{"id":"https://openalex.org/W2164138482","doi":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","title":"Reactivity of Vanadocene with a Nitrile bCtN Bond Activated by a Tris(fluorophenyl)borane as Lewis Acid: Formation of Borane Adducts of Vanada(IV)azirine Complexes\u2014EPR Evidence for an Intramolecular CbF\u22c5\u22c5\u22c5V Interaction","display_name":"Reactivity of Vanadocene with a Nitrile bCtN Bond Activated by a Tris(fluorophenyl)borane as Lewis Acid: Formation of Borane Adducts of Vanada(IV)azirine Complexes\u2014EPR Evidence for an Intramolecular CbF\u22c5\u22c5\u22c5V Interaction","publication_year":2002,"publication_date":"2002-06-17","ids":{"openalex":"https://openalex.org/W2164138482","doi":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","mag":"2164138482","pmid":"https://pubmed.ncbi.nlm.nih.gov/12391647"},"language":"en","primary_location":{"id":"doi:10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","doi":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082449700","display_name":"Robert Choukroun","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Robert Choukroun","raw_affiliation_strings":["Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse, France. choukrou@lcc-toulouse.fr","Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse, France. choukrou@lcc-toulouse.fr","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069731013","display_name":"Christian Y. Lorber","orcid":"https://orcid.org/0000-0003-1361-5373","observed_orcids":["https://orcid.org/0000-0003-1361-5373"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Christian Lorber","raw_affiliation_strings":["Equipe Pre\u0301curseurs Mole\u0301culaires et Mate\u0301riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Equipe Pre\u0301curseurs Mole\u0301culaires et Mate\u0301riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5081380948","display_name":"B. Donnadieu","orcid":"https://orcid.org/0000-0002-0655-0578","observed_orcids":["https://orcid.org/0000-0002-0655-0578"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Bruno Donnadieu","raw_affiliation_strings":["Equipe Pre\u0301curseurs Mole\u0301culaires et Mate\u0301riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Equipe Pre\u0301curseurs Mole\u0301culaires et Mate\u0301riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Equipe Pr\u00e9curseurs Mol\u00e9culaires et Mat\u00e9riaux Laboratoire de Chimie de Coordination, CNRS UPR 8241 205 route de Narbonne, 31077 Toulouse Cedex 4 (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":3.7503,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.94051886,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"8","issue":"12","first_page":"2700","last_page":"2700"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.478300005197525,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.478300005197525,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.3353999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.08420000225305557,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/vanadocene","display_name":"vanadocene","score":0.996999979019165},{"id":"https://openalex.org/keywords/nitrile-activation","display_name":"nitrile activation","score":0.7739999890327454},{"id":"https://openalex.org/keywords/lewis-acid-activation","display_name":"Lewis acid activation","score":0.7519999742507935},{"id":"https://openalex.org/keywords/borane-adducts","display_name":"borane adducts","score":0.972000002861023},{"id":"https://openalex.org/keywords/vanadium-iv","display_name":"vanadium(IV)","score":0.7269999980926514},{"id":"https://openalex.org/keywords/intramolecular-interactions","display_name":"intramolecular interactions","score":0.6399999856948853},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.7950000166893005},{"id":"https://openalex.org/keywords/organovanadium-chemistry","display_name":"organovanadium chemistry","score":0.4050000011920929}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8393512964248657},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.7025854587554932},{"id":"https://openalex.org/C2779240715","wikidata":"https://www.wikidata.org/wiki/Q333936","display_name":"Nitrile","level":2,"score":0.6832611560821533},{"id":"https://openalex.org/C2778826510","wikidata":"https://www.wikidata.org/wiki/Q15634214","display_name":"Borane","level":3,"score":0.6636452674865723},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.6053776144981384},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.6017617583274841},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5623990297317505},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.5527842044830322},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5217441320419312},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.49044176936149597},{"id":"https://openalex.org/C2775982830","wikidata":"https://www.wikidata.org/wiki/Q67913382","display_name":"Azirine","level":3,"score":0.4576403796672821},{"id":"https://openalex.org/C186927785","wikidata":"https://www.wikidata.org/wiki/Q374793","display_name":"Unpaired electron","level":3,"score":0.4340878427028656},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.35041338205337524},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.32728311419487},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.17334380745887756},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12721890211105347},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.12607526779174805},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","doi":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-3765(20020617)8:12<2700::aid-chem2700>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"},{"id":"pmid:12391647","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/12391647","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry (Weinheim an der Bergstrasse, Germany)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W1972335482","https://openalex.org/W2034144109","https://openalex.org/W2320057111","https://openalex.org/W2097474260","https://openalex.org/W2085103213","https://openalex.org/W7025021274","https://openalex.org/W2109955336","https://openalex.org/W3040897311","https://openalex.org/W2030380295","https://openalex.org/W2313302198"],"abstract_inverted_index":{"Reaction":[0],"of":[1,15,34,43,54,60,64,89,96,113],"vanadocene":[2],"[V(Cp)2]":[3],"with":[4,26,67,121,137],"\"activated\"":[5],"nitrile":[6],"R1CN.L":[7],"(L:":[8],"Lewis":[9,99],"acid),":[10],"obtained":[11],"by":[12,85,94],"the":[13,31,58,65,68,81,86,90,97,111,129,149,173],"reaction":[14],"borane":[16,32,91],"adducts":[17],"(L":[18],"=":[19,22,39,71,123,139],"BR3;":[20],"R":[21],"C6F5,":[23],"2,6-F2C6H3,":[24],"3,4,5-F3C6H2)":[25],"nitriles":[27],"(CH3CN,":[28],"F3CC6H4CN),":[29],"yields":[30],"adduct":[33],"vanada(IV)azirine":[35],"complexes":[36],"[V(Cp)2(eta":[37],"2-R1C":[38],"N.L)].":[40],"EPR":[41,106,133],"studies":[42],"a":[44,114,118],"fluid":[45,119],"solution":[46,120],"were":[47],"conducted":[48],"on":[49],"these":[50],"complexes.":[51],"A":[52,152],"doublet":[53],"octets":[55],"due":[56],"to":[57,75,80,157],"coupling":[59,79],"one":[61],"unpaired":[62],"electron":[63],"vanadium":[66],"51V":[69],"(I":[70],"7/2)":[72],"nucleus":[73],"and":[74,125,163,168],"an":[76,178],"additional":[77],"hyperfine":[78],"ortho-F":[82,144,169],"atom":[83],"borne":[84],"phenyl":[87,150],"ring":[88],"was":[92],"elucidated":[93],"means":[95],"different":[98],"acids":[100],"used":[101],"in":[102,117,141,148,172],"this":[103,161],"work.":[104],"This":[105],"behaviour":[107],"gives":[108],"evidence":[109],"for":[110,176],"presence":[112],"C-F...V":[115],"interaction":[116],"L":[122,138],"B(C6F5)3":[124],"B(2,6-F2C6H3)3.":[126],"In":[127],"contrast,":[128],"expected":[130,174],"eight":[131],"line":[132],"pattern":[134],"is":[135],"observed":[136],"B(3,4,5-F3C6H2)3,":[140],"which":[142],"no":[143],"atoms":[145,170],"are":[146,171],"present":[147],"ring.":[151],"model":[153],"can":[154],"be":[155],"drawn":[156],"take":[158],"into":[159],"account":[160],"flexibility":[162],"V...F":[164],"distances":[165],"between":[166],"V":[167],"range":[175],"such":[177],"interaction.":[179]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}