,505],"they":[8],"represent":[9],"one":[10],"of":[11,16,26,32,41,49,58,68,100,107,163,195,228,264,285,291,327,339,359,389,438,459,463,471,484],"the":[12,30,39,53,61,75,96,117,120,142,180,188,193,226,250,282,302,314,325,336,347,357,360,378,394,406,420,457,469,472,478],"most":[13],"abundant":[14],"groups":[15,387],"biopolymers":[17],"in":[18,52,141,160,169,179,225,249,289,298,324,365,414,443,507],"nature.":[19,508],"Lignin":[20],"chemistry":[21],"research,":[22],"which":[23,205,294,384,439],"has":[24,35,132],"been":[25,36],"great":[27],"importance":[28],"for":[29,63,87,129,306,316,456],"progress":[31],"pulping":[33],"technologies,":[34],"plagued":[37],"difficulties":[40],"its":[42,277],"isolation":[43],"characterization.":[45],"The":[46,333,481],"pioneering":[47],"work":[48,73],"Karl":[50],"Freudenberg":[51],"1950\u2019s":[54],"with":[55,74,401],"synthetic":[56],"models":[57],"lignin":[59,70,91,101,130,158,185,211,245,307,311,366,396,464,503],"paved":[60],"way":[62],"a":[64,85,124,138,156,161,201,268,328,343],"detailed":[65],"structural":[66,105],"characterization":[67],"many":[69],"substructures.":[71],"His":[72],"so-called":[76],"\u201csynthetic":[77],"lignins\u201d":[78],"or":[79],"dehydrogenative":[80,446],"polymers":[81,373,425,447],"(DHP)":[82],"also":[83,260],"laid":[84],"foundation":[86],"understanding":[88],"how":[89,173,243,497],"different":[90,127,174,270],"substructures":[92,341,431],"formed,":[94],"reinforcing":[95],"already":[97],"existing":[98],"theory":[99,115],"polymerization.":[102],"However,":[103],"subsequent":[104],"characterizations":[106],"DHPs":[108,147,323,334],"lignins":[110,399],"have":[111,453],"repeatedly":[112],"put":[113],"this":[114,145],"to":[116,171,276,495],"test.":[118],"In":[119,144,192],"past":[121],"decade,":[122],"even":[123],"new":[125,303],"radically":[126],"hypothesis":[128],"polymerization":[131,504],"emerged":[133],"is":[135,206],"sustained":[136],"few":[139,434],"researchers":[140],"field.":[143],"work,":[146],"were":[148],"from":[150],"phenolic":[151],"monomers,":[152],"mostly":[153],"coniferyl":[154,409,444],"alcohol,":[155,410],"common":[157,395,442],"monomer,":[159],"variety":[162],"reaction":[164],"conditions.":[165],"This":[166,451],"was":[167,213,220,259,319,368,475],"done":[168],"order":[170],"establish":[172],"chemical":[175,415],"factors,":[176],"potentially":[177],"active":[178],"plant":[181,251],"cell":[182,252],"wall":[183],"during":[184,210,222,238,262],"polymerization,":[186,212,240,308,367],"influence":[187],"polymer\u2019s":[189],"final":[190,283],"properties.":[191,418],"presence":[194,227,326],"nicotine":[196],"amide":[197],"adenine":[198],"dinucleotide":[199],"(NADH),":[200],"quinone":[202],"methide":[203],"model,":[204],"an":[207,390,460],"intermediate":[208],"formed":[209,248],"effectively":[214],"reduced.":[215],"An":[216],"equivalent":[217],"reduced":[218,244],"structure":[219,506],"DHP":[223],"synthesis":[224,263,345],"NADH.":[229],"These":[230],"studies":[231],"showed":[232],"that":[233,310,351],"reduction":[234],"might":[235,501],"take":[236],"place":[237],"oxidative":[239],"possibly":[241],"explaining":[242],"structures":[246],"wall.":[253],"Another":[254],"reductive":[255],"agent,":[256],"ascorbic":[257],"acid,":[258,403],"tested":[261,320],"DHPs.":[265],"It":[266],"displayed":[267,411],"totally":[269],"effect":[271],"than":[272,477],"NADH,":[273],"probably":[274],"due":[275],"anti-oxidant":[278],"nature,":[279],"altering":[281],"amounts":[284,338],"certain":[286],"inter-unit":[287,430],"substructures,":[288],"favour":[290],"\u03b2-O-4\u2032":[292],"structures,":[293,436],"so":[296],"prominent":[297],"natural":[299,449],"lignins.":[300,450],"Furthermore,":[301],"suggested":[304],"model":[305,348],"stating":[309],"itself":[312],"possesses":[313],"ability":[315],"template":[317],"replication,":[318],"synthesizing":[322],"simple":[329],"\u03b2-\u03b2\u2032":[330,340],"substructure":[331],"model.":[332],"same":[337],"as":[342],"control":[344],"without":[346],"structure,":[349],"indicating":[350],"no":[352,428],"replication":[353],"had":[354],"occurred.":[355],"Finally,":[356],"role":[358],"monolignol":[361,381],"\u03b3-carbon":[362],"oxidation":[363],"state":[364],"studied.":[369],"Hypothetically,":[370],"lignin-":[371],"like":[372,393],"could":[374,452],"be":[375],"plant,":[379],"using":[380],"biosynthetic":[382],"precursors":[383],"exhibit":[385],"\u03b3-carbonyl":[386],"instead":[388],"alcohol":[391,445],"group,":[392],"monomer.":[397],"Synthetic":[398],"ferulic":[402,421],"coniferaldehyde":[404,424],"normal":[407],"monolignol,":[408],"important":[412,461],"differences":[413],"physical":[417],"Both":[419],"acid":[422],"exhibited":[426],"almost":[427],"saturated":[429],"very":[433,441],"cyclic":[435],"both":[437],"significant":[454],"implications":[455,483],"formation":[458],"type":[462],"carbohydrate":[465],"complexes":[466],"(LCC).":[467],"Also":[468],"hydrophobicity":[470],"alcohol-type":[473],"polymer":[474],"lower":[476],"other":[479],"two.":[480],"biological":[482],"these":[486,499],"findings":[487],"discussed":[489],"some":[491],"suggestions":[492],"made":[494],"explain":[496],"factors":[500],"affect":[502]},"counts_by_year":[{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-08-13T07:04:57.449891","created_date":"2016-06-24T00:00:00"}