{"id":"https://openalex.org/W2152391111","doi":"https://doi.org/10.1039/p29920000829","title":"Functionalised 1,10-phenanthroline metallocatalysts as models for hydrolytic metalloenzymes","display_name":"Functionalised 1,10-phenanthroline metallocatalysts as models for hydrolytic metalloenzymes","publication_year":1992,"publication_date":"1992-01-01","ids":{"openalex":"https://openalex.org/W2152391111","doi":"https://doi.org/10.1039/p29920000829","mag":"2152391111"},"language":"en","primary_location":{"id":"doi:10.1039/p29920000829","doi":"https://doi.org/10.1039/p29920000829","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29920000829","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://research.wur.nl/en/publications/functionalised-110-phenanthroline-metallocatalysts-as-models-for-","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5044887833","display_name":"John G. J. Weijnen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John G. J. Weijnen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036749739","display_name":"Arie Koudijs","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Arie Koudijs","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022899666","display_name":"Gerard A. Schellekens","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gerard A. Schellekens","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5109150890","display_name":"Johan F. J. Engbersen","orcid":"https://orcid.org/0000-0001-8197-2028","observed_orcids":["https://orcid.org/0000-0001-8197-2028"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Johan F. J. Engbersen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.2773,"has_fulltext":false,"cited_by_count":40,"citation_normalized_percentile":{"value":0.77437864,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":null,"issue":"5","first_page":"829","last_page":"829"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.4771000146865845,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.4771000146865845,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.25609999895095825,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.07699999958276749,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/1-10-phenanthroline-derivatives","display_name":"1,10-phenanthroline derivatives","score":0.9350000023841858},{"id":"https://openalex.org/keywords/metalloenzyme-models","display_name":"metalloenzyme models","score":0.5899999737739563},{"id":"https://openalex.org/keywords/ester-hydrolysis","display_name":"ester hydrolysis","score":0.8560000061988831},{"id":"https://openalex.org/keywords/zinc-complexes","display_name":"zinc complexes","score":0.6039999723434448},{"id":"https://openalex.org/keywords/mixed-micelles","display_name":"mixed micelles","score":0.7020000219345093},{"id":"https://openalex.org/keywords/metallosurfactants","display_name":"metallosurfactants","score":0.7020000219345093},{"id":"https://openalex.org/keywords/ligand-activation","display_name":"ligand activation","score":0.753000020980835},{"id":"https://openalex.org/keywords/p-nitrophenyl-esters","display_name":"p-nitrophenyl esters","score":0.8759999871253967},{"id":"https://openalex.org/keywords/p-nitrophenyl-picolinate","display_name":"p-nitrophenyl picolinate","score":0.8999999761581421},{"id":"https://openalex.org/keywords/hydrolysis-kinetics","display_name":"hydrolysis kinetics","score":0.7940000295639038}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8786574602127075},{"id":"https://openalex.org/C2777660389","wikidata":"https://www.wikidata.org/wiki/Q416005","display_name":"Phenanthroline","level":2,"score":0.8326957821846008},{"id":"https://openalex.org/C2780591741","wikidata":"https://www.wikidata.org/wiki/Q899405","display_name":"Hydroxymethyl","level":2,"score":0.731277346611023},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6571341753005981},{"id":"https://openalex.org/C11268172","wikidata":"https://www.wikidata.org/wiki/Q421110","display_name":"Micelle","level":3,"score":0.576569676399231},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.5681537389755249},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.560297966003418},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.558626115322113},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5573103427886963},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.44041872024536133},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1919848620891571},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.13815364241600037},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11525806784629822},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.06993067264556885},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.06226125359535217},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.04465445876121521}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1039/p29920000829","doi":"https://doi.org/10.1039/p29920000829","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29920000829","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"},{"id":"pmh:oai:ris.utwente.nl:openaire_cris_publications/c5d6812b-d646-4aa3-b9ef-e3367260299c","doi":null,"is_oa":false,"landing_page_url":"https://research.utwente.nl/en/publications/c5d6812b-d646-4aa3-b9ef-e3367260299c","pdf_url":null,"source":{"id":"https://openalex.org/S4406922991","display_name":"University of Twente Research Information","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Weijnen, J G J, Koudijs, A, Schellekens, G A & Engbersen, J F J 1992, '1,10-Phenanthroline functionalised metallocatalysts as models for hydrolytic metalloenzymes', Journal of the Chemical Society. Perkin transactions II, vol. 0, no. 2, pp. 829-834.","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:library.wur.nl:wurpubs/17215","doi":null,"is_oa":true,"landing_page_url":"https://research.wur.nl/en/publications/functionalised-110-phenanthroline-metallocatalysts-as-models-for-","pdf_url":null,"source":{"id":"https://openalex.org/S4210201231","display_name":"Socio-Environmental Systems Modeling","issn_l":"2663-3027","issn":["2663-3027"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"ISSN: 0300-9580","raw_type":"Article/Letter to editor"},{"id":"pmh:ut:oai:ris.utwente.nl:publications/c5d6812b-d646-4aa3-b9ef-e3367260299c","doi":null,"is_oa":false,"landing_page_url":"https://research.utwente.nl/en/publications/110phenanthroline-functionalised-metallocatalysts-as-models-for-hydrolytic-metalloenzymes(c5d6812b-d646-4aa3-b9ef-e3367260299c).html","pdf_url":null,"source":{"id":"https://openalex.org/S4406922991","display_name":"University of Twente Research Information","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the Chemical Society. Perkin transactions II, 0(2), 829 - 834. Chemical Society","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:wur:oai:library.wur.nl:wurpubs/17215","doi":null,"is_oa":false,"landing_page_url":"https://research.wur.nl/en/publications/functionalised-110-phenanthroline-metallocatalysts-as-models-for-","pdf_url":null,"source":{"id":"https://openalex.org/S4306401843","display_name":"Data Archiving and Networked Services (DANS)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1322597698","host_organization_name":"Royal Netherlands Academy of Arts and Sciences","host_organization_lineage":["https://openalex.org/I1322597698"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of Chemical Society, Perkin Transactions, 2, 829 - 834","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:library.wur.nl:wurpubs/17215","doi":null,"is_oa":true,"landing_page_url":"https://research.wur.nl/en/publications/functionalised-110-phenanthroline-metallocatalysts-as-models-for-","pdf_url":null,"source":{"id":"https://openalex.org/S4210201231","display_name":"Socio-Environmental Systems Modeling","issn_l":"2663-3027","issn":["2663-3027"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"ISSN: 0300-9580","raw_type":"Article/Letter to editor"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W1727936282","https://openalex.org/W1919168459","https://openalex.org/W1967681298","https://openalex.org/W1974650261","https://openalex.org/W1979379774","https://openalex.org/W1994015745","https://openalex.org/W1995423512","https://openalex.org/W1997413810","https://openalex.org/W1997985416","https://openalex.org/W1999772235","https://openalex.org/W2003278944","https://openalex.org/W2008773963","https://openalex.org/W2017710579","https://openalex.org/W2022930735","https://openalex.org/W2030323006","https://openalex.org/W2033864205","https://openalex.org/W2051146307","https://openalex.org/W2053144855","https://openalex.org/W2058933888","https://openalex.org/W2062068259","https://openalex.org/W2076351609","https://openalex.org/W2078453695","https://openalex.org/W2083819391","https://openalex.org/W2089459862","https://openalex.org/W2090738641","https://openalex.org/W2133457438","https://openalex.org/W2316083874","https://openalex.org/W2951260078","https://openalex.org/W2952055935","https://openalex.org/W2952876512","https://openalex.org/W3004458782","https://openalex.org/W3004731295","https://openalex.org/W3004877019","https://openalex.org/W3005271270"],"related_works":["https://openalex.org/W18499246","https://openalex.org/W2113424796","https://openalex.org/W2112106607","https://openalex.org/W2089167050","https://openalex.org/W2089603514","https://openalex.org/W2043397057","https://openalex.org/W1997273731","https://openalex.org/W2027375895","https://openalex.org/W2953301399","https://openalex.org/W2383297903"],"abstract_inverted_index":{"The":[0,16,53,101,117],"synthesis":[1],"of":[2,19,28,32,73,103,135],"three":[3],"new":[4],"1,10-phenanthroline":[5],"derivatives":[6],"is":[7,76,108,125,144],"reported:":[8],"2-(N-methyldodecylamino)methyl-9-(hydroxymethyl)-1,10-phenanthroline":[9],"(1),":[10],"2-(N,N-dimethylamino)methyl-9-(hydroxymethyl)-1,10-phenanthroline":[11],"(2),":[12],"and":[13,23,31,46,70,96],"2-(N-methyldodecylamino)methyl-1,10-phenanthroline":[14],"(3).":[15],"esterolytic":[17],"activities":[18],"the":[20,26,38,71,121,133],"complexes":[21,65,95],"1\u2013MII":[22],"3\u2013MII":[24],"in":[25,34,57],"presence":[27],"cationogenic":[29],"micelles":[30,59],"2\u2013MII":[33],"pure":[35],"buffer":[36],"toward":[37],"substrates":[39],"p-nitrophenyl":[40,43,47],"picolinate":[41],"(PNPP),":[42],"octanoate":[44],"(PNPO),":[45],"dodecanoate":[48],"(PNPD)":[49],"have":[50],"been":[51],"investigated.":[52],"lipophilic":[54],"ligand":[55,74,104],"1":[56,62,64,92,94,99],"mixed":[58],"forms":[60,90],"only":[61],":":[63,93,98],"with":[66],"bivalent":[67],"metal":[68],"ions":[69],"order":[72,102],"activation":[75,105],"ZnII":[77,114],">":[78,80,82,112,115],"CoII":[79,111],"CdII":[81],"NiII,":[83],"while":[84],"its":[85],"water":[86],"soluble":[87],"analogue":[88],"2":[89,97,107],"both":[91],"complexes.":[100],"for":[106],"also":[109],"different:":[110],"NiII\u2248":[113],"CdII.":[116],"metallosurfactant":[118],"3,":[119],"lacking":[120],"nucleophilic":[122],"hydroxy":[123],"group,":[124],"25":[126],"times":[127],"less":[128],"active":[129],"than":[130],"1\u2013ZnII.":[131],"For":[132],"hydrolysis":[134],"PNPP":[136],"catalysed":[137],"by":[138],"1\u2013ZnII,":[139],"a":[140],"detailed":[141],"kinetic":[142],"analysis":[143],"given.":[145]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}