{"id":"https://openalex.org/W2160306148","doi":"https://doi.org/10.1002/cssc.200900213","title":"Reductive Splitting of Cellulose in the Ionic Liquid 1\u2010Butyl\u20103\u2010Methylimidazolium Chloride","display_name":"Reductive Splitting of Cellulose in the Ionic Liquid 1\u2010Butyl\u20103\u2010Methylimidazolium Chloride","publication_year":2010,"publication_date":"2010-01-04","ids":{"openalex":"https://openalex.org/W2160306148","doi":"https://doi.org/10.1002/cssc.200900213","mag":"2160306148","pmid":"https://pubmed.ncbi.nlm.nih.gov/20049766"},"language":"en","primary_location":{"id":"doi:10.1002/cssc.200900213","doi":"https://doi.org/10.1002/cssc.200900213","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cssc.200900213","pdf_url":null,"source":{"id":"https://openalex.org/S193447295","display_name":"ChemSusChem","issn_l":"1864-5631","issn":["1864-5631","1864-564X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemSusChem","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5007755555","display_name":"Igor A. Ignatyev","orcid":"https://orcid.org/0000-0002-0847-1304","observed_orcids":["https://orcid.org/0000-0002-0847-1304"]},"institutions":[{"id":"https://openalex.org/I99464096","display_name":"KU Leuven","ror":"https://ror.org/05f950310","country_code":"BE","type":"education","lineage":["https://openalex.org/I99464096"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Igor\u2005A. Ignatyev","raw_affiliation_strings":["Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven, Belgium","institution_ids":["https://openalex.org/I99464096"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017774420","display_name":"Charlie Van Doorslaer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99464096","display_name":"KU Leuven","ror":"https://ror.org/05f950310","country_code":"BE","type":"education","lineage":["https://openalex.org/I99464096"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Charlie Van\u2005Doorslaer","raw_affiliation_strings":["Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),","institution_ids":["https://openalex.org/I99464096"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111542323","display_name":"Pascal G. N. Mertens","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99464096","display_name":"KU Leuven","ror":"https://ror.org/05f950310","country_code":"BE","type":"education","lineage":["https://openalex.org/I99464096"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Pascal\u2005G.\u2005N. Mertens","raw_affiliation_strings":["Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),","institution_ids":["https://openalex.org/I99464096"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052943366","display_name":"Koen Binnemans","orcid":"https://orcid.org/0000-0003-4768-3606","observed_orcids":["https://orcid.org/0000-0003-4768-3606"]},"institutions":[{"id":"https://openalex.org/I99464096","display_name":"KU Leuven","ror":"https://ror.org/05f950310","country_code":"BE","type":"education","lineage":["https://openalex.org/I99464096"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Koen Binnemans","raw_affiliation_strings":["Laboratory of Coordination Chemistry, Department of Chemistry, K.U. Leuven, Celestijnenlaan 200F, P.O. Box 2404, 3001 Leuven (Belgium)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Coordination Chemistry, Department of Chemistry, K.U. Leuven, Celestijnenlaan 200F, P.O. Box 2404, 3001 Leuven (Belgium)","institution_ids":["https://openalex.org/I99464096"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5077238999","display_name":"Dirk E De Vos","orcid":"https://orcid.org/0000-0003-0490-9652","observed_orcids":["https://orcid.org/0000-0003-0490-9652"]},"institutions":[{"id":"https://openalex.org/I99464096","display_name":"KU Leuven","ror":"https://ror.org/05f950310","country_code":"BE","type":"education","lineage":["https://openalex.org/I99464096"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Dirk\u2005E. De\u2005Vos","raw_affiliation_strings":["Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, PO Box 2461, 3001 Leuven (Belgium),","institution_ids":["https://openalex.org/I99464096"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I99464096"],"apc_list":{"value":4550,"currency":"USD","value_usd":4550},"apc_paid":null,"fwci":3.6884,"has_fulltext":false,"cited_by_count":67,"citation_normalized_percentile":{"value":0.93748392,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"3","issue":"1","first_page":"91","last_page":"96"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":0.7333999872207642,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":0.7333999872207642,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10480","display_name":"Ionic liquids properties and applications","score":0.2150000035762787,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10171","display_name":"Biofuel production and bioconversion","score":0.02199999988079071,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cellulose-depolymerization","display_name":"cellulose depolymerization","score":0.9559999704360962},{"id":"https://openalex.org/keywords/ionic-liquids","display_name":"ionic liquids","score":0.8140000104904175},{"id":"https://openalex.org/keywords/1-butyl-3-methylimidazolium-chloride","display_name":"1-butyl-3-methylimidazolium chloride","score":1.0},{"id":"https://openalex.org/keywords/hydrogen-transfer","display_name":"hydrogen transfer","score":0.574999988079071},{"id":"https://openalex.org/keywords/heterogeneous-metal-catalysts","display_name":"heterogeneous metal catalysts","score":0.7440000176429749},{"id":"https://openalex.org/keywords/cellobiose","display_name":"cellobiose","score":0.996999979019165},{"id":"https://openalex.org/keywords/sorbitol","display_name":"sorbitol","score":0.9570000171661377},{"id":"https://openalex.org/keywords/biomass-conversion","display_name":"biomass conversion","score":0.5080000162124634}],"concepts":[{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.9505033493041992},{"id":"https://openalex.org/C49852136","wikidata":"https://www.wikidata.org/wiki/Q906487","display_name":"Depolymerization","level":2,"score":0.8469372987747192},{"id":"https://openalex.org/C2779251873","wikidata":"https://www.wikidata.org/wiki/Q80294","display_name":"Cellulose","level":2,"score":0.8353254795074463},{"id":"https://openalex.org/C2780412358","wikidata":"https://www.wikidata.org/wiki/Q409017","display_name":"Cellobiose","level":4,"score":0.7118352651596069},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7070042490959167},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6712157130241394},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.6204879879951477},{"id":"https://openalex.org/C2778695967","wikidata":"https://www.wikidata.org/wiki/Q44791900","display_name":"Chloride","level":2,"score":0.5581251978874207},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5450263023376465},{"id":"https://openalex.org/C2781087020","wikidata":"https://www.wikidata.org/wiki/Q211086","display_name":"Hydrogen chloride","level":2,"score":0.53792405128479},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.47569048404693604},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.4452701807022095},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4413193464279175},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4347516596317291},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3268664479255676},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.19680854678153992},{"id":"https://openalex.org/C141603559","wikidata":"https://www.wikidata.org/wiki/Q410324","display_name":"Cellulase","level":3,"score":0.10252350568771362},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D002475","descriptor_name":"Cellobiose","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D002482","descriptor_name":"Cellulose","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D003508","descriptor_name":"Cycloheptanes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D005019","descriptor_name":"Ethyl Ethers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D006859","descriptor_name":"Hydrogen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D007093","descriptor_name":"Imidazoles","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012428","descriptor_name":"Ruthenium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D012995","descriptor_name":"Solubility","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013012","descriptor_name":"Sorbitol","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D013696","descriptor_name":"Temperature","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D052578","descriptor_name":"Ionic Liquids","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D055162","descriptor_name":"Biocatalysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":3,"locations":[{"id":"doi:10.1002/cssc.200900213","doi":"https://doi.org/10.1002/cssc.200900213","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cssc.200900213","pdf_url":null,"source":{"id":"https://openalex.org/S193447295","display_name":"ChemSusChem","issn_l":"1864-5631","issn":["1864-5631","1864-564X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemSusChem","raw_type":"journal-article"},{"id":"pmid:20049766","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/20049766","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemSusChem","raw_type":"Journal Article"},{"id":"pmh:oai:lirias2repo.kuleuven.be:123456789/262099","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/20049766","pdf_url":null,"source":{"id":"https://openalex.org/S7407055369","display_name":"Lirias","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ChemSusChem: Chemistry & Sustainability, Energy & Materials, vol. 3 (1), (91-96)","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","display_name":"Responsible consumption and production","score":0.5925999879837036},{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.5690000057220459}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":65,"referenced_works":["https://openalex.org/W600148124","https://openalex.org/W1966669239","https://openalex.org/W1968707830","https://openalex.org/W1975527874","https://openalex.org/W1980836177","https://openalex.org/W1983099985","https://openalex.org/W1983496093","https://openalex.org/W1984769267","https://openalex.org/W1987931160","https://openalex.org/W1990319336","https://openalex.org/W1992293247","https://openalex.org/W1992460702","https://openalex.org/W1997722813","https://openalex.org/W2000692841","https://openalex.org/W2000800395","https://openalex.org/W2010682907","https://openalex.org/W2013356455","https://openalex.org/W2015403706","https://openalex.org/W2017765446","https://openalex.org/W2018097443","https://openalex.org/W2020218915","https://openalex.org/W2023227463","https://openalex.org/W2027376271","https://openalex.org/W2043117267","https://openalex.org/W2043547629","https://openalex.org/W2047615003","https://openalex.org/W2050690904","https://openalex.org/W2057644245","https://openalex.org/W2061499109","https://openalex.org/W2063756264","https://openalex.org/W2064799493","https://openalex.org/W2068708018","https://openalex.org/W2070488141","https://openalex.org/W2073095158","https://openalex.org/W2073930643","https://openalex.org/W2074374289","https://openalex.org/W2076577388","https://openalex.org/W2084726128","https://openalex.org/W2085193495","https://openalex.org/W2086113831","https://openalex.org/W2087593192","https://openalex.org/W2088826850","https://openalex.org/W2090259321","https://openalex.org/W2107819541","https://openalex.org/W2113553543","https://openalex.org/W2115595224","https://openalex.org/W2117140479","https://openalex.org/W2124373921","https://openalex.org/W2125519621","https://openalex.org/W2130743093","https://openalex.org/W2131382161","https://openalex.org/W2147281365","https://openalex.org/W2148823926","https://openalex.org/W2149276351","https://openalex.org/W2155649389","https://openalex.org/W2157453825","https://openalex.org/W2163075518","https://openalex.org/W2165861896","https://openalex.org/W2165913304","https://openalex.org/W2322309501","https://openalex.org/W2334692551","https://openalex.org/W2950881692","https://openalex.org/W4210262044","https://openalex.org/W4244640408","https://openalex.org/W4252928458"],"related_works":["https://openalex.org/W2521329747","https://openalex.org/W2124444489","https://openalex.org/W15831872","https://openalex.org/W2117140479","https://openalex.org/W7111786043","https://openalex.org/W2127692491","https://openalex.org/W4249421390","https://openalex.org/W2058565291","https://openalex.org/W1977230149","https://openalex.org/W2073930643"],"abstract_inverted_index":{"The":[0,70],"depolymerization":[1,32],"of":[2,16,33,38,51,55,64],"cellulose":[3,34,71],"is":[4,59,72],"carried":[5],"out":[6],"in":[7,13,85],"the":[8,14,20,31,36,52,56,62,67,82],"ionic":[9],"liquid":[10],"1-butyl-3-methylimidazolium":[11],"chloride":[12],"presence":[15],"hydrogen":[17,65],"gas.":[18],"First,":[19],"ketal":[21],"1,1-diethoxycyclohexane":[22],"and":[23,43],"cellobiose":[24],"were":[25],"used":[26],"as":[27,81],"model":[28],"substrates.":[29],"For":[30],"itself,":[35],"combination":[37],"a":[39,44],"heterogeneous":[40],"metal":[41],"catalyst":[42,47],"homogeneous":[45],"ruthenium":[46,57],"proved":[48],"effective.":[49],"One":[50],"possible":[53],"roles":[54],"compound":[58],"to":[60,66],"enhance":[61],"transfer":[63],"metallic":[68],"surface.":[69],"fully":[73],"converted":[74],"under":[75],"relatively":[76],"mild":[77],"conditions,":[78],"with":[79],"sorbitol":[80],"dominant":[83],"product":[84],"51-74%":[86],"yield.":[87]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":11},{"year":2013,"cited_by_count":7},{"year":2012,"cited_by_count":7}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}