{"id":"https://openalex.org/W2140764005","doi":"https://doi.org/10.1039/ft9908602757","title":"Infrared spectroscopic comparison of the chemisorbed species from ethene, propene, but-1-ene and cis- and trans-but-2-ene on Pt(111) and on a platinum/silica catalyst","display_name":"Infrared spectroscopic comparison of the chemisorbed species from ethene, propene, but-1-ene and cis- and trans-but-2-ene on Pt(111) and on a platinum/silica catalyst","publication_year":1990,"publication_date":"1990-01-01","ids":{"openalex":"https://openalex.org/W2140764005","doi":"https://doi.org/10.1039/ft9908602757","mag":"2140764005"},"language":"en","primary_location":{"id":"doi:10.1039/ft9908602757","doi":"https://doi.org/10.1039/ft9908602757","is_oa":false,"landing_page_url":"https://doi.org/10.1039/ft9908602757","pdf_url":null,"source":{"id":"https://openalex.org/S10145039","display_name":"Journal of the Chemical Society Faraday Transactions","issn_l":"0956-5000","issn":["0956-5000","1364-5455"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Faraday Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109196323","display_name":"Michael A. Chesters","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Michael A. Chesters","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":null,"display_name":"Carlos De La Cruz","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Carlos De La Cruz","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021098743","display_name":"Peter Gardner","orcid":"https://orcid.org/0000-0003-4034-3764","observed_orcids":["https://orcid.org/0000-0003-4034-3764"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Peter Gardner","raw_affiliation_strings":["Chemical Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110711417","display_name":"E\u013aaine M. McCash","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Elaine M. McCash","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033628686","display_name":"Paul D. A. Pudney","orcid":"https://orcid.org/0000-0002-9708-6968","observed_orcids":["https://orcid.org/0000-0002-9708-6968"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Paul Pudney","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061961596","display_name":"Gulerana Shahid","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"G. Shahid","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5111832274","display_name":"N. Sheppard","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Norman Sheppard","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":3.5846,"has_fulltext":false,"cited_by_count":107,"citation_normalized_percentile":{"value":0.93517943,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"86","issue":"15","first_page":"2757","last_page":"2757"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.7163000106811523,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.7163000106811523,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.13729999959468842,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.09260000288486481,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chemisorption","display_name":"chemisorption","score":0.722000002861023},{"id":"https://openalex.org/keywords/alkenes","display_name":"alkenes","score":0.8370000123977661},{"id":"https://openalex.org/keywords/ethylene","display_name":"ethylene","score":0.7950000166893005},{"id":"https://openalex.org/keywords/propylene","display_name":"propylene","score":1.0},{"id":"https://openalex.org/keywords/1-butene","display_name":"1-butene","score":0.996999979019165},{"id":"https://openalex.org/keywords/but-2-yne","display_name":"but-2-yne","score":0.9900000095367432},{"id":"https://openalex.org/keywords/pt-111","display_name":"Pt(111)","score":0.8799999952316284},{"id":"https://openalex.org/keywords/pt-sio2-catalyst","display_name":"Pt/SiO2 catalyst","score":0.9610000252723694},{"id":"https://openalex.org/keywords/double-bond-isomerization","display_name":"double bond isomerization","score":0.8859999775886536}],"concepts":[{"id":"https://openalex.org/C2777954637","wikidata":"https://www.wikidata.org/wiki/Q151324","display_name":"Propene","level":3,"score":0.9283501505851746},{"id":"https://openalex.org/C27777614","wikidata":"https://www.wikidata.org/wiki/Q26469","display_name":"Ene reaction","level":2,"score":0.909293532371521},{"id":"https://openalex.org/C33790079","wikidata":"https://www.wikidata.org/wiki/Q899417","display_name":"Chemisorption","level":3,"score":0.7956643104553223},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7679606676101685},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.689662516117096},{"id":"https://openalex.org/C518104683","wikidata":"https://www.wikidata.org/wiki/Q880","display_name":"Platinum","level":3,"score":0.5927639603614807},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5904374718666077},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.5604509115219116},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.43404942750930786},{"id":"https://openalex.org/C2780422782","wikidata":"https://www.wikidata.org/wiki/Q342790","display_name":"Acrolein","level":3,"score":0.4210491478443146},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.23901769518852234},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1432492733001709},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.08328184485435486},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/ft9908602757","doi":"https://doi.org/10.1039/ft9908602757","is_oa":false,"landing_page_url":"https://doi.org/10.1039/ft9908602757","pdf_url":null,"source":{"id":"https://openalex.org/S10145039","display_name":"Journal of the Chemical Society Faraday Transactions","issn_l":"0956-5000","issn":["0956-5000","1364-5455"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Faraday Transactions","raw_type":"journal-article"},{"id":"pmh:oai:pure.atira.dk:openaire_cris_publications/1ec1ff8f-9727-4094-a405-0333d97e74c7","doi":null,"is_oa":false,"landing_page_url":"https://research.manchester.ac.uk/en/publications/1ec1ff8f-9727-4094-a405-0333d97e74c7","pdf_url":null,"source":{"id":"https://openalex.org/S4306400662","display_name":"Research Explorer (The University of Manchester)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I28407311","host_organization_name":"University of Manchester","host_organization_lineage":["https://openalex.org/I28407311"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chesters, M A, Delacruz, C, Gardner, P, McCash, E M, Pudney, P, Shahid, G & Sheppard, N 1990, 'Infrared Spectroscopic Comparison of the Chemisorbed Species from Ethene, Propene, but-1-Ene and Cis-but-2-Ene and Trans-but-2-Ene on Pt(111) and on a Platinum Silica Catalyst', Journal of the Chemical Society-Faraday Transactions, vol. 86, no. 15, pp. 2757-2763.","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W986163383","https://openalex.org/W1968015055","https://openalex.org/W1968845614","https://openalex.org/W1977360514","https://openalex.org/W1979152651","https://openalex.org/W1990330725","https://openalex.org/W1993069470","https://openalex.org/W1993119212","https://openalex.org/W1998584164","https://openalex.org/W2007640533","https://openalex.org/W2010551614","https://openalex.org/W2011764801","https://openalex.org/W2032110292","https://openalex.org/W2053161236","https://openalex.org/W2079448633","https://openalex.org/W2081573413","https://openalex.org/W2084431367","https://openalex.org/W2101136229","https://openalex.org/W2111201663","https://openalex.org/W4234701526"],"related_works":["https://openalex.org/W7010542964","https://openalex.org/W2070419330","https://openalex.org/W1978428918","https://openalex.org/W1985128834","https://openalex.org/W2078599253","https://openalex.org/W2135447518","https://openalex.org/W2062338601","https://openalex.org/W1970963914","https://openalex.org/W2047448550","https://openalex.org/W2048471725"],"abstract_inverted_index":{"The":[0,24,65],"chemisorption":[1],"of":[2,33,74,89,94,135,142,157,180],"ethene,":[3,47,95],"propene,":[4],"but-1-ene,":[5],"cis-":[6,66,144],"and":[7,9,49,67,97,145,198,206],"trans-but-2-ene":[8],"but-2-yne":[10,75,90,183],"has":[11],"been":[12,27],"studied":[13],"on":[14,37,99,152,204,207],"a":[15,38,81],"Pt(111)":[16,45,205],"surface":[17,46,79],"using":[18],"reflection":[19],"absorption":[20],"infrared":[21,31,187],"spectroscopy":[22],"(RAIRS).":[23],"results":[25],"have":[26],"compared":[28],"with":[29,132,155],"transmission":[30],"spectra":[32,93,149,188],"the":[34,44,54,72,78,106,115,121,136,140,143,158,166,196,201,208],"alkenes":[35],"adsorbed":[36,52,70,110],"finely":[39,167],"divided":[40,168],"impregnated":[41],"Pt/SiO2":[42,100,153,209],"catalyst.On":[43],"propene":[48,96],"but-1-ene":[50,98],"are":[51,69],"in":[53,71,80],"corresponding":[55],"n-alkylidyne":[56],"form":[57,73],"CH3(CH2)nCPt3(n=":[58],"0,":[59],"1,":[60],"2)":[61],"at":[62,194],"room":[63],"temperature.":[64],"trans-but-2-enes":[68],"bonded":[76,182],"to":[77,114,118,174,190],"di-\u03c3/\u03c0":[82,181],"fashion,":[83],"as":[84,162],"was":[85,184],"confirmed":[86],"by":[87],"adsorption":[88],"itself.The":[91],"room-temperature":[92],"all":[101],"exhibited":[102],"prominent":[103,160],"absorptions":[104],"from":[105,163],"n-alkylidyne,":[107],"but":[108,154],"other":[109],"species":[111,124,202],"also":[112,185],"contributed":[113],"spectra,":[116],"considered":[117],"be":[119,191],"predominantly":[120],"appropriate":[122],"di-\u03c3":[123],"PtCH2CH(R)Pt":[125],"(R":[126],"=":[127],"H,":[128],"CH3,":[129],"C2H5)":[130],"together":[131],"smaller":[133,178],"amounts":[134],"relevant":[137],"\u03c0-complexes.":[138],"In":[139],"case":[141],"trans-but-2-enes,":[146],"virtually":[147],"identical":[148],"were":[150],"obtained":[151],"many":[156],"same":[159],"features":[161],"but-1-ene.":[164],"Clearly":[165],"catalyst":[169],"had":[170],"sites":[171],"which":[172],"led":[173],"double-bond":[175],"isomerization.":[176],"A":[177],"proportion":[179],"present.The":[186],"proved":[189],"very":[192],"effective":[193],"delineating":[195],"similarities":[197],"differences":[199],"between":[200],"chemisorbed":[203],"catalyst.":[210]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}