{"id":"https://openalex.org/W2160255191","doi":"https://doi.org/10.1039/a908410j","title":"Kinetics and mechanism of the chromium(VI) oxidation of methyl \u03b1-D-glucopyranoside and methyl \u03b1-D-mannopyranoside \u2020","display_name":"Kinetics and mechanism of the chromium(VI) oxidation of methyl \u03b1-D-glucopyranoside and methyl \u03b1-D-mannopyranoside \u2020","publication_year":2000,"publication_date":"2000-01-01","ids":{"openalex":"https://openalex.org/W2160255191","doi":"https://doi.org/10.1039/a908410j","mag":"2160255191"},"language":"en","primary_location":{"id":"doi:10.1039/a908410j","doi":"https://doi.org/10.1039/a908410j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a908410j","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5029170202","display_name":"Sandra Signorella","orcid":"https://orcid.org/0000-0002-1547-6891","observed_orcids":["https://orcid.org/0000-0002-1547-6891"]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Sandra Signorella","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110014795","display_name":"Mar\u00eda In\u00e9s Frascaroli","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Mar\u00eda In\u00e9s Frascaroli","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Silvia Garc\u00eda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Silvia Garc\u00eda","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015502608","display_name":"Mabel Santoro","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Mabel Santoro","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022815688","display_name":"Juan Carlos Gonz\u00e1lez","orcid":"https://orcid.org/0000-0003-2314-7980","observed_orcids":["https://orcid.org/0000-0003-2314-7980"]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Juan Carlos Gonz\u00e1lez","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046276188","display_name":"Claudia M. Palopoli","orcid":"https://orcid.org/0000-0002-8185-6841","observed_orcids":["https://orcid.org/0000-0002-8185-6841"]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Claudia Palopoli","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087517265","display_name":"Ver\u00f3nica Daier","orcid":"https://orcid.org/0000-0002-4041-502X","observed_orcids":["https://orcid.org/0000-0002-4041-502X"]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Ver\u00f3nica Daier","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110265290","display_name":"Nieves M. C. Casado","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210102755","display_name":"Instituto de Desarrollo Tecnol\u00f3gico para la Industria Qu\u00edmica","ror":"https://ror.org/01kwwh635","country_code":"AR","type":"facility","lineage":["https://openalex.org/I151201029","https://openalex.org/I3121987637","https://openalex.org/I4210087694","https://openalex.org/I4210102755","https://openalex.org/I4210123736","https://openalex.org/I4387155568"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Nieves Casado","raw_affiliation_strings":["Instituto de Desarrollo Tecnol\u00f3gico para la Industria Qu\u00edmica, G\u00fcemes 3450, Santa Fe, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Instituto de Desarrollo Tecnol\u00f3gico para la Industria Qu\u00edmica, G\u00fcemes 3450, Santa Fe, Argentina","institution_ids":["https://openalex.org/I4210102755"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5031900681","display_name":"Luis Federico Sala","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4141589","display_name":"National University of Rosario","ror":"https://ror.org/02tphfq59","country_code":"AR","type":"education","lineage":["https://openalex.org/I4141589"]}],"countries":["AR"],"is_corresponding":true,"raw_author_name":"Luis F. Sala","raw_affiliation_strings":["Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Facultad de Ciencias Bioqu\u00edmicas y Farmac\u00e9uticas, UNR, Suipacha 531, Rosario, Argentina","institution_ids":["https://openalex.org/I4141589"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5031900681"],"corresponding_institution_ids":["https://openalex.org/I4141589"],"apc_list":null,"apc_paid":null,"fwci":1.1607,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.74740671,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":null,"issue":"10","first_page":"1617","last_page":"1623"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.3118000030517578,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.3118000030517578,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.24369999766349792,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.20000000298023224,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chromium-vi-oxidation","display_name":"chromium(VI) oxidation","score":0.9700000286102295},{"id":"https://openalex.org/keywords/methyl-alpha-d-glucopyranoside","display_name":"methyl \u03b1-D-glucopyranoside","score":0.953000009059906},{"id":"https://openalex.org/keywords/methyl-alpha-d-mannopyranoside","display_name":"methyl \u03b1-D-mannopyranoside","score":1.0},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.7129999995231628},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.871999979019165},{"id":"https://openalex.org/keywords/chromium-v-intermediate","display_name":"chromium(V) intermediate","score":0.656000018119812},{"id":"https://openalex.org/keywords/redox-reactions","display_name":"redox reactions","score":0.36899998784065247},{"id":"https://openalex.org/keywords/acid-effect","display_name":"acid effect","score":0.3449999988079071},{"id":"https://openalex.org/keywords/rate-law","display_name":"rate law","score":0.5820000171661377}],"concepts":[{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.7673513889312744},{"id":"https://openalex.org/C511782168","wikidata":"https://www.wikidata.org/wiki/Q725","display_name":"Chromium","level":2,"score":0.7020303606987},{"id":"https://openalex.org/C89611455","wikidata":"https://www.wikidata.org/wiki/Q6804646","display_name":"Mechanism (biology)","level":2,"score":0.6824830174446106},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6355891823768616},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.15636011958122253},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.09100276231765747},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/a908410j","doi":"https://doi.org/10.1039/a908410j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a908410j","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320310213","display_name":"Fundaci\u00f3n Antorchas","ror":"https://ror.org/00bgqc639"},{"id":"https://openalex.org/F4320320671","display_name":"National Research Foundation","ror":"https://ror.org/05s0g1g46"},{"id":"https://openalex.org/F4320324112","display_name":"Third World Academy of Sciences","ror":"https://ror.org/00twbd828"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W1964193431","https://openalex.org/W1964973617","https://openalex.org/W1965655464","https://openalex.org/W1966746874","https://openalex.org/W1970511748","https://openalex.org/W1976513248","https://openalex.org/W1984275131","https://openalex.org/W1987881083","https://openalex.org/W2000619502","https://openalex.org/W2002665543","https://openalex.org/W2005726129","https://openalex.org/W2015702419","https://openalex.org/W2016677181","https://openalex.org/W2017350338","https://openalex.org/W2024756447","https://openalex.org/W2033182067","https://openalex.org/W2034915767","https://openalex.org/W2036709777","https://openalex.org/W2038100090","https://openalex.org/W2039566819","https://openalex.org/W2048832974","https://openalex.org/W2051595393","https://openalex.org/W2054548548","https://openalex.org/W2077514296","https://openalex.org/W2087159469","https://openalex.org/W2092292656","https://openalex.org/W2130546974","https://openalex.org/W2153577006","https://openalex.org/W2169649544","https://openalex.org/W2320362942","https://openalex.org/W2325916028","https://openalex.org/W2950870908","https://openalex.org/W2952488330","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W2027889956","https://openalex.org/W2008812265","https://openalex.org/W2083091636","https://openalex.org/W2006314394","https://openalex.org/W2000619502","https://openalex.org/W2027172059","https://openalex.org/W2141016165","https://openalex.org/W2948332414","https://openalex.org/W2092292656","https://openalex.org/W2557354512"],"abstract_inverted_index":{"The":[0,31,56],"oxidation":[1],"of":[2,23,140],"methyl":[3,7,15,25],"\u03b1-D-glucopyranoside":[4],"(Glc1Me)":[5],"and":[6,14,41,80,97,125,132],"\u03b1-D-mannopyranoside":[8],"(Man1Me)":[9],"by":[10,129],"CrVI":[11,28,36,42,121],"yielded":[12],"Cr3+":[13],"\u03b1-D-glycofuranurono-6,3-lactone":[16],"as":[17],"final":[18],"products":[19],"when":[20],"an":[21],"excess":[22],"the":[24,48,52,61,117,133,138,146],"glycoside":[26],"over":[27],"was":[29],"used.":[30],"redox":[32,54,62],"reaction":[33],"occurs":[34],"through":[35],"\u2192":[37,39,43,45],"CrIV":[38],"CrIII":[40,46],"CrV":[44,114],"paths,":[47],"CrVI/CrIV":[49],"reduction":[50],"being":[51],"slow":[53],"step.":[55],"complete":[57],"rate":[58],"laws":[59],"for":[60],"reactions":[63],"are":[64],"expressed":[65],"by:":[66],"\u2212d[CrVI]/dt":[67,81],"=":[68,72,82,89,99],"kGH[H+]2[Glc1Me][CrVI],":[69],"where":[70,87],"kGH":[71],"(6.75":[73],"\u00b1":[74,91,101],"0.05)":[75],"\u00d7":[76,93,103],"10\u22123":[77,104],"M\u22123":[78,105],"s\u22121;":[79],"(kM0":[83],"+":[84],"kMH":[85,98],"[H+]2)[Man1Me][CrVI],":[86],"kM0":[88],"(5":[90],"1)":[92],"10\u22124":[94],"M\u22121":[95],"s\u22121":[96],"(6.5":[100],"0.2)":[102],"s\u22121,":[106],"at":[107],"40":[108],"\u00b0C.":[109],"In":[110],"acid":[111],"medium,":[112],"intermediate":[113],"reacts":[115],"with":[116],"substrate":[118],"faster":[119],"than":[120],"does.":[122],"Chromium(V)":[123],"mono-":[124],"bis-chelates":[126],"were":[127],"detected":[128],"EPR":[130,134],"spectroscopy,":[131],"spectra":[135],"show":[136],"that":[137],"distribution":[139],"these":[141],"species":[142],"essentially":[143],"depends":[144],"on":[145],"solution":[147],"acidity.":[148]},"counts_by_year":[{"year":2018,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}
