{"id":"https://openalex.org/W2163561983","doi":"https://doi.org/10.1002/chem.200802341","title":"Asymmetric Gold\u2010Catalyzed Hydroarylation/Cyclization Reactions","display_name":"Asymmetric Gold\u2010Catalyzed Hydroarylation/Cyclization Reactions","publication_year":2009,"publication_date":"2009-01-02","ids":{"openalex":"https://openalex.org/W2163561983","doi":"https://doi.org/10.1002/chem.200802341","mag":"2163561983","pmid":"https://pubmed.ncbi.nlm.nih.gov/19123228"},"language":"en","primary_location":{"id":"doi:10.1002/chem.200802341","doi":"https://doi.org/10.1002/chem.200802341","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.200802341","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5031610768","display_name":"Chung\u2010Meng Chao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149758196","display_name":"Chimie ParisTech - PSL","ror":"https://ror.org/05q65zh81","country_code":"FR","type":"education","lineage":["https://openalex.org/I149758196","https://openalex.org/I190752583"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Chung\u2010Meng Chao","raw_affiliation_strings":["Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05, France","institution_ids":["https://openalex.org/I149758196"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008818006","display_name":"Maxime R. Vitale","orcid":"https://orcid.org/0000-0002-6740-2472","observed_orcids":["https://orcid.org/0000-0002-6740-2472"]},"institutions":[{"id":"https://openalex.org/I149758196","display_name":"Chimie ParisTech - PSL","ror":"https://ror.org/05q65zh81","country_code":"FR","type":"education","lineage":["https://openalex.org/I149758196","https://openalex.org/I190752583"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Maxime\u2005R. Vitale","raw_affiliation_strings":["Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]},{"raw_affiliation_string":"Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032621571","display_name":"Patrick Yves Toullec","orcid":"https://orcid.org/0000-0003-0376-5052","observed_orcids":["https://orcid.org/0000-0003-0376-5052"]},"institutions":[{"id":"https://openalex.org/I149758196","display_name":"Chimie ParisTech - PSL","ror":"https://ror.org/05q65zh81","country_code":"FR","type":"education","lineage":["https://openalex.org/I149758196","https://openalex.org/I190752583"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Patrick\u2005Y. Toullec","raw_affiliation_strings":["Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]},{"raw_affiliation_string":"Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103566338","display_name":"Jean\u2010Pierre Gen\u00eat","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149758196","display_name":"Chimie ParisTech - PSL","ror":"https://ror.org/05q65zh81","country_code":"FR","type":"education","lineage":["https://openalex.org/I149758196","https://openalex.org/I190752583"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Jean\u2010Pierre Gen\u00eat","raw_affiliation_strings":["Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057366218","display_name":"V\u00e9ronique Michelet","orcid":"https://orcid.org/0000-0002-2217-9115","observed_orcids":["https://orcid.org/0000-0002-2217-9115"]},"institutions":[{"id":"https://openalex.org/I149758196","display_name":"Chimie ParisTech - PSL","ror":"https://ror.org/05q65zh81","country_code":"FR","type":"education","lineage":["https://openalex.org/I149758196","https://openalex.org/I190752583"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"V\u00e9ronique Michelet","raw_affiliation_strings":["Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Synthe\u0300se Se\u0301lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Supe\u0301rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]},{"raw_affiliation_string":"Laboratoire de Synth\u00e8se S\u00e9lective Organique et Produits Naturels, UMR 7573, Ecole Nationale Sup\u00e9rieure de Chimie de Paris rue P. et M. Curie, 75231 Paris cedex 05 (France),","institution_ids":["https://openalex.org/I149758196"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5057366218"],"corresponding_institution_ids":["https://openalex.org/I149758196"],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":10.2668,"has_fulltext":false,"cited_by_count":166,"citation_normalized_percentile":{"value":0.99203348,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":100},"biblio":{"volume":"15","issue":"6","first_page":"1319","last_page":"1323"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gold-catalysis","display_name":"gold catalysis","score":0.8949999809265137},{"id":"https://openalex.org/keywords/asymmetric-hydroarylation","display_name":"asymmetric hydroarylation","score":0.8510000109672546},{"id":"https://openalex.org/keywords/cyclization","display_name":"cyclization","score":0.7570000290870667},{"id":"https://openalex.org/keywords/1-6-enynes","display_name":"1,6-enynes","score":0.9549999833106995},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.8230000138282776},{"id":"https://openalex.org/keywords/alkene-rearrangement","display_name":"alkene rearrangement","score":0.5910000205039978},{"id":"https://openalex.org/keywords/nucleophilic-addition-to-alkenes","display_name":"nucleophilic addition to alkenes","score":0.7599999904632568},{"id":"https://openalex.org/keywords/pyrrole","display_name":"pyrrole","score":0.5580000281333923},{"id":"https://openalex.org/keywords/indole-derivatives","display_name":"indole derivatives","score":0.8479999899864197},{"id":"https://openalex.org/keywords/1-3-5-trimethoxybenzene","display_name":"1,3,5-trimethoxybenzene","score":0.8140000104904175},{"id":"https://openalex.org/keywords/1-3-dimethoxybenzene","display_name":"1,3-dimethoxybenzene","score":0.9710000157356262}],"concepts":[{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.7839311361312866},{"id":"https://openalex.org/C2776946247","wikidata":"https://www.wikidata.org/wiki/Q410597","display_name":"Bromobenzene","level":3,"score":0.70148766040802},{"id":"https://openalex.org/C2776254738","wikidata":"https://www.wikidata.org/wiki/Q81406","display_name":"Alkene","level":3,"score":0.6815249919891357},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6078029870986938},{"id":"https://openalex.org/C2779400197","wikidata":"https://www.wikidata.org/wiki/Q242627","display_name":"Pyrrole","level":2,"score":0.5803148746490479},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.5733453035354614},{"id":"https://openalex.org/C192527728","wikidata":"https://www.wikidata.org/wiki/Q1465700","display_name":"Indole test","level":2,"score":0.5593229532241821},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5453670620918274},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5255947113037109},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3600342869758606},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.31494513154029846},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.31277865171432495}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/chem.200802341","doi":"https://doi.org/10.1002/chem.200802341","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.200802341","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},{"id":"pmid:19123228","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19123228","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry (Weinheim an der Bergstrasse, Germany)","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-00370120v1","doi":null,"is_oa":false,"landing_page_url":"https://hal.science/hal-00370120","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry - A European Journal, 2009, 15, pp.1319-1323","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":98,"referenced_works":["https://openalex.org/W1974992646","https://openalex.org/W1975520800","https://openalex.org/W1975869640","https://openalex.org/W1976005232","https://openalex.org/W1976523895","https://openalex.org/W1977876550","https://openalex.org/W1987126722","https://openalex.org/W1987176537","https://openalex.org/W1988247142","https://openalex.org/W1988806469","https://openalex.org/W1991336003","https://openalex.org/W1991341486","https://openalex.org/W1998375603","https://openalex.org/W2002161566","https://openalex.org/W2005239780","https://openalex.org/W2005345467","https://openalex.org/W2014210468","https://openalex.org/W2019123141","https://openalex.org/W2019263180","https://openalex.org/W2025002140","https://openalex.org/W2025474947","https://openalex.org/W2034666141","https://openalex.org/W2040122123","https://openalex.org/W2045962849","https://openalex.org/W2051299152","https://openalex.org/W2057747671","https://openalex.org/W2058442753","https://openalex.org/W2061050859","https://openalex.org/W2065104863","https://openalex.org/W2065510965","https://openalex.org/W2071772558","https://openalex.org/W2075454501","https://openalex.org/W2076072148","https://openalex.org/W2076328278","https://openalex.org/W2078276140","https://openalex.org/W2081237845","https://openalex.org/W2083716989","https://openalex.org/W2084568011","https://openalex.org/W2087059370","https://openalex.org/W2088958203","https://openalex.org/W2099083467","https://openalex.org/W2099477055","https://openalex.org/W2099674459","https://openalex.org/W2101098989","https://openalex.org/W2102987254","https://openalex.org/W2103191961","https://openalex.org/W2103586606","https://openalex.org/W2104633117","https://openalex.org/W2106375771","https://openalex.org/W2107250741","https://openalex.org/W2107743975","https://openalex.org/W2112468447","https://openalex.org/W2112645213","https://openalex.org/W2113368796","https://openalex.org/W2115497667","https://openalex.org/W2121785274","https://openalex.org/W2121970136","https://openalex.org/W2123000264","https://openalex.org/W2128147343","https://openalex.org/W2137460597","https://openalex.org/W2140542212","https://openalex.org/W2140756280","https://openalex.org/W2140775423","https://openalex.org/W2141620060","https://openalex.org/W2146155738","https://openalex.org/W2146258459","https://openalex.org/W2147703562","https://openalex.org/W2148363281","https://openalex.org/W2149642513","https://openalex.org/W2156846886","https://openalex.org/W2160574842","https://openalex.org/W2161764986","https://openalex.org/W2166303952","https://openalex.org/W2167215290","https://openalex.org/W2167506093","https://openalex.org/W2171801879","https://openalex.org/W2174696032","https://openalex.org/W2319900189","https://openalex.org/W2335752384","https://openalex.org/W2949680609","https://openalex.org/W2949695352","https://openalex.org/W2949698852","https://openalex.org/W2950265756","https://openalex.org/W2950647151","https://openalex.org/W2951006189","https://openalex.org/W2952082074","https://openalex.org/W2952285447","https://openalex.org/W2952392521","https://openalex.org/W2952991413","https://openalex.org/W2953280730","https://openalex.org/W4211021418","https://openalex.org/W4211044815","https://openalex.org/W4240097923","https://openalex.org/W4244844192","https://openalex.org/W4247720395","https://openalex.org/W4248548839","https://openalex.org/W4249158466","https://openalex.org/W4252777229"],"related_works":["https://openalex.org/W2952008698","https://openalex.org/W2016394722","https://openalex.org/W3040867415","https://openalex.org/W2952163817","https://openalex.org/W6947452313","https://openalex.org/W2070631021","https://openalex.org/W2952129009","https://openalex.org/W4206728246","https://openalex.org/W4253079530","https://openalex.org/W2032769574"],"abstract_inverted_index":{"Gold":[0],"efficiency:":[1],"An":[2],"efficient":[3],"AuI":[4],"catalytic":[5],"system":[6],"is":[7],"described":[8],"for":[9],"the":[10,20,28],"enantioselective":[11],"hydroarylation/cyclization":[12],"reaction":[13],"of":[14,19,31],"1,6-enynes":[15],"(see":[16],"scheme).":[17],"Use":[18],"(R)-4-MeO-3,5-(tBu)2-MeOBIPHEP\u2013gold":[21],"complex":[22],"led":[23],"to":[24,42],"clean":[25],"rearrangements":[26],"implying":[27],"formal":[29],"addition":[30],"a":[32,47],"carbon":[33],"nucleophile":[34],"(1,3,5-trimethoxybenzene,":[35],"1,3-dimethoxybenzene,":[36],"pyrrole,":[37],"1,3,5-trimethoxy-2-bromobenzene":[38],"and":[39],"indole":[40],"derivatives)":[41],"an":[43],"alkene":[44],"followed":[45],"by":[46],"cyclization":[48],"process.":[49]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":10},{"year":2021,"cited_by_count":9},{"year":2020,"cited_by_count":7},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":10},{"year":2016,"cited_by_count":11},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":12},{"year":2013,"cited_by_count":17},{"year":2012,"cited_by_count":15}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
