{"id":"https://openalex.org/W2153998315","doi":"https://doi.org/10.1002/pol.1985.170230203","title":"The relative reactivity of primary and secondary amine hydrogen atoms of aromatic amines with epichlorohydrin and N\u2010 and O\u2010glycidyl compounds","display_name":"The relative reactivity of primary and secondary amine hydrogen atoms of aromatic amines with epichlorohydrin and N\u2010 and O\u2010glycidyl compounds","publication_year":1985,"publication_date":"1985-02-01","ids":{"openalex":"https://openalex.org/W2153998315","doi":"https://doi.org/10.1002/pol.1985.170230203","mag":"2153998315"},"language":"en","primary_location":{"id":"doi:10.1002/pol.1985.170230203","doi":"https://doi.org/10.1002/pol.1985.170230203","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1985.170230203","pdf_url":null,"source":{"id":"https://openalex.org/S4210225168","display_name":"Journal of Polymer Science Polymer Chemistry Edition","issn_l":"0360-6376","issn":["0360-6376","1542-9369"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science: Polymer Chemistry Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011788965","display_name":"Peter Johncock","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"P. Johncock","raw_affiliation_strings":["Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066219593","display_name":"L. Porecha","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"L. Porecha","raw_affiliation_strings":["Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5007358234","display_name":"Graham Tudgey","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"G. F. Tudgey","raw_affiliation_strings":["Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Materials and Structures Department, Royal Aircraft Establishment, Farnborough, England","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":4.5778,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.95968547,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":null,"biblio":{"volume":"23","issue":"2","first_page":"291","last_page":"301"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8095999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8095999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.04050000011920929,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11145","display_name":"Epoxy Resin Curing Processes","score":0.03020000085234642,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/aromatic-amines","display_name":"aromatic amines","score":0.9179999828338623},{"id":"https://openalex.org/keywords/epichlorohydrin","display_name":"epichlorohydrin","score":0.878000020980835},{"id":"https://openalex.org/keywords/glycidyl-ethers","display_name":"glycidyl ethers","score":0.7950000166893005},{"id":"https://openalex.org/keywords/relative-reactivity","display_name":"relative reactivity","score":0.6959999799728394},{"id":"https://openalex.org/keywords/aniline","display_name":"aniline","score":0.9950000047683716},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.6230000257492065},{"id":"https://openalex.org/keywords/catalytic-effect","display_name":"catalytic effect","score":0.5809999704360962},{"id":"https://openalex.org/keywords/steric-effects","display_name":"steric effects","score":0.5680000185966492}],"concepts":[{"id":"https://openalex.org/C2778925040","wikidata":"https://www.wikidata.org/wiki/Q423083","display_name":"Epichlorohydrin","level":2,"score":0.9337543249130249},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.8235233426094055},{"id":"https://openalex.org/C2777977315","wikidata":"https://www.wikidata.org/wiki/Q7243056","display_name":"Primary (astronomy)","level":2,"score":0.8034839630126953},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.769943356513977},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6988581418991089},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.5093461275100708},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.45550987124443054},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4438210129737854},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/pol.1985.170230203","doi":"https://doi.org/10.1002/pol.1985.170230203","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1985.170230203","pdf_url":null,"source":{"id":"https://openalex.org/S4210225168","display_name":"Journal of Polymer Science Polymer Chemistry Edition","issn_l":"0360-6376","issn":["0360-6376","1542-9369"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science: Polymer Chemistry Edition","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W223949962","https://openalex.org/W2039062275","https://openalex.org/W2053350007","https://openalex.org/W2057013040","https://openalex.org/W2085368622","https://openalex.org/W2088730497","https://openalex.org/W2133831029","https://openalex.org/W2158009579"],"related_works":["https://openalex.org/W2051350702","https://openalex.org/W1977487407","https://openalex.org/W2319396244","https://openalex.org/W2323415906","https://openalex.org/W2318749532","https://openalex.org/W2950370628","https://openalex.org/W1500492031","https://openalex.org/W2332188891","https://openalex.org/W1972409906","https://openalex.org/W2331585598"],"abstract_inverted_index":{"Abstract":[0],"The":[1,75],"relative":[2],"value":[3,76],"of":[4,19,24,52,58,71,89,97],"the":[5,9,12,50,56,69,78,87,90],"rate":[6],"constants":[7],"for":[8,55,77],"reactions":[10,57],"between":[11,80],"secondary":[13],"and":[14,23,30,45,82,99],"primary":[15],"amine":[16],"hydrogen":[17],"atoms":[18],"3\u2010trifluoromethylaniline":[20,81],"with":[21,26,31,49,61,68],"epichlorohydrin,":[22],"aniline":[25],"phenyl":[27],"glycidyl":[28],"ether":[29],"some":[32],"N\u2010alkyl\u2010N\u2010glycidylanilines":[33],"were":[34],"determined":[35],"by":[36,86],"HPLC":[37],"analysis.":[38],"Values":[39],"ranged":[40],"from":[41],"0.14":[42],"to":[43],"0.24":[44],"are":[46],"in":[47,65],"agreement":[48],"findings":[51],"earlier":[53],"workers":[54],"aromatic":[59],"amines":[60],"O\u2010glycidyl":[62],"compounds":[63],"but":[64],"direct":[66],"conflict":[67],"claim":[70],"a":[72,94],"recent":[73],"publication.":[74],"reaction":[79],"epichlorohydrin":[83],"was":[84],"unaffected":[85],"nature":[88],"catalyst,":[91],"which":[92],"covered":[93],"wide":[95],"range":[96],"strengths":[98],"steric":[100],"requirements.":[101]},"counts_by_year":[],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}