{"id":"https://openalex.org/W2165097359","doi":"https://doi.org/10.1039/c3dt32865a","title":"X-ray transient absorption structural characterization of the 3MLCT triplet excited state of cis-[Ru(bpy)2(py)2]2+","display_name":"X-ray transient absorption structural characterization of the 3MLCT triplet excited state of cis-[Ru(bpy)2(py)2]2+","publication_year":2013,"publication_date":"2013-01-01","ids":{"openalex":"https://openalex.org/W2165097359","doi":"https://doi.org/10.1039/c3dt32865a","mag":"2165097359","pmid":"https://pubmed.ncbi.nlm.nih.gov/23474490"},"language":"en","primary_location":{"id":"doi:10.1039/c3dt32865a","doi":"https://doi.org/10.1039/c3dt32865a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3dt32865a","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://iris.unito.it/bitstream/2318/126928/2/Open_Access_Version.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5009521760","display_name":"Elisa Borfecchia","orcid":"https://orcid.org/0000-0001-8374-8329","observed_orcids":["https://orcid.org/0000-0001-8374-8329"]},"institutions":[{"id":"https://openalex.org/I4210155898","display_name":"National Interuniversity Consortium of Materials Science and Technology","ror":"https://ror.org/04k80k910","country_code":"IT","type":"education","lineage":["https://openalex.org/I4210155898"]},{"id":"https://openalex.org/I55143463","display_name":"University of Turin","ror":"https://ror.org/048tbm396","country_code":"IT","type":"education","lineage":["https://openalex.org/I55143463"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Elisa Borfecchia","raw_affiliation_strings":["Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, Turin, Italy","Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]},{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076563986","display_name":"Claudio Garino","orcid":"https://orcid.org/0000-0002-7854-6076","observed_orcids":["https://orcid.org/0000-0002-7854-6076"]},"institutions":[{"id":"https://openalex.org/I4210155898","display_name":"National Interuniversity Consortium of Materials Science and Technology","ror":"https://ror.org/04k80k910","country_code":"IT","type":"education","lineage":["https://openalex.org/I4210155898"]},{"id":"https://openalex.org/I55143463","display_name":"University of Turin","ror":"https://ror.org/048tbm396","country_code":"IT","type":"education","lineage":["https://openalex.org/I55143463"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Claudio Garino","raw_affiliation_strings":["Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081050083","display_name":"Luca Salassa","orcid":"https://orcid.org/0000-0002-2112-9095","observed_orcids":["https://orcid.org/0000-0002-2112-9095"]},"institutions":[{"id":"https://openalex.org/I39555362","display_name":"University of Warwick","ror":"https://ror.org/01a77tt86","country_code":"GB","type":"education","lineage":["https://openalex.org/I39555362"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Luca Salassa","raw_affiliation_strings":["Department of Chemistry, University of Warwick, Gibbet Hill Rd, Coventry CV4 7AL, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Warwick, Gibbet Hill Rd, Coventry CV4 7AL, UK","institution_ids":["https://openalex.org/I39555362"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012548773","display_name":"Tiziana Ruiu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210155898","display_name":"National Interuniversity Consortium of Materials Science and Technology","ror":"https://ror.org/04k80k910","country_code":"IT","type":"education","lineage":["https://openalex.org/I4210155898"]},{"id":"https://openalex.org/I55143463","display_name":"University of Turin","ror":"https://ror.org/048tbm396","country_code":"IT","type":"education","lineage":["https://openalex.org/I55143463"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Tiziana Ruiu","raw_affiliation_strings":["Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008063541","display_name":"Diego Gianolio","orcid":"https://orcid.org/0000-0002-0708-4492","observed_orcids":["https://orcid.org/0000-0002-0708-4492"]},"institutions":[{"id":"https://openalex.org/I2802711169","display_name":"Diamond Light Source","ror":"https://ror.org/05etxs293","country_code":"GB","type":"facility","lineage":["https://openalex.org/I2802711169"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Diego Gianolio","raw_affiliation_strings":["Diamond Light Source Ltd, Harwell Science and Innovation Campus, OX11 0DE Didcot, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Diamond Light Source Ltd, Harwell Science and Innovation Campus, OX11 0DE Didcot, UK","institution_ids":["https://openalex.org/I2802711169"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100357463","display_name":"Xiaoyi Zhang","orcid":"https://orcid.org/0000-0001-9732-1449","observed_orcids":["https://orcid.org/0000-0001-9732-1449","https://orcid.org/0009-0006-0096-125X"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xiaoyi Zhang","raw_affiliation_strings":["X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022393072","display_name":"Klaus Attenkofer","orcid":"https://orcid.org/0000-0003-1588-3611","observed_orcids":["https://orcid.org/0000-0003-1588-3611"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Klaus Attenkofer","raw_affiliation_strings":["X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014620636","display_name":"Lin X. Chen","orcid":"https://orcid.org/0000-0002-8450-6687","observed_orcids":["https://orcid.org/0000-0002-8450-6687"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lin X. Chen","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA","X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA","institution_ids":["https://openalex.org/I111979921"]},{"raw_affiliation_string":"X-ray Science Division and Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL 60439, USA","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014854500","display_name":"Roberto Gobetto","orcid":"https://orcid.org/0000-0002-2431-8051","observed_orcids":["https://orcid.org/0000-0002-2431-8051"]},"institutions":[{"id":"https://openalex.org/I4210155898","display_name":"National Interuniversity Consortium of Materials Science and Technology","ror":"https://ror.org/04k80k910","country_code":"IT","type":"education","lineage":["https://openalex.org/I4210155898"]},{"id":"https://openalex.org/I55143463","display_name":"University of Turin","ror":"https://ror.org/048tbm396","country_code":"IT","type":"education","lineage":["https://openalex.org/I55143463"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Roberto Gobetto","raw_affiliation_strings":["Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071855899","display_name":"Peter John Sadler","orcid":"https://orcid.org/0000-0001-9160-1941","observed_orcids":["https://orcid.org/0000-0001-9160-1941"]},"institutions":[{"id":"https://openalex.org/I39555362","display_name":"University of Warwick","ror":"https://ror.org/01a77tt86","country_code":"GB","type":"education","lineage":["https://openalex.org/I39555362"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Peter J. Sadler","raw_affiliation_strings":["Department of Chemistry, University of Warwick, Gibbet Hill Rd, Coventry CV4 7AL, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Warwick, Gibbet Hill Rd, Coventry CV4 7AL, UK","institution_ids":["https://openalex.org/I39555362"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5065176254","display_name":"Carlo Lamberti","orcid":"https://orcid.org/0000-0001-8004-2312","observed_orcids":["https://orcid.org/0000-0001-8004-2312"]},"institutions":[{"id":"https://openalex.org/I4210155898","display_name":"National Interuniversity Consortium of Materials Science and Technology","ror":"https://ror.org/04k80k910","country_code":"IT","type":"education","lineage":["https://openalex.org/I4210155898"]},{"id":"https://openalex.org/I55143463","display_name":"University of Turin","ror":"https://ror.org/048tbm396","country_code":"IT","type":"education","lineage":["https://openalex.org/I55143463"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Carlo Lamberti","raw_affiliation_strings":["Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, NIS Centre of Excellence, and INSTM Reference Centre, University of Turin, via P. Giuria 7, 10125 Turin, Italy","institution_ids":["https://openalex.org/I4210155898","https://openalex.org/I55143463"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5065176254","https://openalex.org/A5081050083"],"corresponding_institution_ids":["https://openalex.org/I39555362","https://openalex.org/I4210155898","https://openalex.org/I55143463"],"apc_list":null,"apc_paid":null,"fwci":4.6455,"has_fulltext":true,"cited_by_count":44,"citation_normalized_percentile":{"value":0.9573308,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"42","issue":"18","first_page":"6564","last_page":"6564"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.012199999764561653,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-polypyridyl-complexes","display_name":"ruthenium polypyridyl complexes","score":0.8569999933242798},{"id":"https://openalex.org/keywords/triplet-state","display_name":"triplet state","score":0.7260000109672546},{"id":"https://openalex.org/keywords/mlct-excited-states","display_name":"MLCT excited states","score":0.7160000205039978},{"id":"https://openalex.org/keywords/ligand-dissociation","display_name":"ligand dissociation","score":0.7110000252723694},{"id":"https://openalex.org/keywords/excited-state-dynamics","display_name":"excited-state dynamics","score":0.7509999871253967},{"id":"https://openalex.org/keywords/excited-state-structure","display_name":"excited-state geometry","score":0.6660000085830688},{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.7390000224113464},{"id":"https://openalex.org/keywords/ruthenium-ii-complexes","display_name":"ruthenium(II) complexes","score":0.5630000233650208}],"concepts":[{"id":"https://openalex.org/C95503338","wikidata":"https://www.wikidata.org/wiki/Q186105","display_name":"Ultrafast laser spectroscopy","level":3,"score":0.8392747640609741},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.6759664416313171},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5906897187232971},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.554999053478241},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.5270699858665466},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.52198326587677},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5062450766563416},{"id":"https://openalex.org/C76766466","wikidata":"https://www.wikidata.org/wiki/Q3036629","display_name":"Triplet state","level":3,"score":0.4904145896434784},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4750290513038635},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4250658452510834},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.3787626624107361},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3164711892604828},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.26629483699798584},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.18248897790908813},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.1405237913131714},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.05971613526344299},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/c3dt32865a","doi":"https://doi.org/10.1039/c3dt32865a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3dt32865a","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:23474490","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23474490","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"},{"id":"pmh:oai:iris.unito.it:2318/126928","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2318/126928","pdf_url":"https://iris.unito.it/bitstream/2318/126928/2/Open_Access_Version.pdf","source":{"id":"https://openalex.org/S4306400637","display_name":"Institutional Research Information System University of Turin (University of Turin)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I55143463","host_organization_name":"University of Turin","host_organization_lineage":["https://openalex.org/I55143463"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:iris.unito.it:2318/126928","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2318/126928","pdf_url":"https://iris.unito.it/bitstream/2318/126928/2/Open_Access_Version.pdf","source":{"id":"https://openalex.org/S4306400637","display_name":"Institutional Research Information System University of Turin (University of Turin)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I55143463","host_organization_name":"University of Turin","host_organization_lineage":["https://openalex.org/I55143463"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G102163711","display_name":null,"funder_award_id":"DE\u2010 AC02\u201006CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G262962599","display_name":null,"funder_award_id":"AC02\u201006CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320322930","display_name":"Ministerio de Ciencia e Innovaci\u00f3n","ror":null}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2165097359.pdf","grobid_xml":"https://content.openalex.org/works/W2165097359.grobid-xml"},"referenced_works_count":50,"referenced_works":["https://openalex.org/W1500927176","https://openalex.org/W1963806719","https://openalex.org/W1966900138","https://openalex.org/W1968028071","https://openalex.org/W1976889929","https://openalex.org/W1979794816","https://openalex.org/W1984726770","https://openalex.org/W1988004423","https://openalex.org/W1991333852","https://openalex.org/W1992847270","https://openalex.org/W1993569566","https://openalex.org/W1994151712","https://openalex.org/W1998454659","https://openalex.org/W2006120627","https://openalex.org/W2010297085","https://openalex.org/W2012641304","https://openalex.org/W2016098540","https://openalex.org/W2016249727","https://openalex.org/W2024608500","https://openalex.org/W2026968671","https://openalex.org/W2027934995","https://openalex.org/W2030117631","https://openalex.org/W2036425804","https://openalex.org/W2037621685","https://openalex.org/W2042555602","https://openalex.org/W2060930566","https://openalex.org/W2064456720","https://openalex.org/W2069793801","https://openalex.org/W2072904062","https://openalex.org/W2076859568","https://openalex.org/W2082845860","https://openalex.org/W2086634861","https://openalex.org/W2086758918","https://openalex.org/W2089464927","https://openalex.org/W2089627958","https://openalex.org/W2090108602","https://openalex.org/W2093910216","https://openalex.org/W2099587830","https://openalex.org/W2104148174","https://openalex.org/W2107709985","https://openalex.org/W2109279969","https://openalex.org/W2124062102","https://openalex.org/W2125579691","https://openalex.org/W2135650285","https://openalex.org/W2152601731","https://openalex.org/W2166513029","https://openalex.org/W2170549062","https://openalex.org/W2316136868","https://openalex.org/W2317917755","https://openalex.org/W2951794441"],"related_works":["https://openalex.org/W2514593649","https://openalex.org/W2320995402","https://openalex.org/W2026968671","https://openalex.org/W800574761","https://openalex.org/W1543416546","https://openalex.org/W2084088235","https://openalex.org/W1993569566","https://openalex.org/W1987921470","https://openalex.org/W1991649888","https://openalex.org/W2086758918"],"abstract_inverted_index":{"The":[0],"excited":[1],"state":[2,103,155],"dynamics":[3],"and":[4,20,26,60,71,85,95,135],"structure":[5,99,160],"of":[6,40,52,57,100,130,138],"the":[7,50,65,69,74,97,101,106,111,122,131,139,146,153],"photochemically":[8],"active":[9],"complex":[10],"cis-[Ru(bpy)2(py)2](2+)":[11,36],"have":[12],"been":[13],"investigated":[14],"using":[15],"optical":[16],"transient":[17,22,98],"absorption":[18,23],"(OTA)":[19],"X-ray":[21],"(XTA)":[24],"spectroscopy,":[25],"density":[27],"functional":[28],"theory":[29],"(DFT).":[30],"Upon":[31],"light-excitation":[32],"in":[33,110],"aqueous":[34],"solution":[35],"undergoes":[37],"ultrafast":[38],"dissociation":[39],"one":[41],"pyridine":[42],"ligand":[43],"to":[44,68,105,145],"form":[45],"cis-[Ru(bpy)2(py)(H2O)](2+).":[46],"OTA":[47,112],"measurements":[48],"highlighted":[49],"presence":[51],"two":[53],"major":[54],"time":[55,108],"components":[56],"1700":[58],"ps":[59,62,87],"130":[61],"through":[63],"which":[64],"system":[66],"decays":[67],"ground-state":[70],"evolves":[72],"towards":[73],"photoproduct.":[75],"XTA":[76,119],"data":[77],"were":[78],"acquired":[79],"after":[80],"150":[81],"ps,":[82,84],"500":[83],"3000":[86],"from":[88],"laser":[89],"excitation":[90],"(\u03bbexc":[91],"=":[92],"351":[93],"nm)":[94],"provided":[96],"(3)MLCT":[102,123],"corresponding":[104],"longer":[107],"component":[109],"experiment.":[113],"In":[114],"excellent":[115],"agreement":[116],"with":[117,143,161],"DFT,":[118],"shows":[120],"that":[121,152],"geometry":[124],"is":[125],"characterized":[126],"by":[127],"an":[128],"elongation":[129],"dissociating":[132],"Ru-N(py)":[133,162],"bond":[134,142],"a":[136,157],"shortening":[137],"trans":[140],"Ru-N(bpy)":[141],"respect":[144],"ground":[147],"state.":[148],"Conversely,":[149],"calculations":[150],"show":[151],"(3)MC":[154],"has":[156],"highly":[158],"distorted":[159],"bonds":[163],"between":[164],"2.77-3.05":[165],"\u00c5.":[166]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2024,"cited_by_count":4},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":6},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":5}],"updated_date":"2026-10-24T09:50:30.924529","created_date":"2016-06-24T00:00:00"}