{"id":"https://openalex.org/W2144674326","doi":"https://doi.org/10.1002/adfm.201300401","title":"Three\u2010Dimensionally Ordered Macroporous Polymeric Materials by Colloidal Crystal Templating for Reversible CO 2 Capture","display_name":"Three\u2010Dimensionally Ordered Macroporous Polymeric Materials by Colloidal Crystal Templating for Reversible CO 2 Capture","publication_year":2013,"publication_date":"2013-04-19","ids":{"openalex":"https://openalex.org/W2144674326","doi":"https://doi.org/10.1002/adfm.201300401","mag":"2144674326"},"language":"en","primary_location":{"id":"doi:10.1002/adfm.201300401","doi":"https://doi.org/10.1002/adfm.201300401","is_oa":false,"landing_page_url":"https://doi.org/10.1002/adfm.201300401","pdf_url":null,"source":{"id":"https://openalex.org/S135204980","display_name":"Advanced Functional Materials","issn_l":"1616-301X","issn":["1616-301X","1616-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-3","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Advanced Functional Materials","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5112331132","display_name":"Hongkun He","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hongkun He","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009175477","display_name":"Mingjiang Zhong","orcid":"https://orcid.org/0000-0001-7533-4708","observed_orcids":["https://orcid.org/0000-0001-7533-4708","https://orcid.org/0000-0002-3927-8101"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mingjiang Zhong","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074585419","display_name":"Dominik Konkolewicz","orcid":"https://orcid.org/0000-0002-3828-5481","observed_orcids":["https://orcid.org/0000-0002-3828-5481"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Dominik Konkolewicz","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036214262","display_name":"Karin Yacatto","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Karin Yacatto","raw_affiliation_strings":["Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015467757","display_name":"Timothy Rappold","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Timothy Rappold","raw_affiliation_strings":["Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":null,"display_name":"Glenn Sugar","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Glenn Sugar","raw_affiliation_strings":["Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108213197","display_name":"Nathaniel E. David","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Nathaniel E. David","raw_affiliation_strings":["Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kilimanjaro Energy, Inc., San Francisco, CA 94107, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007091603","display_name":"Jeff Gelb","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jeff Gelb","raw_affiliation_strings":["Xradia, Inc., Pleasanton, CA 94588, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xradia, Inc., Pleasanton, CA 94588, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051662103","display_name":"Naomi Kotwal","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Naomi Kotwal","raw_affiliation_strings":["Xradia, Inc., Pleasanton, CA 94588, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xradia, Inc., Pleasanton, CA 94588, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111710086","display_name":"Arno Merkle","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Arno Merkle","raw_affiliation_strings":["Xradia, Inc., Pleasanton, CA 94588, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xradia, Inc., Pleasanton, CA 94588, USA","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5056539244","display_name":"Krzysztof Aleksander Matyjaszewski","orcid":"https://orcid.org/0000-0003-1960-3402","observed_orcids":["https://orcid.org/0000-0003-1960-3402"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Krzysztof Matyjaszewski","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213. USA","institution_ids":["https://openalex.org/I74973139"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5056539244"],"corresponding_institution_ids":["https://openalex.org/I74973139"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":10.606,"has_fulltext":false,"cited_by_count":74,"citation_normalized_percentile":{"value":0.984026,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"23","issue":"37","first_page":"4720","last_page":"4728"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10967","display_name":"Carbon Dioxide Capture Technologies","score":0.9175000190734863,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10967","display_name":"Carbon Dioxide Capture Technologies","score":0.9175000190734863,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.06109999865293503,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.004699999932199717,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/colloidal-crystal-templating","display_name":"colloidal crystal templating","score":0.9950000047683716},{"id":"https://openalex.org/keywords/polystyrene-colloidal-crystals","display_name":"polystyrene colloidal crystals","score":0.9879999756813049},{"id":"https://openalex.org/keywords/porous-polymer-films","display_name":"porous polymer films","score":0.4869999885559082},{"id":"https://openalex.org/keywords/capillary-penetration","display_name":"capillary penetration","score":0.7850000262260437}],"concepts":[{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.8613466620445251},{"id":"https://openalex.org/C125574357","wikidata":"https://www.wikidata.org/wiki/Q1100469","display_name":"Colloidal crystal","level":3,"score":0.7996094226837158},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.6142509579658508},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.6077948212623596},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.6056808233261108},{"id":"https://openalex.org/C59789625","wikidata":"https://www.wikidata.org/wiki/Q181780","display_name":"Colloid","level":2,"score":0.5280847549438477},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.50132155418396},{"id":"https://openalex.org/C6648577","wikidata":"https://www.wikidata.org/wiki/Q622669","display_name":"Porosity","level":2,"score":0.42126792669296265},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.41584512591362},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.34177300333976746},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.1701027750968933},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/adfm.201300401","doi":"https://doi.org/10.1002/adfm.201300401","is_oa":false,"landing_page_url":"https://doi.org/10.1002/adfm.201300401","pdf_url":null,"source":{"id":"https://openalex.org/S135204980","display_name":"Advanced Functional Materials","issn_l":"1616-301X","issn":["1616-301X","1616-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-3","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Advanced Functional Materials","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":74,"referenced_works":["https://openalex.org/W1486598704","https://openalex.org/W1579170559","https://openalex.org/W1649401714","https://openalex.org/W1940823002","https://openalex.org/W1967743582","https://openalex.org/W1968746837","https://openalex.org/W1968914064","https://openalex.org/W1971632124","https://openalex.org/W1973088909","https://openalex.org/W1974348238","https://openalex.org/W1974665855","https://openalex.org/W1975936117","https://openalex.org/W1980074085","https://openalex.org/W1980755128","https://openalex.org/W1981164146","https://openalex.org/W1982236815","https://openalex.org/W1985148570","https://openalex.org/W1990906290","https://openalex.org/W1992257934","https://openalex.org/W1993993221","https://openalex.org/W1996944876","https://openalex.org/W2001280311","https://openalex.org/W2001895292","https://openalex.org/W2002074284","https://openalex.org/W2002151021","https://openalex.org/W2002655208","https://openalex.org/W2005020039","https://openalex.org/W2005852883","https://openalex.org/W2013541735","https://openalex.org/W2014021003","https://openalex.org/W2016814255","https://openalex.org/W2017445739","https://openalex.org/W2020812793","https://openalex.org/W2021753512","https://openalex.org/W2031649698","https://openalex.org/W2032556527","https://openalex.org/W2035231511","https://openalex.org/W2041735485","https://openalex.org/W2041983638","https://openalex.org/W2042973006","https://openalex.org/W2043068792","https://openalex.org/W2043720689","https://openalex.org/W2046873382","https://openalex.org/W2049541689","https://openalex.org/W2054126210","https://openalex.org/W2068074443","https://openalex.org/W2071363352","https://openalex.org/W2072755723","https://openalex.org/W2082336921","https://openalex.org/W2084346461","https://openalex.org/W2088954567","https://openalex.org/W2093705018","https://openalex.org/W2094965297","https://openalex.org/W2096754272","https://openalex.org/W2104943417","https://openalex.org/W2107125662","https://openalex.org/W2116581764","https://openalex.org/W2125053394","https://openalex.org/W2125808109","https://openalex.org/W2125869069","https://openalex.org/W2128705258","https://openalex.org/W2131741145","https://openalex.org/W2148442815","https://openalex.org/W2149507322","https://openalex.org/W2149865841","https://openalex.org/W2151125551","https://openalex.org/W2158190465","https://openalex.org/W2159639771","https://openalex.org/W2167403064","https://openalex.org/W2317747468","https://openalex.org/W2327021338","https://openalex.org/W2328381716","https://openalex.org/W2333033211","https://openalex.org/W2952263674"],"related_works":["https://openalex.org/W1983081274","https://openalex.org/W2148442815","https://openalex.org/W2367999720","https://openalex.org/W2386951365","https://openalex.org/W2392442563","https://openalex.org/W2356573880","https://openalex.org/W2352993274","https://openalex.org/W4254394551","https://openalex.org/W2804153728","https://openalex.org/W2889820616"],"abstract_inverted_index":{"Abstract":[0],"The":[1,158],"design":[2],"and":[3,11,50,151,161,245],"preparation":[4],"of":[5,18,81,92,110,177,182,224,269],"porous":[6,101,142],"materials":[7,31,238,273],"with":[8,32,145,216,254,274],"controlled":[9],"structures":[10,37,55],"functionalities":[12,276],"is":[13,75,96],"crucial":[14],"to":[15,98,139,202,249,264],"a":[16,127,153,208,222,229,250,266],"variety":[17],"absorption\u2010":[19],"or":[20,85],"separation\u2010relevant":[21],"applications,":[22],"including":[23],"CO":[24,61,241],"2":[25,62,242],"capture.":[26],"Here,":[27],"novel":[28],"functional":[29,213,256],"polymeric":[30,272],"three\u2010dimensionally":[33],"ordered":[34,54,270],"macroporous":[35,214,271],"(3DOM)":[36],"are":[38,56,164,219],"prepared":[39,220],"by":[40,67,107,125],"using":[41,46,126,152,198],"colloidal":[42,72,155,192,226,235],"crystals":[43,227],"as":[44],"templates":[45],"relatively":[47],"simple,":[48],"rapid,":[49],"inexpensive":[51],"approaches.":[52],"These":[53],"used":[57,138],"for":[58,185,277],"the":[59,71,90,93,100,108,111,146,171,178,187,191,234],"reversible":[60],"capture":[63],"from":[64,77,166,221],"ambient":[65],"air":[66],"humidity":[68],"swing.":[69],"Typically,":[70],"crystal":[73,156,193,236],"template":[74,194,223],"synthesized":[76,165],"polymer":[78],"latex":[79],"particles":[80],"poly(methyl":[82],"methacrylate)":[83],"(PMMA)":[84],"polystyrene":[86],"(PS).":[87],"To":[88],"maintain":[89],"functionality":[91],"material,":[94],"it":[95],"important":[97],"prevent":[99],"structure":[102],"collapsing,":[103],"which":[104,135,174],"can":[105,122,136],"occur":[106],"hydrolysis":[109,121],"ester":[112],"bonds":[113],"in":[114,228],"conventional":[115],"crosslinkers":[116],"under":[117,207],"basic":[118],"conditions.":[119],"This":[120,258],"be":[123,137,262],"prevented":[124],"water\u2010soluble":[128],"crosslinker":[129,163],"containing":[130],"two":[131],"quaternary":[132],"ammonium":[133],"moieties,":[134],"prepare":[140],"stable":[141],"crosslinked":[143],"polymers":[144],"monomer":[147,160,188],"(vinylbenzyl)trimethylammonium":[148],"chloride":[149,168],"(VBTMACl)":[150],"PMMA\u2010based":[154],"template.":[157],"hydroxide\u2010containing":[159],"dicationic":[162],"their":[167],"precursors,":[169],"avoiding":[170],"ion\u2010exchange":[172],"step":[173],"causes":[175],"shrinkage":[176],"pores.":[179],"An":[180],"analysis":[181],"different":[183],"methods":[184],"infiltrating":[186],"solution":[189],"into":[190],"shows":[195],"that":[196],"infiltration":[197,206],"capillary":[199],"forces":[200],"leads":[201],"fewer":[203],"defects":[204],"than":[205],"partial":[209],"vacuum.":[210],"In":[211,232],"addition,":[212],"films":[215],"micrometer":[217],"thickness":[218],"PS\u2010based":[225],"thin":[230],"film.":[231],"general,":[233],"templated":[237],"showed":[239],"improved":[240],"absorption/desorption":[243],"rates":[244],"swing":[246],"sizes":[247],"compared":[248],"commercially":[251],"available":[252],"material":[253],"similar":[255],"groups.":[257],"work":[259],"could":[260],"easily":[261],"extended":[263],"create":[265],"new":[267],"generation":[268],"tunable":[275],"other":[278],"applications.":[279]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":10},{"year":2024,"cited_by_count":12},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":4},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":6},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":6},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":2}],"updated_date":"2026-10-18T09:31:52.927876","created_date":"2016-06-24T00:00:00"}