{"id":"https://openalex.org/W2142053548","doi":"https://doi.org/10.1002/047084289x.ri063","title":"Iron(III) Nitrate-K10 Montmorillonite Clay","display_name":"Iron(III) Nitrate-K10 Montmorillonite Clay","publication_year":2001,"publication_date":"2001-04-15","ids":{"openalex":"https://openalex.org/W2142053548","doi":"https://doi.org/10.1002/047084289x.ri063","mag":"2142053548"},"language":"en","primary_location":{"id":"doi:10.1002/047084289x.ri063","doi":"https://doi.org/10.1002/047084289x.ri063","is_oa":false,"landing_page_url":"https://doi.org/10.1002/047084289x.ri063","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Encyclopedia of Reagents for Organic Synthesis","raw_type":"reference-entry"},"volume":{"id":"https://openalex.org/W4212905075","display_name":"Encyclopedia of Reagents for Organic Synthesis"},"type":"reference-entry","is_traditional":false,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110070486","display_name":"Andr\u00e9 Corn\u00e9lis","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Andr\u00e9 Corn\u00e9lis","raw_affiliation_strings":["Universite\u0301 de Lie\u0300ge, Belgium","Universit\u00e9 de Li\u00e8ge, Belgium#TAB#"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universite\u0301 de Lie\u0300ge, Belgium","institution_ids":["https://openalex.org/I157674565"]},{"raw_affiliation_string":"Universit\u00e9 de Li\u00e8ge, Belgium#TAB#","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062710106","display_name":"Pierre Laszlo","orcid":"https://orcid.org/0000-0003-4334-771X","observed_orcids":["https://orcid.org/0000-0003-4334-771X"]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Pierre Laszlo","raw_affiliation_strings":["Universite\u0301 de Lie\u0300ge, Belgium","Universit\u00e9 de Li\u00e8ge, Belgium#TAB#"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universite\u0301 de Lie\u0300ge, Belgium","institution_ids":["https://openalex.org/I157674565"]},{"raw_affiliation_string":"Universit\u00e9 de Li\u00e8ge, Belgium#TAB#","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5090157553","display_name":"Mark W. Zettler","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210133143","display_name":"Dow Chemical (United States)","ror":"https://ror.org/032hx4q18","country_code":"US","type":"company","lineage":["https://openalex.org/I4210133143"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark W. Zettler","raw_affiliation_strings":["Dow Chemical Company, Midland, MI, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dow Chemical Company, Midland, MI, USA","institution_ids":["https://openalex.org/I4210133143"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.40380001068115234,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.40380001068115234,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.3411000072956085,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11852","display_name":"Clay minerals and soil interactions","score":0.09189999848604202,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iron-iii-nitrate","display_name":"iron(III) nitrate","score":0.8970000147819519},{"id":"https://openalex.org/keywords/aromatic-ring-oxidation","display_name":"aromatic ring oxidation","score":0.7889999747276306},{"id":"https://openalex.org/keywords/exothermic-decomposition","display_name":"exothermic decomposition","score":0.6899999976158142},{"id":"https://openalex.org/keywords/reagent-preparation","display_name":"reagent preparation","score":0.6029999852180481},{"id":"https://openalex.org/keywords/reagent-storage-and-handling","display_name":"reagent handling and storage","score":0.6110000014305115}],"concepts":[{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.7387938499450684},{"id":"https://openalex.org/C2781213060","wikidata":"https://www.wikidata.org/wiki/Q49546","display_name":"Acetone","level":2,"score":0.6337536573410034},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5457011461257935},{"id":"https://openalex.org/C2777515222","wikidata":"https://www.wikidata.org/wiki/Q422131","display_name":"Montmorillonite","level":2,"score":0.5038947463035583},{"id":"https://openalex.org/C45119746","wikidata":"https://www.wikidata.org/wiki/Q205949","display_name":"Exothermic reaction","level":2,"score":0.4989125728607178},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4979884624481201},{"id":"https://openalex.org/C155574463","wikidata":"https://www.wikidata.org/wiki/Q170731","display_name":"Solubility","level":2,"score":0.4714473485946655},{"id":"https://openalex.org/C548081761","wikidata":"https://www.wikidata.org/wiki/Q180388","display_name":"Waste management","level":1,"score":0.3839952051639557},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.332222580909729},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3308420777320862},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.25561797618865967},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.08653181791305542}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/047084289x.ri063","doi":"https://doi.org/10.1002/047084289x.ri063","is_oa":false,"landing_page_url":"https://doi.org/10.1002/047084289x.ri063","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Encyclopedia of Reagents for Organic Synthesis","raw_type":"reference-entry"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W1963833693","https://openalex.org/W1975035721","https://openalex.org/W1975480409","https://openalex.org/W1976857220","https://openalex.org/W1994923758","https://openalex.org/W2005808986","https://openalex.org/W2026999078","https://openalex.org/W2043157582","https://openalex.org/W2046829868","https://openalex.org/W2047477180","https://openalex.org/W2059891488","https://openalex.org/W2062104924","https://openalex.org/W2063000462","https://openalex.org/W2080847581","https://openalex.org/W2084100603","https://openalex.org/W2949485064","https://openalex.org/W2950543010","https://openalex.org/W4248943363","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W2084100603","https://openalex.org/W2952136530","https://openalex.org/W2047477180","https://openalex.org/W2949706552","https://openalex.org/W2045710171","https://openalex.org/W2949485064","https://openalex.org/W2019614491","https://openalex.org/W2018643916","https://openalex.org/W2952964282","https://openalex.org/W2073641906"],"abstract_inverted_index":{"(mild,":[0],"inexpensive":[1],"NO+":[2],"source;2":[3],"oxidizes":[4],"aromatic":[5],"rings":[6],"to":[7,71,126],"radical":[8],"cations3)":[9],"Alternate":[10],"Name:":[11],"clayfen.":[12],"Solubility:":[13],"clay":[14,40],"support:":[15],"insol":[16],"water,":[17,22],"organic":[18],"solvents.":[19],"Fe(NO3)3:":[20],"sol":[21],"acetone,":[23],"ethanol.":[24],"Form":[25],"Supplied":[26],"in:":[27],"rusty":[28],"yellow,":[29],"free-flowing":[30],"floury":[31],"powder.":[32],"Preparative":[33],"Method:":[34],"controlled":[35],"solvent":[36],"elimination":[37],"from":[38],"K10":[39],"(30":[41],"g)":[42,50],"suspended":[43],"in":[44,51,108,112,152],"a":[45,97,153],"solution":[46],"of":[47,80,85],"Fe(NO3)3\u00b79H2O":[48],"(22.5":[49],"acetone":[52],"(375":[53],"mL).1":[54],"Handling,":[55],"Storage,":[56],"and":[57,96,124,134],"Precautions:":[58],"most":[59],"applications":[60],"require":[61],"freshly":[62],"prepared":[63],"(1\u20132":[64],"h)":[65],"reagent.":[66],"Clayfen":[67],"is":[68,89],"unstable,":[69],"prone":[70],"vigorous":[72],"or":[73],"slow":[74],"exothermic":[75],"decomposition,":[76],"together":[77],"with":[78,114,130],"evolution":[79],"NO2":[81],"gas.":[82],"Careful":[83],"observance":[84],"the":[86,100,103,131],"preparation":[87],"procedure1":[88],"critical":[90],"(in":[91],"particular,":[92,137],"T":[93],"<50":[94],"\u00b0C":[95],"crust":[98],"on":[99],"glassware":[101],"at":[102],"flaking-off":[104],"stage).":[105],"Never":[106],"store":[107],"gas-tight":[109],"containers,":[110],"nor":[111],"contact":[113],"strongly":[115],"reducing":[116],"material":[117],"such":[118],"as":[119],"aluminum.":[120],"Nitrates":[121],"are":[122,125],"dangerous,":[123],"be":[127,140,150],"used":[128],"only":[129,142],"appropriate":[132,144],"precautions":[133],"protections.":[135],"In":[136],"scaling-up":[138],"should":[139,149],"attempted":[141],"after":[143],"safety":[145],"tests.":[146],"This":[147],"reagent":[148],"handled":[151],"fume":[154],"hood.":[155]},"counts_by_year":[{"year":2025,"cited_by_count":1}],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2016-06-24T00:00:00"}