{"id":"https://openalex.org/W2159731685","doi":"https://doi.org/10.1021/ja00033a038","title":"Differential metal ion stabilization of reactants and transition states in the transacylation of crown ether aryl acetates","display_name":"Differential metal ion stabilization of reactants and transition states in the transacylation of crown ether aryl acetates","publication_year":1992,"publication_date":"1992-03-01","ids":{"openalex":"https://openalex.org/W2159731685","doi":"https://doi.org/10.1021/ja00033a038","mag":"2159731685"},"language":"en","primary_location":{"id":"doi:10.1021/ja00033a038","doi":"https://doi.org/10.1021/ja00033a038","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00033a038","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://research.utwente.nl/files/176072682/ja00033a038.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5034334632","display_name":"Roberta Cacciapaglia","orcid":"https://orcid.org/0000-0002-3119-4851","observed_orcids":["https://orcid.org/0000-0002-3119-4851"]},"institutions":[{"id":"https://openalex.org/I861853513","display_name":"Sapienza University of Rome","ror":"https://ror.org/02be6w209","country_code":"IT","type":"education","lineage":["https://openalex.org/I861853513"]},{"id":"https://openalex.org/I94624287","display_name":"University of Twente","ror":"https://ror.org/006hf6230","country_code":"NL","type":"education","lineage":["https://openalex.org/I94624287"]}],"countries":["IT","NL"],"is_corresponding":false,"raw_author_name":"Roberta Cacciapaglia","raw_affiliation_strings":["Contribution from Centro CNR Meccanismi di Reazione and Dipartimento di Chimica, Universita la Sapienza, 00185 Roma, Italy, and Laboratory of Organic Chemistry,","University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from Centro CNR Meccanismi di Reazione and Dipartimento di Chimica, Universita la Sapienza, 00185 Roma, Italy, and Laboratory of Organic Chemistry,","institution_ids":["https://openalex.org/I861853513"]},{"raw_affiliation_string":"University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands","institution_ids":["https://openalex.org/I94624287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072072373","display_name":"Arie R. Van Doorn","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Arie R. Van Doorn","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016493387","display_name":"Luigi Mandolini","orcid":"https://orcid.org/0000-0003-0511-3680","observed_orcids":["https://orcid.org/0000-0003-0511-3680"]},"institutions":[{"id":"https://openalex.org/I94624287","display_name":"University of Twente","ror":"https://ror.org/006hf6230","country_code":"NL","type":"education","lineage":["https://openalex.org/I94624287"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Luigi Mandolini","raw_affiliation_strings":["Universita la Sapienza. * University of Twente"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita la Sapienza. * University of Twente","institution_ids":["https://openalex.org/I94624287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112298693","display_name":"David N. Reinhoudt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I94624287","display_name":"University of Twente","ror":"https://ror.org/006hf6230","country_code":"NL","type":"education","lineage":["https://openalex.org/I94624287"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"David N. Reinhoudt","raw_affiliation_strings":["Universita la Sapienza. * University of Twente"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita la Sapienza. * University of Twente","institution_ids":["https://openalex.org/I94624287"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054594631","display_name":"Willem Verboom","orcid":"https://orcid.org/0000-0002-6863-8655","observed_orcids":["https://orcid.org/0000-0002-6863-8655","https://orcid.org/0000-0002-6874-3842"]},"institutions":[{"id":"https://openalex.org/I861853513","display_name":"Sapienza University of Rome","ror":"https://ror.org/02be6w209","country_code":"IT","type":"education","lineage":["https://openalex.org/I861853513"]},{"id":"https://openalex.org/I94624287","display_name":"University of Twente","ror":"https://ror.org/006hf6230","country_code":"NL","type":"education","lineage":["https://openalex.org/I94624287"]}],"countries":["IT","NL"],"is_corresponding":false,"raw_author_name":"Willem Verboom","raw_affiliation_strings":["Contribution from Centro CNR Meccanismi di Reazione and Dipartimento di Chimica, Universita la Sapienza, 00185 Roma, Italy, and Laboratory of Organic Chemistry,","University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from Centro CNR Meccanismi di Reazione and Dipartimento di Chimica, Universita la Sapienza, 00185 Roma, Italy, and Laboratory of Organic Chemistry,","institution_ids":["https://openalex.org/I861853513"]},{"raw_affiliation_string":"University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands","institution_ids":["https://openalex.org/I94624287"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.1511,"has_fulltext":true,"cited_by_count":34,"citation_normalized_percentile":{"value":0.95412562,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"114","issue":"7","first_page":"2611","last_page":"2617"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8633000254631042,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8633000254631042,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.08250000327825546,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.01940000057220459,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/transacylation","display_name":"transacylation","score":0.8069999814033508},{"id":"https://openalex.org/keywords/metal-ion-catalysis","display_name":"metal ion catalysis","score":0.8610000014305115},{"id":"https://openalex.org/keywords/metal-ion-stabilization","display_name":"metal ion stabilization","score":0.6890000104904175},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.7770000100135803},{"id":"https://openalex.org/keywords/reaction-intermediates","display_name":"reaction intermediates","score":0.4519999921321869},{"id":"https://openalex.org/keywords/acyl-transfer","display_name":"acyl transfer","score":0.39800000190734863},{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.3709999918937683}],"concepts":[{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.6686854362487793},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.6226520538330078},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.483376681804657},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.4452388286590576},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.421234667301178},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.2901133894920349},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.21079948544502258},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.20443060994148254},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/ja00033a038","doi":"https://doi.org/10.1021/ja00033a038","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00033a038","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmh:oai:iris.uniroma1.it:11573/462288","doi":null,"is_oa":false,"landing_page_url":"http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=A1992HK67100038&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=0c7ff228ccbaaa74236f48834a34396a","pdf_url":null,"source":{"id":"https://openalex.org/S4377196107","display_name":"IRIS Research product catalog (Sapienza University of Rome)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:ris.utwente.nl:openaire/02cb5f7c-b156-46ce-b788-5bb449fd6f74","doi":null,"is_oa":true,"landing_page_url":"https://research.utwente.nl/files/176072682/ja00033a038.pdf","pdf_url":null,"source":{"id":"https://openalex.org/S4406922991","display_name":"University of Twente Research Information","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Cacciapaglia, R, van Doorn, A R, Mandolini, L, Reinhoudt, D N & Verboom, W 1992, 'Differential metal ion stabilization of reactants and transition states in the transacylation of crown ether aryl acetates', Journal of the American Chemical Society, vol. 114, no. 7, pp. 2611-2617. https://doi.org/10.1021/ja00033a038","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:ut:oai:ris.utwente.nl:publications/02cb5f7c-b156-46ce-b788-5bb449fd6f74","doi":null,"is_oa":true,"landing_page_url":"https://research.utwente.nl/en/publications/02cb5f7c-b156-46ce-b788-5bb449fd6f74","pdf_url":null,"source":{"id":"https://openalex.org/S4406922991","display_name":"University of Twente Research Information","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society, 114(7), 2611 - 2617. American Chemical Society","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:ris.utwente.nl:openaire/02cb5f7c-b156-46ce-b788-5bb449fd6f74","doi":null,"is_oa":true,"landing_page_url":"https://research.utwente.nl/files/176072682/ja00033a038.pdf","pdf_url":null,"source":{"id":"https://openalex.org/S4406922991","display_name":"University of Twente Research Information","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Cacciapaglia, R, van Doorn, A R, Mandolini, L, Reinhoudt, D N & Verboom, W 1992, 'Differential metal ion stabilization of reactants and transition states in the transacylation of crown ether aryl acetates', Journal of the American Chemical Society, vol. 114, no. 7, pp. 2611-2617. https://doi.org/10.1021/ja00033a038","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":2,"referenced_works":["https://openalex.org/W2613467369","https://openalex.org/W4240446580"],"related_works":["https://openalex.org/W2033868374","https://openalex.org/W2029520749","https://openalex.org/W7036562115","https://openalex.org/W1581353363","https://openalex.org/W2950579696","https://openalex.org/W1973216464","https://openalex.org/W4220854611","https://openalex.org/W2275207057","https://openalex.org/W4230638863","https://openalex.org/W2918175963"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTDifferential":[3],"metal":[4],"ion":[5],"stabilization":[6],"of":[7,15,67,102,128],"reactants":[8],"and":[9,30,77,82,111,155,172,188,190],"transition":[10],"states":[11],"in":[12],"the":[13,64,95,100,129,140,153,156,161,168,174],"transacylation":[14],"crown":[16],"ether":[17],"aryl":[18],"acetatesRoberta":[19],"Cacciapaglia,":[20],"Arie":[21],"R.":[22],"Van":[23],"Doorn,":[24],"Luigi":[25],"Mandolini,":[26],"David":[27],"N.":[28],"Reinhoudt,":[29],"Willem":[31],"VerboomCite":[32],"this:":[33],"J.":[34],"Am.":[35],"Chem.":[36],"Soc.":[37],"1992,":[38],"114,":[39],"7,":[40],"2611\u20132617Publication":[41],"Date":[42],"(Print):March":[43],"1,":[44],"1992Publication":[45],"History":[46],"Published":[47],"online1":[48],"May":[49],"2002Published":[50],"inissue":[51],"1":[52],"March":[53],"1992https://pubs.acs.org/doi/10.1021/ja00033a038https://doi.org/10.1021/ja00033a038research-articleACS":[54],"PublicationsRequest":[55],"reuse":[56],"permissionsArticle":[57],"Views138Altmetric-Citations26LEARN":[58],"ABOUT":[59],"THESE":[60],"METRICSArticle":[61],"Views":[62],"are":[63,86,99],"COUNTER-compliant":[65],"sum":[66],"full":[68],"text":[69],"article":[70,134],"downloads":[71],"since":[72],"November":[73],"2008":[74],"(both":[75],"PDF":[76],"HTML)":[78],"across":[79],"all":[80],"institutions":[81],"individuals.":[83],"These":[84],"metrics":[85],"regularly":[87],"updated":[88,112],"to":[89,94],"reflect":[90],"usage":[91],"leading":[92],"up":[93],"last":[96],"few":[97],"days.Citations":[98],"number":[101],"other":[103],"articles":[104],"citing":[105],"this":[106],"article,":[107],"calculated":[108],"by":[109],"Crossref":[110,118],"daily.":[113],"Find":[114,164],"more":[115,165],"information":[116,166],"about":[117,152],"citation":[119],"counts.The":[120],"Altmetric":[121,169],"Attention":[122,170],"Score":[123,171],"is":[124,176],"a":[125,132,145],"quantitative":[126],"measure":[127],"attention":[130],"that":[131],"research":[133],"has":[135],"received":[136],"online.":[137],"Clicking":[138],"on":[139,167],"donut":[141],"icon":[142],"will":[143],"load":[144],"page":[146],"at":[147],"altmetric.com":[148],"with":[149,184],"additional":[150],"details":[151],"score":[154,175],"social":[157],"media":[158],"presence":[159],"for":[160],"given":[162],"article.":[163],"how":[173],"calculated.":[177],"Share":[178,193],"Add":[179],"toView":[180],"InAdd":[181],"Full":[182],"Text":[183],"ReferenceAdd":[185],"Description":[186],"ExportRISCitationCitation":[187],"abstractCitation":[189],"referencesMore":[191],"Options":[192],"onFacebookTwitterWechatLinked":[194],"InRedditEmail":[195],"Other":[196],"access":[197],"optionsGet":[198],"e-AlertscloseSupporting":[199],"Info":[200],"(1)\u00bbSupporting":[201],"Information":[202,204],"Supporting":[203],"Get":[205],"e-Alerts":[206]},"counts_by_year":[{"year":2019,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-26T08:19:03.415552","created_date":"2016-06-24T00:00:00"}