{"id":"https://openalex.org/W2139888221","doi":"https://doi.org/10.1039/a800595h","title":"Bridgehead diphosphines in the bicyclo[3.3.3]undecane and bicyclo[4.4.4]tetradecane series: synthesis, structure and properties","display_name":"Bridgehead diphosphines in the bicyclo[3.3.3]undecane and bicyclo[4.4.4]tetradecane series: synthesis, structure and properties","publication_year":1998,"publication_date":"1998-01-01","ids":{"openalex":"https://openalex.org/W2139888221","doi":"https://doi.org/10.1039/a800595h","mag":"2139888221"},"language":"en","primary_location":{"id":"doi:10.1039/a800595h","doi":"https://doi.org/10.1039/a800595h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a800595h","pdf_url":null,"source":{"id":"https://openalex.org/S955628534","display_name":"Journal of the Chemical Society Perkin Transactions 1","issn_l":"1364-5463","issn":["1364-5463","1470-4358","1472-7781","2050-8263"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 1","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057875051","display_name":"Roger W. Alder","orcid":"https://orcid.org/0000-0002-3675-1186","observed_orcids":["https://orcid.org/0000-0002-3675-1186"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Roger W. Alder","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108434226","display_name":"Dianne\u00a0D. Ellis","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Dianne D. Ellis","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020894344","display_name":"Rolf Gleiter","orcid":"https://orcid.org/0000-0001-5853-381X","observed_orcids":["https://orcid.org/0000-0001-5853-381X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Rolf Gleiter","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5105412889","display_name":"Christopher Harris","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Christopher J. Harris","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":null,"display_name":"Holger Lange","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Holger Lange","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109974063","display_name":"A. Guy. Orpen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"A. Guy Orpen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089857232","display_name":"DAVID M. READ","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David Read","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":null,"display_name":"Peter N. Taylor","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Peter N. Taylor","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.0185,"has_fulltext":false,"cited_by_count":33,"citation_normalized_percentile":{"value":0.83066531,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":null,"issue":"10","first_page":"1657","last_page":"1668"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.4975999891757965,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.4975999891757965,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.4171999990940094,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.05920000001788139,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/propellanes","display_name":"propellanes","score":0.8069999814033508},{"id":"https://openalex.org/keywords/ring-size-effects","display_name":"ring size effects","score":0.7009999752044678},{"id":"https://openalex.org/keywords/hydrolysis","display_name":"hydrolysis","score":0.625},{"id":"https://openalex.org/keywords/nucleophilic-substitution","display_name":"nucleophilic substitution","score":0.7319999933242798},{"id":"https://openalex.org/keywords/rearrangement","display_name":"rearrangement","score":0.6460000276565552},{"id":"https://openalex.org/keywords/phosphorus-nitrogen-compounds","display_name":"phosphorus-nitrogen compounds","score":0.4269999861717224},{"id":"https://openalex.org/keywords/phosphorus-nitrogen-double-bond","display_name":"phosphorus-nitrogen double bond","score":0.4860000014305115},{"id":"https://openalex.org/keywords/phosphorus-nitrogen-triple-bond","display_name":"phosphorus-nitrogen triple bond","score":0.5870000123977661}],"concepts":[{"id":"https://openalex.org/C2777714323","wikidata":"https://www.wikidata.org/wiki/Q150808","display_name":"Tetradecane","level":2,"score":0.903853178024292},{"id":"https://openalex.org/C21774173","wikidata":"https://www.wikidata.org/wiki/Q2462024","display_name":"Trifluoromethanesulfonate","level":3,"score":0.8700103759765625},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8450964093208313},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6745542287826538},{"id":"https://openalex.org/C2776445513","wikidata":"https://www.wikidata.org/wiki/Q150731","display_name":"Undecane","level":2,"score":0.5679836273193359},{"id":"https://openalex.org/C24961977","wikidata":"https://www.wikidata.org/wiki/Q225972","display_name":"Bicyclic molecule","level":2,"score":0.4958404004573822},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.4464937746524811},{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.44122153520584106},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.2878684997558594},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.254966676235199},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07908380031585693},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/a800595h","doi":"https://doi.org/10.1039/a800595h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a800595h","pdf_url":null,"source":{"id":"https://openalex.org/S955628534","display_name":"Journal of the Chemical Society Perkin Transactions 1","issn_l":"1364-5463","issn":["1364-5463","1470-4358","1472-7781","2050-8263"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 1","raw_type":"journal-article"},{"id":"pmh:oai:research-information.bris.ac.uk:openaire_cris_publications/8bea9075-eb3f-44c7-bdd2-ac90147f51fd","doi":null,"is_oa":false,"landing_page_url":"https://research-information.bris.ac.uk/en/publications/8bea9075-eb3f-44c7-bdd2-ac90147f51fd","pdf_url":null,"source":{"id":"https://openalex.org/S7407055359","display_name":"Explore Bristol Research","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Alder, RW, Ellis, DD, Gleiter, R, Harris, CJ, Lange, H, Orpen, AG, Read, D & Taylor, PN 1998, 'Bridgehead diphosphines in the bicyclo[3.3.3]undecane and bicyclo[4.4.4]tetradecane series: synthesis, structure and properties', Journal of the Chemical Society, Perkin Transactions 1, pp. 1657 - 1668.","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320875","display_name":"Deutscher Akademischer Austauschdienst","ror":"https://ror.org/039djdh30"},{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320334627","display_name":"Engineering and Physical Sciences Research Council","ror":"https://ror.org/0439y7842"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":22,"referenced_works":["https://openalex.org/W1518274616","https://openalex.org/W1555832263","https://openalex.org/W1974325862","https://openalex.org/W1979499454","https://openalex.org/W1993383767","https://openalex.org/W1994645231","https://openalex.org/W2002107432","https://openalex.org/W2002530972","https://openalex.org/W2010752238","https://openalex.org/W2027369193","https://openalex.org/W2034285922","https://openalex.org/W2037250645","https://openalex.org/W2039338371","https://openalex.org/W2062370334","https://openalex.org/W2146229983","https://openalex.org/W2149158196","https://openalex.org/W2157002594","https://openalex.org/W2328752507","https://openalex.org/W2331644229","https://openalex.org/W2952402477","https://openalex.org/W2952592993","https://openalex.org/W2952650369"],"related_works":["https://openalex.org/W2126837159","https://openalex.org/W2125006220","https://openalex.org/W2025699453","https://openalex.org/W2949982925","https://openalex.org/W2316279917","https://openalex.org/W2103836632","https://openalex.org/W2950442137","https://openalex.org/W2028715545","https://openalex.org/W2013625910","https://openalex.org/W2951073134"],"abstract_inverted_index":{"Several":[0],"propellane":[1],"diphosphonium":[2],"salts":[3],"8":[4],"are":[5,21],"prepared":[6],"by":[7,107,170],"the":[8,65],"reaction":[9,130],"of":[10,131,139,151,179],"1,k":[11],"+":[12],"2-diphosphabicyclo[k.l.0]alkanes":[13],"6":[14],"with":[15,38,58,96,135,148,153,161],"\u03b1,\u03c9-alkanediol":[16],"bis-triflates":[17],"[bis(trifluoromethanesulfonates)];":[18],"their":[19],"properties":[20],"strongly":[22],"dependent":[23],"on":[24],"ring":[25],"size.":[26],"1,6-Diphosphoniatricyclo[4.4.4.0]tetradecane":[27],"bis-triflate":[28,79,93,157],"8d":[29],"is":[30,81,105,159,181,205],"stable":[31],"in":[32],"acidic":[33],"aqueous":[34],"solution,":[35],"and":[36,47,51,84,137,143,194,197],"reacts":[37,95],"nucleophiles":[39],"[X":[40],"=":[41],"F\u2013,":[42],"MeO\u2013,":[43],"H\u2013":[44],"(from":[45,49],"BH4\u2013)":[46],"R\u2013":[48],"Grignard":[50],"alkyllithium":[52],"reagents)]":[53],"to":[54,98,109,116,121,125,163,167,174,207],"give":[55,99,110,126],"products":[56],"13\u201318":[57],"partial":[59],"X\u2013P\u2013P+":[60],"bonding,":[61],"hydroxide":[62],"ion":[63],"gives":[64,155],"diphosphine":[66],"monooxide":[67],"12b":[68],"but":[69],"even":[70],"this":[71,204],"may":[72],"retain":[73],"some":[74],"P\u2013P":[75],"bonding.":[76],"However":[77,113],"1,5-diphosphoniatricyclo[3.3.3.0]undecane":[78],"8a":[80],"hydrolysed":[82],"irreversibly":[83],"much":[85],"more":[86],"rapidly":[87],"than":[88],"its":[89,183],"[4.4.4.0]":[90],"counterpart.":[91],"1,6-Diphosphoniatricyclo[4.4.3.0]tridecane":[92],"8c":[94],"NaBH4":[97],"a":[100,122],"hydride":[101,132],"adduct":[102,133],"15a":[103],"which":[104,158],"deprotonated":[106],"BunLi":[108],"1,6-diphosphabicyclo[4.4.3]tridecane":[111],"9c.":[112],"several":[114],"attempts":[115],"prepare":[117,168],"1,6-diphosphabicyclo[4.4.4]tetradecane":[118,169],"9d":[119],"led":[120],"deep-seated":[123],"rearrangement":[124],"1,4-bis(1-phospholan-1-yl)butane.":[127],"These":[128],"included":[129],"15b":[134],"BunLi,":[136],"debenzylations":[138],"1-benzyl-1-phosphonia-6-phosphabicyclo[4.4.4]tetradecane":[140],"trifluoromethanesulfonate":[141],"16b":[142],"1,6-dibenzyl-1,6-diphosphoniabicyclo[4.4.4]tetradecane":[144],"bromide":[145],"triflate":[146],"21":[147],"LiAlH4.":[149],"Reaction":[150],"cis-1,5-dibenzyl-1,5-diphosphacyclooctane":[152],"CH2(CH2OTf)2":[154],"1,5-dibenzyl-1,5-diphosphoniabicyclo[3.3.3]undecane":[156],"debenzylated":[160],"LiAlH4":[162],"1,5-diphosphabicyclo[3.3.3]undecane":[164,180],"9a.":[165],"Attempts":[166],"related":[171],"methods":[172],"lead":[173],"oligomerisation":[175],"reactions.":[176],"The":[177],"structure":[178],"reported;":[182],"He(I)":[184],"photoelectron":[185],"spectrum":[186],"shows":[187],"two":[188],"well":[189],"separated":[190],"bands":[191],"at":[192],"7.58":[193],"8.14":[195],"eV,":[196],"RHF/6-31G*":[198],"ab":[199],"initio":[200],"calculations":[201],"indicating":[202],"that":[203],"due":[206],"through-bond":[208],"interactions.":[209]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":2}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-06-24T00:00:00"}
