{"id":"https://openalex.org/W2153131704","doi":"https://doi.org/10.1039/dt9890000403","title":"Preparation and interconversion of dimeric di-\u00b5-hydroxo and tri-\u00b5-hydroxo complexes of platinum( II ) and palladium( II ) with 2,2\u2032-bipyridine and 1,10-phenanthroline","display_name":"Preparation and interconversion of dimeric di-\u00b5-hydroxo and tri-\u00b5-hydroxo complexes of platinum( II ) and palladium( II ) with 2,2\u2032-bipyridine and 1,10-phenanthroline","publication_year":1989,"publication_date":"1989-01-01","ids":{"openalex":"https://openalex.org/W2153131704","doi":"https://doi.org/10.1039/dt9890000403","mag":"2153131704"},"language":"en","primary_location":{"id":"doi:10.1039/dt9890000403","doi":"https://doi.org/10.1039/dt9890000403","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9890000403","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Dalton Trans.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5069174593","display_name":"Smita Wimmer","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Smita Wimmer","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066913765","display_name":"Paule Castan","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Paule Castan","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110099661","display_name":"Franz L. Wimmer","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Franz L. Wimmer","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5109890556","display_name":"Neil P. Johnson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Neil P. Johnson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.7673,"has_fulltext":false,"cited_by_count":115,"citation_normalized_percentile":{"value":0.87841659,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":null,"issue":"3","first_page":"403","last_page":"412"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.7153000235557556,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.7153000235557556,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.09040000289678574,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.0778999999165535,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/platinum-ii-complexes","display_name":"platinum(II) complexes","score":0.9660000205039978},{"id":"https://openalex.org/keywords/palladium-ii-complexes","display_name":"palladium(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/hydroxo-bridged-dimers","display_name":"hydroxo-bridged dimers","score":0.8399999737739563},{"id":"https://openalex.org/keywords/2-2-bipyridine","display_name":"2,2'-bipyridine","score":0.9190000295639038},{"id":"https://openalex.org/keywords/1-10-phenanthroline","display_name":"1,10-phenanthroline","score":1.0},{"id":"https://openalex.org/keywords/nitrate-complexes","display_name":"nitrate complexes","score":0.5699999928474426},{"id":"https://openalex.org/keywords/silver-nitrate","display_name":"silver nitrate","score":0.4740000069141388},{"id":"https://openalex.org/keywords/nitric-acid-hydrolysis","display_name":"nitric acid hydrolysis","score":0.7739999890327454},{"id":"https://openalex.org/keywords/five-coordinate-metal-complexes","display_name":"five-coordinate metal complexes","score":0.5849999785423279},{"id":"https://openalex.org/keywords/dinuclear-complexes","display_name":"dinuclear complexes","score":0.4189999997615814},{"id":"https://openalex.org/keywords/coordination-chemistry","display_name":"coordination chemistry","score":0.33000001311302185}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9115244150161743},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.7548138499259949},{"id":"https://openalex.org/C518104683","wikidata":"https://www.wikidata.org/wiki/Q880","display_name":"Platinum","level":3,"score":0.6719222664833069},{"id":"https://openalex.org/C2778504605","wikidata":"https://www.wikidata.org/wiki/Q83320","display_name":"Nitric acid","level":2,"score":0.657223105430603},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6119346618652344},{"id":"https://openalex.org/C2775896084","wikidata":"https://www.wikidata.org/wiki/Q425597","display_name":"Hydroxide","level":2,"score":0.5558150410652161},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.5495478510856628},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.5286004543304443},{"id":"https://openalex.org/C2777660389","wikidata":"https://www.wikidata.org/wiki/Q416005","display_name":"Phenanthroline","level":2,"score":0.4896688759326935},{"id":"https://openalex.org/C88380143","wikidata":"https://www.wikidata.org/wiki/Q416674","display_name":"Dissolution","level":2,"score":0.4391971528530121},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.40826594829559326},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.33977991342544556},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3016665577888489},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.21831291913986206},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17315545678138733}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/dt9890000403","doi":"https://doi.org/10.1039/dt9890000403","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9890000403","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Dalton Trans.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2952036531","https://openalex.org/W1999322773","https://openalex.org/W3007241671","https://openalex.org/W2081547510","https://openalex.org/W358210967","https://openalex.org/W2063021675","https://openalex.org/W2016202831","https://openalex.org/W2025454576","https://openalex.org/W2039618529","https://openalex.org/W1993474633"],"abstract_inverted_index":{"Treatment":[0],"of":[1,30,42,51,84,129,134],"[Pt(L)I2][L":[2],"=":[3,32,94,99,137],"2,2\u2032-bipyridine":[4],"(bipy)":[5],"or":[6,34,126,139,146],"1,10-phenanthroline":[7],"(phen)]":[8],"with":[9,53,131],"AgNO3":[10,54],"in":[11,25,36,39,55,73],"acetone":[12],"gives":[13,57],"the":[14,40,43,61,88],"nitrato":[15],"complexes":[16,109,156],"[PtL(ONO2)2].":[17],"The":[18,64,79,155],"palladium":[19],"analogues":[20],"were":[21],"prepared":[22,121],"from":[23],"[Pd(L)Cl2]":[24],"dilute":[26],"nitric":[27,48,75],"acid.":[28,49],"Dissolution":[29],"[ML(ONO2)2](M":[31],"Pd":[33],"Pt)":[35],"water":[37,56],"results":[38],"formation":[41],"hydroxo-bridged":[44],"dimers":[45,65,80],"[LM(\u00b5-OH)2ML][NO3]2":[46,58],"plus":[47],"Reaction":[50],"[M(L)Cl2]":[52,130],"directly":[59],"as":[60],"sole":[62],"product.":[63],"are":[66,110],"resistant":[67],"to":[68,86,115,141],"substitution,":[69],"although":[70],"prolonged":[71],"heating":[72],"aqueous":[74],"acid":[76],"reforms":[77],"[ML(ONO2)2].":[78],"add":[81],"1":[82,153],"mol":[83],"OH\u2013":[85],"form":[87],"very":[89],"stable":[90],"trihydroxo-bridged":[91],"compounds":[92],"[LM(\u00b5-OH)3ML]+(M":[93],"Pt,":[95],"deep":[96,101],"red;":[97],"M":[98],"Pd,":[100],"yellow)":[102],"where":[103],"each":[104],"metal":[105],"is":[106],"five-co-ordinate.":[107],"These":[108],"slowly":[111],"cleaved":[112],"by":[113,123,127,160],"hydroxide":[114],"give":[116],"[ML(OH)2],":[117],"which":[118],"was":[119],"also":[120],"either":[122],"base":[124],"hydrolysis":[125],"reaction":[128],"Ag2O.":[132],"Addition":[133],"HX":[135],"(X":[136],"NO3,":[138],"ClO4)":[140],"[PtL(OH)2]":[142],"affords":[143],"[LPt(\u00b5-OH)3PtL]+,":[144],"[LPt(\u00b5-OH)2PtL]2+":[145],"[PtL(ONO2)2]":[147],"at":[148],"pH":[149],"8,":[150],"4,":[151],"and":[152,163,167],"respectively.":[154],"have":[157],"been":[158],"characterised":[159],"i.r.,":[161],"u.v.,":[162],"n.m.r.":[164],"(195Pt,":[165],"13C,":[166],"1H)":[168],"spectroscopy.":[169]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
