{"id":"https://openalex.org/W2159389688","doi":"https://doi.org/10.1039/b200061j","title":"IR laser-induced thermolysis of (chloromethyl)silane: complex reaction involving H2Si:, H2C: and HClSi: transients and yielding nanostructured Si/C/H phases","display_name":"IR laser-induced thermolysis of (chloromethyl)silane: complex reaction involving H2Si:, H2C: and HClSi: transients and yielding nanostructured Si/C/H phases","publication_year":2002,"publication_date":"2002-03-22","ids":{"openalex":"https://openalex.org/W2159389688","doi":"https://doi.org/10.1039/b200061j","mag":"2159389688"},"language":"en","primary_location":{"id":"doi:10.1039/b200061j","doi":"https://doi.org/10.1039/b200061j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b200061j","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5080451771","display_name":"Josef Pola","orcid":"https://orcid.org/0000-0003-2430-1214","observed_orcids":["https://orcid.org/0000-0003-2430-1214"]},"institutions":[{"id":"https://openalex.org/I202391551","display_name":"Czech Academy of Sciences","ror":"https://ror.org/053avzc18","country_code":"CZ","type":"government","lineage":["https://openalex.org/I202391551"]},{"id":"https://openalex.org/I4210118944","display_name":"Czech Academy of Sciences, Institute of Chemical Process Fundamentals","ror":"https://ror.org/02acv3g39","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}],"countries":["CZ"],"is_corresponding":true,"raw_author_name":"Josef Pola","raw_affiliation_strings":["Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic","institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103710053","display_name":"Magna G. Santos","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210158687","display_name":"Instituto de Estructura de la Materia","ror":"https://ror.org/05rtchs68","country_code":"ES","type":"facility","lineage":["https://openalex.org/I4210158687"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Magna Santos","raw_affiliation_strings":["Instituto de Estructura de la Materia, C. S.I. C., Serrano 121, Madrid, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Instituto de Estructura de la Materia, C. S.I. C., Serrano 121, Madrid, Spain","institution_ids":["https://openalex.org/I4210158687"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102761556","display_name":"Luis Diaz","orcid":"https://orcid.org/0000-0002-9622-1523","observed_orcids":["https://orcid.org/0000-0002-9622-1523"]},"institutions":[{"id":"https://openalex.org/I4210158687","display_name":"Instituto de Estructura de la Materia","ror":"https://ror.org/05rtchs68","country_code":"ES","type":"facility","lineage":["https://openalex.org/I4210158687"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Luis D\u00edaz","raw_affiliation_strings":["Instituto de Estructura de la Materia, C. S.I. C., Serrano 121, Madrid, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Instituto de Estructura de la Materia, C. S.I. C., Serrano 121, Madrid, Spain","institution_ids":["https://openalex.org/I4210158687"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045248109","display_name":"Krist\u00fdna Jurs\u00edkov\u00e1","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I202391551","display_name":"Czech Academy of Sciences","ror":"https://ror.org/053avzc18","country_code":"CZ","type":"government","lineage":["https://openalex.org/I202391551"]},{"id":"https://openalex.org/I4210118944","display_name":"Czech Academy of Sciences, Institute of Chemical Process Fundamentals","ror":"https://ror.org/02acv3g39","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Krist\u00fdna Jurs\u00edkov\u00e1","raw_affiliation_strings":["Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic","institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078945039","display_name":"Zden\u0115k Bastl","orcid":"https://orcid.org/0000-0001-6857-4324","observed_orcids":["https://orcid.org/0000-0001-6857-4324"]},"institutions":[{"id":"https://openalex.org/I4210127897","display_name":"Czech Academy of Sciences, Heyrovsky Institute","ror":"https://ror.org/02sat5y74","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210127897"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Zden\u011bk Bastl","raw_affiliation_strings":["J. Heyrovsk\u00fd Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"J. Heyrovsk\u00fd Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic","institution_ids":["https://openalex.org/I4210127897"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112212264","display_name":"Jaroslav Boh\u00e1\u010dek","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I202391551","display_name":"Czech Academy of Sciences","ror":"https://ror.org/053avzc18","country_code":"CZ","type":"government","lineage":["https://openalex.org/I202391551"]},{"id":"https://openalex.org/I4210106307","display_name":"Czech Academy of Sciences, Institute of Inorganic Chemistry","ror":"https://ror.org/01hsjcv06","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210106307"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Jaroslav Boh\u00e1\u010dek","raw_affiliation_strings":["Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, \u0158e\u017e near Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, \u0158e\u017e near Prague, Czech Republic","institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210106307"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018594029","display_name":"Radek Fajg\u0430r","orcid":"https://orcid.org/0000-0003-4603-1745","observed_orcids":["https://orcid.org/0000-0003-4603-1745","https://orcid.org/0000-0002-5100-7187"]},"institutions":[{"id":"https://openalex.org/I202391551","display_name":"Czech Academy of Sciences","ror":"https://ror.org/053avzc18","country_code":"CZ","type":"government","lineage":["https://openalex.org/I202391551"]},{"id":"https://openalex.org/I4210118944","display_name":"Czech Academy of Sciences, Institute of Chemical Process Fundamentals","ror":"https://ror.org/02acv3g39","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Radek Fajgar","raw_affiliation_strings":["Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic","institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5008636763","display_name":"Mark\u00e9ta Urbanov\u00e1","orcid":"https://orcid.org/0000-0002-4935-0672","observed_orcids":["https://orcid.org/0000-0002-4935-0672"]},"institutions":[{"id":"https://openalex.org/I202391551","display_name":"Czech Academy of Sciences","ror":"https://ror.org/053avzc18","country_code":"CZ","type":"government","lineage":["https://openalex.org/I202391551"]},{"id":"https://openalex.org/I4210118944","display_name":"Czech Academy of Sciences, Institute of Chemical Process Fundamentals","ror":"https://ror.org/02acv3g39","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Mark\u00e9ta Urbanov\u00e1","raw_affiliation_strings":["Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laser Chemistry Group, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic","institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210118944"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5080451771"],"corresponding_institution_ids":["https://openalex.org/I202391551","https://openalex.org/I4210118944"],"apc_list":null,"apc_paid":null,"fwci":0.4402,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.60371759,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"12","issue":"5","first_page":"1519","last_page":"1524"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.14259999990463257,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.14259999990463257,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.13590000569820404,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11169","display_name":"Silicon Nanostructures and Photoluminescence","score":0.12430000305175781,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silylenes","display_name":"silylenes","score":0.9010000228881836},{"id":"https://openalex.org/keywords/carbenes","display_name":"carbenes","score":0.984000027179718},{"id":"https://openalex.org/keywords/polycarbosilane","display_name":"polycarbosilane","score":0.9919999837875366},{"id":"https://openalex.org/keywords/dehydrogenation","display_name":"dehydrogenation","score":0.8700000047683716},{"id":"https://openalex.org/keywords/hcl-elimination","display_name":"HCl elimination","score":0.6639999747276306},{"id":"https://openalex.org/keywords/laser-induced-deposition","display_name":"laser-induced deposition","score":0.3720000088214874}],"concepts":[{"id":"https://openalex.org/C160434732","wikidata":"https://www.wikidata.org/wiki/Q2611095","display_name":"Thermal decomposition","level":2,"score":0.8285794258117676},{"id":"https://openalex.org/C2778024649","wikidata":"https://www.wikidata.org/wiki/Q410572","display_name":"Silane","level":2,"score":0.8274281620979309},{"id":"https://openalex.org/C2776758007","wikidata":"https://www.wikidata.org/wiki/Q7517196","display_name":"Silylene","level":3,"score":0.778335690498352},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.6862000226974487},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.5045970678329468},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4942588806152344},{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.4831344783306122},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.48078054189682007},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.4702804386615753},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.42589622735977173},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.42235225439071655},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3350121080875397},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.251170814037323},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.23533812165260315},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/b200061j","doi":"https://doi.org/10.1039/b200061j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b200061j","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321006","display_name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","ror":"https://ror.org/01pv73b02"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":27,"referenced_works":["https://openalex.org/W1627033107","https://openalex.org/W1964148234","https://openalex.org/W1968003450","https://openalex.org/W1970565595","https://openalex.org/W1984941183","https://openalex.org/W1997076744","https://openalex.org/W1998355984","https://openalex.org/W1999111619","https://openalex.org/W2013494167","https://openalex.org/W2015249338","https://openalex.org/W2019168627","https://openalex.org/W2035458106","https://openalex.org/W2054284344","https://openalex.org/W2054566600","https://openalex.org/W2058512563","https://openalex.org/W2062116445","https://openalex.org/W2063863247","https://openalex.org/W2077634430","https://openalex.org/W2078889331","https://openalex.org/W2082463750","https://openalex.org/W2082494868","https://openalex.org/W2085165644","https://openalex.org/W2085795870","https://openalex.org/W2086837819","https://openalex.org/W2131833958","https://openalex.org/W2158487873","https://openalex.org/W2313738196"],"related_works":["https://openalex.org/W2031369136","https://openalex.org/W1973576468","https://openalex.org/W2163539132","https://openalex.org/W2008051734","https://openalex.org/W1971458772","https://openalex.org/W1975614711","https://openalex.org/W1964355545","https://openalex.org/W2021233496","https://openalex.org/W1998902882","https://openalex.org/W2085795870"],"abstract_inverted_index":{"Multi-pulse":[0],"and":[1,14,17,19,29,41,46,60,69,71],"single-pulse":[2],"infrared":[3],"laser":[4],"induced":[5],"thermolysis":[6],"of":[7,26,32,37,43,67,80],"gaseous":[8],"(chloromethyl)silane,":[9],"H3SiCH2Cl":[10],"occurs":[11],"via":[12],"1,1-HCl":[13],"H2C:":[15,45],"elimination":[16],"dehydrogenation":[18],"yields":[20],"nano-structured":[21],"Si/C/H":[22],"phases":[23],"containing":[24],"most":[25],"the":[27,33,78,81],"Si":[28],"C":[30],"atoms":[31],"precursor.":[34],"The":[35,62],"identification":[36],"final":[38],"volatile":[39],"products":[40],"observation":[42],"H2Si:,":[44],"HClSi:":[47],"transients":[48],"by":[49],"LIF":[50],"spectroscopy":[51],"suggest":[52],"that":[53],"intermediate":[54],"silene":[55],"isomers":[56],"decompose":[57],"into":[58],"silylene":[59],"carbene.":[61],"deposited":[63],"films":[64],"are":[65],"composed":[66],"SiC":[68],"polycarbosilane":[70],"their":[72],"H":[73],"content":[74],"differs":[75],"depending":[76],"on":[77],"mode":[79],"IR":[82],"thermolysis.":[83]},"counts_by_year":[{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2016-06-24T00:00:00"}
