{"id":"https://openalex.org/W2161952166","doi":"https://doi.org/10.1039/b209877f","title":"Structural and spectroscopic characterisation of bis-ligand complexes of iron(ii), nickel(ii) and nickel(iii) with the hydrotris(methimazolyl)borate anion: soft S6 donor sets generating a weak ligand field","display_name":"Structural and spectroscopic characterisation of bis-ligand complexes of iron(ii), nickel(ii) and nickel(iii) with the hydrotris(methimazolyl)borate anion: soft S6 donor sets generating a weak ligand field","publication_year":2003,"publication_date":"2003-02-12","ids":{"openalex":"https://openalex.org/W2161952166","doi":"https://doi.org/10.1039/b209877f","mag":"2161952166"},"language":"en","primary_location":{"id":"doi:10.1039/b209877f","doi":"https://doi.org/10.1039/b209877f","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b209877f","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://ruj.uj.edu.pl/xmlui/handle/item/262898","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110249545","display_name":"Mark M. Garner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7882870","display_name":"University of Glasgow","ror":"https://ror.org/00vtgdb53","country_code":"GB","type":"education","lineage":["https://openalex.org/I7882870"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Mark Garner","raw_affiliation_strings":["Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK","institution_ids":["https://openalex.org/I7882870"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024192982","display_name":"Krzysztof Lewi\u0144ski","orcid":"https://orcid.org/0000-0003-3074-7175","observed_orcids":["https://orcid.org/0000-0003-3074-7175"]},"institutions":[{"id":"https://openalex.org/I126596746","display_name":"Jagiellonian University","ror":"https://ror.org/03bqmcz70","country_code":"PL","type":"education","lineage":["https://openalex.org/I126596746"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Krzysztof Lewinski","raw_affiliation_strings":["Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland","institution_ids":["https://openalex.org/I126596746"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077805764","display_name":"Agnieszka Pattek-Janczyk","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I126596746","display_name":"Jagiellonian University","ror":"https://ror.org/03bqmcz70","country_code":"PL","type":"education","lineage":["https://openalex.org/I126596746"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Agnieszka Pattek-Janczyk","raw_affiliation_strings":["Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland","institution_ids":["https://openalex.org/I126596746"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065601990","display_name":"J. Reglinski","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7882870","display_name":"University of Glasgow","ror":"https://ror.org/00vtgdb53","country_code":"GB","type":"education","lineage":["https://openalex.org/I7882870"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"John Reglinski","raw_affiliation_strings":["Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK","institution_ids":["https://openalex.org/I7882870"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058572222","display_name":"Barbara Sieklucka","orcid":"https://orcid.org/0000-0003-3211-5008","observed_orcids":["https://orcid.org/0000-0003-3211-5008"]},"institutions":[{"id":"https://openalex.org/I126596746","display_name":"Jagiellonian University","ror":"https://ror.org/03bqmcz70","country_code":"PL","type":"education","lineage":["https://openalex.org/I126596746"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Barbara Sieklucka","raw_affiliation_strings":["Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland","institution_ids":["https://openalex.org/I126596746"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030981453","display_name":"Mark D. Spicer","orcid":"https://orcid.org/0000-0002-6000-5677","observed_orcids":["https://orcid.org/0000-0002-6000-5677"]},"institutions":[{"id":"https://openalex.org/I7882870","display_name":"University of Glasgow","ror":"https://ror.org/00vtgdb53","country_code":"GB","type":"education","lineage":["https://openalex.org/I7882870"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Mark D. Spicer","raw_affiliation_strings":["Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK","institution_ids":["https://openalex.org/I7882870"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5046486617","display_name":"Maciej Szaleniec","orcid":"https://orcid.org/0000-0002-7650-9263","observed_orcids":["https://orcid.org/0000-0002-7650-9263"]},"institutions":[{"id":"https://openalex.org/I126596746","display_name":"Jagiellonian University","ror":"https://ror.org/03bqmcz70","country_code":"PL","type":"education","lineage":["https://openalex.org/I126596746"]},{"id":"https://openalex.org/I7882870","display_name":"University of Glasgow","ror":"https://ror.org/00vtgdb53","country_code":"GB","type":"education","lineage":["https://openalex.org/I7882870"]}],"countries":["GB","PL"],"is_corresponding":false,"raw_author_name":"Maciej Szaleniec","raw_affiliation_strings":["Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK","Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Pure & Applied Chemistry, 295 Cathedral Street, Glasgow, UK","institution_ids":["https://openalex.org/I7882870"]},{"raw_affiliation_string":"Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krak\u00f3w, Poland","institution_ids":["https://openalex.org/I126596746"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5030981453"],"corresponding_institution_ids":["https://openalex.org/I7882870"],"apc_list":null,"apc_paid":null,"fwci":2.4367,"has_fulltext":false,"cited_by_count":37,"citation_normalized_percentile":{"value":0.89161926,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":null,"issue":"6","first_page":"1181","last_page":"1185"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.5454000234603882,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.5454000234603882,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.20559999346733093,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.08410000056028366,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bis-ligand-complexes","display_name":"bis-ligand complexes","score":0.8209999799728394},{"id":"https://openalex.org/keywords/iron-ii-complexes","display_name":"iron(II) complexes","score":0.9779999852180481},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":0.9950000047683716},{"id":"https://openalex.org/keywords/nickel-iii-complexes","display_name":"nickel(III) complexes","score":0.9940000176429749},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.746999979019165},{"id":"https://openalex.org/keywords/trigonal-distortion","display_name":"trigonal distortion","score":0.7369999885559082},{"id":"https://openalex.org/keywords/high-spin-iron-ii","display_name":"high-spin iron(II)","score":0.7519999742507935},{"id":"https://openalex.org/keywords/paramagnetic-behaviour","display_name":"paramagnetic behaviour","score":0.675000011920929},{"id":"https://openalex.org/keywords/mossbauer-spectroscopy","display_name":"M\u00f6ssbauer spectroscopy","score":0.9819999933242798},{"id":"https://openalex.org/keywords/halide-complexes","display_name":"halide complexes","score":0.3880000114440918},{"id":"https://openalex.org/keywords/borate-ligands","display_name":"borate ligands","score":0.46000000834465027}],"concepts":[{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.84351646900177},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7508701086044312},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7308265566825867},{"id":"https://openalex.org/C501308230","wikidata":"https://www.wikidata.org/wiki/Q618","display_name":"Boron","level":2,"score":0.7178716063499451},{"id":"https://openalex.org/C57805442","wikidata":"https://www.wikidata.org/wiki/Q898951","display_name":"Ligand field theory","level":3,"score":0.6494351029396057},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.631009578704834},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.6175668835639954},{"id":"https://openalex.org/C70854507","wikidata":"https://www.wikidata.org/wiki/Q899927","display_name":"M\u00f6ssbauer spectroscopy","level":2,"score":0.4648861587047577},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.4499746263027191},{"id":"https://openalex.org/C11181451","wikidata":"https://www.wikidata.org/wiki/Q899789","display_name":"Spectrochemical series","level":4,"score":0.4359997808933258},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.3574349880218506},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3267550468444824},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.16540473699569702},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/b209877f","doi":"https://doi.org/10.1039/b209877f","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b209877f","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmh:oai:ruj.uj.edu.pl:item/262898","doi":null,"is_oa":true,"landing_page_url":"https://ruj.uj.edu.pl/xmlui/handle/item/262898","pdf_url":null,"source":{"id":"https://openalex.org/S4306400316","display_name":"Homo Politicus (Academy of Humanities and Economics in Lodz)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"artyku\u0142 w czasopi\u015bmie"},{"id":"mag:3110249015","doi":null,"is_oa":false,"landing_page_url":"https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902213380065148","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"Dalton Transactions","raw_type":null}],"best_oa_location":{"id":"pmh:oai:ruj.uj.edu.pl:item/262898","doi":null,"is_oa":true,"landing_page_url":"https://ruj.uj.edu.pl/xmlui/handle/item/262898","pdf_url":null,"source":{"id":"https://openalex.org/S4306400316","display_name":"Homo Politicus (Academy of Humanities and Economics in Lodz)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"artyku\u0142 w czasopi\u015bmie"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":21,"referenced_works":["https://openalex.org/W1974775438","https://openalex.org/W1979946766","https://openalex.org/W1984654275","https://openalex.org/W1985453005","https://openalex.org/W1987523965","https://openalex.org/W1994058163","https://openalex.org/W1995713751","https://openalex.org/W2012563025","https://openalex.org/W2026900018","https://openalex.org/W2039793559","https://openalex.org/W2044112950","https://openalex.org/W2057657865","https://openalex.org/W2063334178","https://openalex.org/W2067562683","https://openalex.org/W2076408787","https://openalex.org/W2085925082","https://openalex.org/W2089901760","https://openalex.org/W2095531445","https://openalex.org/W2153649073","https://openalex.org/W2315266515","https://openalex.org/W2324425784"],"related_works":["https://openalex.org/W2022580653","https://openalex.org/W1981166131","https://openalex.org/W2059844267","https://openalex.org/W2080238079","https://openalex.org/W2319573825","https://openalex.org/W2076921947","https://openalex.org/W2912127400","https://openalex.org/W2327174279","https://openalex.org/W2093125470","https://openalex.org/W2334619768"],"abstract_inverted_index":{"Reaction":[0,86],"of":[1,14,51,63,75,87,96],"iron(II)":[2,65],"and":[3,53,55],"nickel(II)":[4],"halides":[5],"with":[6,47,82,89],"sodium":[7],"hydrotris(methimazolyl)borate":[8],"(NaTm)":[9],"results":[10,91],"in":[11,23,30,92],"the":[12,39,60,64,76],"formation":[13],"2":[15],"\u2236":[16],"1":[17],"complexes":[18,68],"[M(Tm)2].":[19],"Crystallographic":[20],"characterisation":[21],"reveals":[22],"both":[24],"cases":[25],"trigonally":[26],"distorted":[27],"octahedral":[28],"geometry":[29],"an":[31],"S6":[32],"donor":[33],"set.":[34],"Spectroscopic":[35],"properties":[36],"indicate":[37],"that":[38,50],"Tm":[40],"ligand":[41,45],"generates":[42],"a":[43,83,93,97],"weak":[44],"field,":[46],"Dq":[48],"between":[49],"H2O":[52],"Cl\u2212":[54],"this":[56],"is":[57,79,100],"confirmed":[58],"by":[59],"high-spin":[61,84],"configuration":[62],"complex.":[66,85],"Both":[67],"display":[69],"classical":[70],"paramagnetic":[71],"behaviour.":[72],"M\u00f6ssbauer":[73],"spectroscopy":[74],"iron":[77],"complex":[78],"also":[80],"consistent":[81],"NiCl2\u00b76H2O":[88],"[Tl(Tm)]":[90],"small":[94],"quantity":[95],"material":[98],"which":[99],"crystallographically":[101],"demonstrated":[102],"to":[103],"be":[104],"[Ni(Tm)2]Br.":[105]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-06-24T00:00:00"}