{"id":"https://openalex.org/W2158486063","doi":"https://doi.org/10.1098/rsta.2012.0128","title":"Photochemistry and DNA photocleavage by a new unsupported dirhodium(II,II) complex","display_name":"Photochemistry and DNA photocleavage by a new unsupported dirhodium(II,II) complex","publication_year":2013,"publication_date":"2013-06-18","ids":{"openalex":"https://openalex.org/W2158486063","doi":"https://doi.org/10.1098/rsta.2012.0128","mag":"2158486063","pmid":"https://pubmed.ncbi.nlm.nih.gov/23776291"},"language":"en","primary_location":{"id":"doi:10.1098/rsta.2012.0128","doi":"https://doi.org/10.1098/rsta.2012.0128","is_oa":false,"landing_page_url":"https://doi.org/10.1098/rsta.2012.0128","pdf_url":null,"source":{"id":"https://openalex.org/S99517592","display_name":"Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences","issn_l":"1364-503X","issn":["1364-503X","1471-2962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319787","host_organization_name":"Royal Society","host_organization_lineage":["https://openalex.org/P4310319787"],"host_organization_lineage_names":["Royal Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5022393208","display_name":"Zhanyong Li","orcid":"https://orcid.org/0000-0002-3230-5955","observed_orcids":["https://orcid.org/0000-0002-3230-5955"]},"institutions":[{"id":"https://openalex.org/I91045830","display_name":"Texas A&M University","ror":"https://ror.org/01f5ytq51","country_code":"US","type":"education","lineage":["https://openalex.org/I91045830"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhanyong Li","raw_affiliation_strings":["Department of Chemistry, Texas A&amp;M University, College Station, TX 77840, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Texas A&amp;M University, College Station, TX 77840, USA","institution_ids":["https://openalex.org/I91045830"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016896858","display_name":"Scott J. Burya","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Scott J. Burya","raw_affiliation_strings":["Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA","institution_ids":["https://openalex.org/I52357470"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038676358","display_name":"Claudia Turr\u00f3","orcid":"https://orcid.org/0000-0003-3202-5870","observed_orcids":["https://orcid.org/0000-0003-3202-5870"]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Claudia Turro","raw_affiliation_strings":["Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA","institution_ids":["https://openalex.org/I52357470"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5056201103","display_name":"Kim R. Dunbar","orcid":"https://orcid.org/0000-0001-5728-7805","observed_orcids":["https://orcid.org/0000-0001-5728-7805"]},"institutions":[{"id":"https://openalex.org/I91045830","display_name":"Texas A&M University","ror":"https://ror.org/01f5ytq51","country_code":"US","type":"education","lineage":["https://openalex.org/I91045830"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Kim R. Dunbar","raw_affiliation_strings":["Department of Chemistry, Texas A&amp;M University, College Station, TX 77840, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Texas A&amp;M University, College Station, TX 77840, USA","institution_ids":["https://openalex.org/I91045830"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5038676358","https://openalex.org/A5056201103"],"corresponding_institution_ids":["https://openalex.org/I52357470","https://openalex.org/I91045830"],"apc_list":null,"apc_paid":null,"fwci":1.4277,"has_fulltext":false,"cited_by_count":14,"citation_normalized_percentile":{"value":0.81959173,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"371","issue":"1995","first_page":"20120128","last_page":"20120128"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9735999703407288,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9735999703407288,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T10957","display_name":"Photodynamic Therapy Research Studies","score":0.00570000009611249,"subfield":{"id":"https://openalex.org/subfields/2740","display_name":"Pulmonary and Respiratory Medicine"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.004000000189989805,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dirhodium-ii-complexes","display_name":"dirhodium(II) complexes","score":0.8870000243186951},{"id":"https://openalex.org/keywords/supported-metal-complexes","display_name":"supported metal complexes","score":0.5289999842643738},{"id":"https://openalex.org/keywords/dna-photocleavage","display_name":"DNA photocleavage","score":0.7609999775886536},{"id":"https://openalex.org/keywords/photodynamic-therapy","display_name":"photodynamic therapy","score":0.6480000019073486},{"id":"https://openalex.org/keywords/ligand-dissociation","display_name":"ligand dissociation","score":0.5450000166893005},{"id":"https://openalex.org/keywords/quantum-yield","display_name":"quantum yield","score":0.6359999775886536},{"id":"https://openalex.org/keywords/visible-light-photochemistry","display_name":"visible-light photochemistry","score":0.5889999866485596},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6600000262260437},{"id":"https://openalex.org/keywords/photoproducts","display_name":"photoproducts","score":0.6539999842643738}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7467607855796814},{"id":"https://openalex.org/C175689099","wikidata":"https://www.wikidata.org/wiki/Q908109","display_name":"Homolysis","level":3,"score":0.7464143633842468},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6996397376060486},{"id":"https://openalex.org/C171001562","wikidata":"https://www.wikidata.org/wiki/Q2856048","display_name":"Quantum yield","level":3,"score":0.6192026138305664},{"id":"https://openalex.org/C2777516457","wikidata":"https://www.wikidata.org/wiki/Q2413613","display_name":"Singlet oxygen","level":3,"score":0.6121031641960144},{"id":"https://openalex.org/C40684141","wikidata":"https://www.wikidata.org/wiki/Q902061","display_name":"Electrospray ionization","level":3,"score":0.549415647983551},{"id":"https://openalex.org/C33062035","wikidata":"https://www.wikidata.org/wiki/Q3296863","display_name":"Singlet state","level":3,"score":0.5451937317848206},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.47209829092025757},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4661112427711487},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.45605701208114624},{"id":"https://openalex.org/C111337013","wikidata":"https://www.wikidata.org/wiki/Q2737837","display_name":"Irradiation","level":2,"score":0.45014622807502747},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.42821985483169556},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.35893678665161133},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.31437361240386963},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.19265681505203247},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.15794527530670166},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.1104593276977539},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.091602623462677},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07841265201568604},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D001665","descriptor_name":"Binding Sites","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004247","descriptor_name":"DNA","qualifier_ui":"Q000235","qualifier_name":"genetics","is_major_topic":true},{"descriptor_ui":"D004247","descriptor_name":"DNA","qualifier_ui":"Q000528","qualifier_name":"radiation effects","is_major_topic":false},{"descriptor_ui":"D004247","descriptor_name":"DNA","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008027","descriptor_name":"Light","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010777","descriptor_name":"Photochemistry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D010778","descriptor_name":"Photochemotherapy","qualifier_ui":"Q000639","qualifier_name":"trends","is_major_topic":true},{"descriptor_ui":"D011829","descriptor_name":"Radiation Dosage","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012238","descriptor_name":"Rhodium","qualifier_ui":"Q000528","qualifier_name":"radiation effects","is_major_topic":true},{"descriptor_ui":"D012238","descriptor_name":"Rhodium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1098/rsta.2012.0128","doi":"https://doi.org/10.1098/rsta.2012.0128","is_oa":false,"landing_page_url":"https://doi.org/10.1098/rsta.2012.0128","pdf_url":null,"source":{"id":"https://openalex.org/S99517592","display_name":"Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences","issn_l":"1364-503X","issn":["1364-503X","1471-2962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319787","host_organization_name":"Royal Society","host_organization_lineage":["https://openalex.org/P4310319787"],"host_organization_lineage_names":["Royal Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences","raw_type":"journal-article"},{"id":"pmid:23776291","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23776291","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Philosophical transactions. Series A, Mathematical, physical, and engineering sciences","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":67,"referenced_works":["https://openalex.org/W581732000","https://openalex.org/W612414919","https://openalex.org/W1542265872","https://openalex.org/W1592584163","https://openalex.org/W1965186484","https://openalex.org/W1973537908","https://openalex.org/W1974693247","https://openalex.org/W1976075691","https://openalex.org/W1980411311","https://openalex.org/W1981483717","https://openalex.org/W1981745234","https://openalex.org/W1982779547","https://openalex.org/W1986406178","https://openalex.org/W1989481343","https://openalex.org/W2001942134","https://openalex.org/W2003774307","https://openalex.org/W2012108057","https://openalex.org/W2013673485","https://openalex.org/W2013846138","https://openalex.org/W2015621995","https://openalex.org/W2015631309","https://openalex.org/W2019194950","https://openalex.org/W2030993908","https://openalex.org/W2031346486","https://openalex.org/W2041459118","https://openalex.org/W2042062103","https://openalex.org/W2043213122","https://openalex.org/W2043610941","https://openalex.org/W2047421878","https://openalex.org/W2050917604","https://openalex.org/W2052573265","https://openalex.org/W2053987411","https://openalex.org/W2054473240","https://openalex.org/W2057321488","https://openalex.org/W2062546205","https://openalex.org/W2064296350","https://openalex.org/W2071500982","https://openalex.org/W2072298860","https://openalex.org/W2081495891","https://openalex.org/W2082917109","https://openalex.org/W2088342618","https://openalex.org/W2093361701","https://openalex.org/W2100773105","https://openalex.org/W2104341392","https://openalex.org/W2104785253","https://openalex.org/W2114793325","https://openalex.org/W2115914766","https://openalex.org/W2119291686","https://openalex.org/W2122141445","https://openalex.org/W2124062102","https://openalex.org/W2124531971","https://openalex.org/W2126614953","https://openalex.org/W2127501457","https://openalex.org/W2129248052","https://openalex.org/W2130177169","https://openalex.org/W2134142659","https://openalex.org/W2145213448","https://openalex.org/W2152601731","https://openalex.org/W2156441552","https://openalex.org/W2166189678","https://openalex.org/W2330648439","https://openalex.org/W2332843627","https://openalex.org/W2401137300","https://openalex.org/W2493041787","https://openalex.org/W2952670656","https://openalex.org/W3133924569","https://openalex.org/W4211024586"],"related_works":["https://openalex.org/W2047421878","https://openalex.org/W2150136645","https://openalex.org/W4220803745","https://openalex.org/W7024399611","https://openalex.org/W1667747048","https://openalex.org/W2030993908","https://openalex.org/W2095372566","https://openalex.org/W2099141199","https://openalex.org/W7021137563","https://openalex.org/W2053987411"],"abstract_inverted_index":{"The":[0,57,69],"new":[1],"complex":[2,102],"[Rh2(phen)2(CH3CN)6](BF4)4":[3],"(1)":[4],"was":[5,15,94],"synthesized":[6],"and":[7,11,67],"characterized":[8],"in":[9,25,28,40,78,105],"solution":[10],"its":[12],"crystal":[13],"structure":[14],"determined.":[16],"Irradiation":[17],"of":[18,31,43,53,76,85,124],"1":[19,77,97,111],"with":[20],"visible":[21],"light":[22],"(\u03bbirr>590":[23,98],"nm)":[24],"water":[26],"results":[27],"the":[29,41,50,54,73,89,101,106,122],"release":[30],"two":[32],"equatorial":[33],"CH3CN":[34],"ligands,":[35],"CH3CNeq,":[36],"as":[37,39],"well":[38],"formation":[42],"mononuclear":[44],"radical":[45],"Rh(II)":[46],"fragments":[47],"stemming":[48],"from":[49],"homolytic":[51],"photocleavage":[52,93],"metal-metal":[55],"bond.":[56],"photoproducts,":[58],"identified":[59],"by":[60],"electrospray":[61],"ionization":[62],"mass":[63],"spectrometry,":[64],"include":[65],"[Rh(phen)(CH3CN)(OH)](+)":[66],"[Rh(phen)(CH3CN)(H2O)3(BF4)](+).":[68],"quantum":[70],"yield":[71],"for":[72,96],"photochemical":[74],"transformation":[75],"H2O":[79],"exceeds":[80],"unity":[81],"(\u03a6550":[82],"nm=1.38)":[83],"indicative":[84],"dark":[86],"reactions":[87],"following":[88],"initial":[90],"photoprocess.":[91],"DNA":[92],"observed":[95],"nm),":[99],"whereas":[100],"is":[103],"unreactive":[104],"dark.":[107],"This":[108],"feature":[109],"makes":[110],"a":[112],"promising":[113],"photodynamic":[114],"therapy":[115],"agent":[116],"that":[117],"does":[118],"not":[119],"operate":[120],"via":[121],"production":[123],"singlet":[125],"oxygen,":[126],"1O2.":[127]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":5},{"year":2013,"cited_by_count":3}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}
