{"id":"https://openalex.org/W2156568263","doi":"https://doi.org/10.1039/c39820001359","title":"Stereoelectronic control of the regioselectivity of both electrophilic and nucleophilic substitution of \u03b7 6 -(1,1-dimethylindane)tricarbonyl-chromium(0)","display_name":"Stereoelectronic control of the regioselectivity of both electrophilic and nucleophilic substitution of \u03b7 6 -(1,1-dimethylindane)tricarbonyl-chromium(0)","publication_year":1982,"publication_date":"1982-01-01","ids":{"openalex":"https://openalex.org/W2156568263","doi":"https://doi.org/10.1039/c39820001359","mag":"2156568263"},"language":"en","primary_location":{"id":"doi:10.1039/c39820001359","doi":"https://doi.org/10.1039/c39820001359","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c39820001359","pdf_url":null,"source":{"id":"https://openalex.org/S4210201432","display_name":"Journal of the Chemical Society Chemical Communications","issn_l":"0022-4936","issn":["0022-4936","2050-5639"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Chem. Commun.","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5079306985","display_name":"W. Roy Jackson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"W. Roy Jackson","raw_affiliation_strings":["School of Chemistry"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078485218","display_name":"Ian D. Rae","orcid":"https://orcid.org/0000-0002-7579-3717","observed_orcids":["https://orcid.org/0000-0002-7579-3717"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ian D. Rae","raw_affiliation_strings":["School of Chemistry"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109328116","display_name":"Margaret G. Wong","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Margaret G. Wong","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037542759","display_name":"Martin F. Semmelhack","orcid":"https://orcid.org/0000-0003-0277-3894","observed_orcids":["https://orcid.org/0000-0003-0277-3894"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Martin F. Semmelhack","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5034303034","display_name":"John N. Garcia","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John N. Garcia","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.7974,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.8960396,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":"23","first_page":"1359","last_page":"1360"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.427700012922287,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.427700012922287,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.42579999566078186,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.07769999653100967,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/stereoelectronic-effects","display_name":"stereoelectronic effects","score":0.9160000085830688},{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.9980000257492065},{"id":"https://openalex.org/keywords/electrophilic-substitution","display_name":"electrophilic substitution","score":0.7919999957084656},{"id":"https://openalex.org/keywords/nucleophilic-substitution","display_name":"nucleophilic substitution","score":0.9980000257492065},{"id":"https://openalex.org/keywords/arene-tricarbonylchromium-complexes","display_name":"arene tricarbonylchromium complexes","score":0.847000002861023},{"id":"https://openalex.org/keywords/conformational-analysis","display_name":"conformational analysis","score":0.4300000071525574}],"concepts":[{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.9418952465057373},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8945835828781128},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.7998793125152588},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7825947999954224},{"id":"https://openalex.org/C511782168","wikidata":"https://www.wikidata.org/wiki/Q725","display_name":"Chromium","level":2,"score":0.6222907900810242},{"id":"https://openalex.org/C2777965246","wikidata":"https://www.wikidata.org/wiki/Q899587","display_name":"Electrophilic substitution","level":2,"score":0.5706849098205566},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5461248159408569},{"id":"https://openalex.org/C135731615","wikidata":"https://www.wikidata.org/wiki/Q658656","display_name":"Nucleophilic substitution","level":2,"score":0.5240749716758728},{"id":"https://openalex.org/C111185830","wikidata":"https://www.wikidata.org/wiki/Q503396","display_name":"Substitution reaction","level":2,"score":0.5203118324279785},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.47659987211227417},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.44771096110343933},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.41312795877456665},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.13101479411125183},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0991692841053009}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c39820001359","doi":"https://doi.org/10.1039/c39820001359","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c39820001359","pdf_url":null,"source":{"id":"https://openalex.org/S4210201432","display_name":"Journal of the Chemical Society Chemical Communications","issn_l":"0022-4936","issn":["0022-4936","2050-5639"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Chem. Commun.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2322656899","https://openalex.org/W2020460854","https://openalex.org/W2011215121","https://openalex.org/W2023964865","https://openalex.org/W2096188193","https://openalex.org/W2072179570","https://openalex.org/W7047785488","https://openalex.org/W2017081458","https://openalex.org/W2040385365","https://openalex.org/W2020086770"],"abstract_inverted_index":{"\u03b7":[0],"6":[1],"-(1,1-Dimethylindane)tricarbonylchromium(0)":[2],"reacts":[3],"with":[4,37],"the":[5,19,23,38,47,55],"nucleophile":[6],"LiC(Me)2CN":[7],"at":[8,26],"C-5,":[9],"a":[10,14,59],"position":[11],"eclipsed":[12,32],"by":[13,33],"metal":[15,34],"carbonyl":[16,35],"bond":[17],"in":[18],"preferred":[20,61],"conformation":[21],"of":[22,49,51],"molecule,":[24],"and":[25,28],"C-6":[27],"C-4,":[29],"positions":[30],"not":[31],"bonds":[36],"electrophile":[39],"MeCO+,":[40],"confirming":[41],"that":[42],"stereoelectronic":[43],"effects":[44],"can":[45],"dominate":[46],"regioselectivity":[48],"substitution":[50],"arenetricarbonylchromium":[52],"complexes":[53],"where":[54],"tricarbonyl-chromium":[56],"unit":[57],"adopts":[58],"highly":[60],"conformation.":[62]},"counts_by_year":[],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}
