{"id":"https://openalex.org/W2162877353","doi":"https://doi.org/10.1039/b807199c","title":"Lariat ethers with fluoroaryl side-arms: a study of CF\u22efmetal cation interaction in the complexes of N-(o-fluoroaryl)azacrown ethers","display_name":"Lariat ethers with fluoroaryl side-arms: a study of CF\u22efmetal cation interaction in the complexes of N-(o-fluoroaryl)azacrown ethers","publication_year":2008,"publication_date":"2008-12-04","ids":{"openalex":"https://openalex.org/W2162877353","doi":"https://doi.org/10.1039/b807199c","mag":"2162877353","pmid":"https://pubmed.ncbi.nlm.nih.gov/19156278"},"language":"en","primary_location":{"id":"doi:10.1039/b807199c","doi":"https://doi.org/10.1039/b807199c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b807199c","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Trans.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5055097436","display_name":"P. K. Sazonov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Petr K. Sazonov","raw_affiliation_strings":["Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow","institution_ids":["https://openalex.org/I19880235"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029937984","display_name":"Lidiya Kh. Minacheva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Lidiya Kh. Minacheva","raw_affiliation_strings":["N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow","institution_ids":["https://openalex.org/I4210108652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019490997","display_name":"Andrei V. Churakov","orcid":"https://orcid.org/0000-0003-3336-4022","observed_orcids":["https://orcid.org/0000-0003-3336-4022"]},"institutions":[{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Andrei V. Churakov","raw_affiliation_strings":["N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow","institution_ids":["https://openalex.org/I4210108652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032770350","display_name":"\u0412.\u0421. \u0421\u0435\u0440\u0433\u0438\u0435\u043d\u043a\u043e","orcid":"https://orcid.org/0000-0002-2743-8921","observed_orcids":["https://orcid.org/0000-0002-2743-8921"]},"institutions":[{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Vladimir S. Sergienko","raw_affiliation_strings":["N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"N. S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow","institution_ids":["https://openalex.org/I4210108652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045356997","display_name":"Galina A. Artamkina","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Galina A. Artamkina","raw_affiliation_strings":["Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow","institution_ids":["https://openalex.org/I19880235"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113221005","display_name":"Yuri F. Oprunenko","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Yuri F. Oprunenko","raw_affiliation_strings":["Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow","institution_ids":["https://openalex.org/I19880235"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5007996916","display_name":"I. P. Beletskaya","orcid":"https://orcid.org/0000-0001-9705-1434","observed_orcids":["https://orcid.org/0000-0001-9705-1434"]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Irina P. Beletskaya","raw_affiliation_strings":["Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Department of the M. V. Lomonosov Moscow State University, 119992 Moscow","institution_ids":["https://openalex.org/I19880235"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5007996916","https://openalex.org/A5055097436"],"corresponding_institution_ids":["https://openalex.org/I19880235"],"apc_list":null,"apc_paid":null,"fwci":0.9409,"has_fulltext":false,"cited_by_count":13,"citation_normalized_percentile":{"value":0.69291934,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":null,"issue":"5","first_page":"843","last_page":"850"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.986299991607666,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.986299991607666,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.006399999838322401,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.000699999975040555,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lariat-ethers","display_name":"lariat ethers","score":0.9610000252723694},{"id":"https://openalex.org/keywords/azacrown-ethers","display_name":"azacrown ethers","score":0.9620000123977661},{"id":"https://openalex.org/keywords/diaza-18-crown-6","display_name":"diaza-18-crown-6","score":0.9390000104904175},{"id":"https://openalex.org/keywords/lead-ii-complexes","display_name":"lead(II) complexes","score":0.6759999990463257},{"id":"https://openalex.org/keywords/barium-ii-complexes","display_name":"barium(II) complexes","score":0.9810000061988831},{"id":"https://openalex.org/keywords/x-ray-crystal-structure","display_name":"X-ray crystal structure","score":0.5839999914169312},{"id":"https://openalex.org/keywords/n-arylation","display_name":"N-arylation","score":0.6850000023841858}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8592370748519897},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.6635667681694031},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6434205174446106},{"id":"https://openalex.org/C184866935","wikidata":"https://www.wikidata.org/wiki/Q191010","display_name":"Titration","level":2,"score":0.5630567669868469},{"id":"https://openalex.org/C46000676","wikidata":"https://www.wikidata.org/wiki/Q804644","display_name":"Lone pair","level":3,"score":0.5548930764198303},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5161577463150024},{"id":"https://openalex.org/C3019440265","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Complex formation","level":2,"score":0.44768407940864563},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.42730477452278137},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.41270098090171814},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3810585141181946},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.17131757736206055},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11048227548599243}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/b807199c","doi":"https://doi.org/10.1039/b807199c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b807199c","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Trans.","raw_type":"journal-article"},{"id":"pmid:19156278","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19156278","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"},{"id":"mag:1606029736","doi":null,"is_oa":false,"landing_page_url":"https://istina.msu.ru/publications/article/2300878/","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"Dalton Transactions","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W1985096764","https://openalex.org/W2000604012","https://openalex.org/W2001781517","https://openalex.org/W2015842063","https://openalex.org/W2017729127","https://openalex.org/W2018806720","https://openalex.org/W2020166056","https://openalex.org/W2028399380","https://openalex.org/W2032842297","https://openalex.org/W2035715009","https://openalex.org/W2043116263","https://openalex.org/W2055040618","https://openalex.org/W2055606342","https://openalex.org/W2057688617","https://openalex.org/W2059730435","https://openalex.org/W2067521270","https://openalex.org/W2068917975","https://openalex.org/W2078241847","https://openalex.org/W2079141923","https://openalex.org/W2087489421","https://openalex.org/W2092315973","https://openalex.org/W2095466114","https://openalex.org/W2113944021","https://openalex.org/W2148066840","https://openalex.org/W2157987627","https://openalex.org/W2949385154","https://openalex.org/W2951864495","https://openalex.org/W2952467258"],"related_works":["https://openalex.org/W1606029736","https://openalex.org/W1989578272","https://openalex.org/W1646839446","https://openalex.org/W2026462579","https://openalex.org/W2040276099","https://openalex.org/W1981397976","https://openalex.org/W2001863857","https://openalex.org/W2039956679","https://openalex.org/W2075337022","https://openalex.org/W1985635445"],"abstract_inverted_index":{"New":[0],"lariat":[1],"ethers,":[2],"N-(o-fluorophenyl)aza-15-crown-5":[3],"(F-A15C5)":[4],"and":[5,32,37,54,59,78,98,125,133],"N,N'-bis(o-fluorophenyl)diaza-18-crown-6":[6],"(F(2)-A(2)18C6),":[7],"were":[8],"prepared":[9],"by":[10,30,71],"the":[11,14,21,42,92,95,168],"N-arylation":[12],"of":[13,20,44,46,55,62,94,116,121,150,159,163,167],"corresponding":[15],"azacrown":[16],"ethers.":[17],"The":[18,88,118],"interaction":[19],"ligands":[22],"with":[23,48,57,147],"metal":[24,96],"cations":[25,107],"was":[26],"studied":[27],"in":[28],"solution":[29],"(1)H":[31],"(19)F":[33],"NMR":[34],"(in":[35],"acetone-d(6))":[36],"UV":[38,72],"spectroscopy":[39],"(MeOH)":[40],"confirming":[41],"formation":[43],"complexes":[45,83,122],"F(2)-A(2)18C6":[47,79],"K(+),":[49],"Na(+),":[50],"Ag(+),":[51],"Ba(2+),":[52],"Pb(2+)":[53,160,169],"F-A15C5":[56,77],"Na(+)":[58],"giving":[60],"evidence":[61],"CFmetal":[63],"cation":[64,97],"interaction.":[65],"Cation":[66],"binding":[67],"constants":[68],"(beta,":[69],"evaluated":[70],"titration":[73],"method),":[74],"demonstrate":[75],"that":[76],"form":[80],"more":[81],"stable":[82],"than":[84],"their":[85],"fluorine-free":[86],"analogs.":[87],"effect":[89],"depends":[90],"on":[91],"nature":[93],"is":[99,139,161],"at":[100],"a":[101,164],"maximum":[102],"for":[103,113],"hard,":[104],"singly":[105],"charged":[106],"(up":[108],"to":[109,153],"3":[110],"logbeta":[111],"units":[112],"K(+)":[114],"complex":[115,143],"F(2)-A(2)18C6).":[117],"X-ray":[119],"structures":[120],"[Pb(F(2)-A(2)18C6)(H(2)O)](ClO(4))(2)":[123],"()":[124,127],"[Ba(F(2)-A(2)18C6)(ClO(4))(2)]":[126],"reveal":[128],"short":[129],"Pb-F":[130],"(2.805":[131],"A)":[132,136],"Ba-F":[134],"(2.965":[135],"contacts.":[137],"Complex":[138],"centrosymmetric":[140],"(C(i)),":[141],"while":[142],"has":[144],"C(2)":[145],"symmetry":[146],"one-side":[148],"coordination":[149,157],"o-fluorophenyl":[151],"groups":[152],"Pb(2+).":[154],"This":[155],"\"one-side\"":[156],"mode":[158],"indicative":[162],"partial":[165],"localization":[166],"lone":[170],"pair.":[171]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}