{"id":"https://openalex.org/W2139883844","doi":"https://doi.org/10.1002/anie.201002646","title":"Technetium\u201099 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4\u2212 Ions","display_name":"Technetium\u201099 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4\u2212 Ions","publication_year":2010,"publication_date":"2010-07-15","ids":{"openalex":"https://openalex.org/W2139883844","doi":"https://doi.org/10.1002/anie.201002646","mag":"2139883844","pmid":"https://pubmed.ncbi.nlm.nih.gov/20632429"},"language":"en","primary_location":{"id":"doi:10.1002/anie.201002646","doi":"https://doi.org/10.1002/anie.201002646","is_oa":false,"landing_page_url":"https://doi.org/10.1002/anie.201002646","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100623503","display_name":"Ping Yu","orcid":"https://orcid.org/0000-0001-7610-6512","observed_orcids":["https://orcid.org/0000-0001-7610-6512","https://orcid.org/0000-0002-6119-5177"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ping Yu","raw_affiliation_strings":["University of California, Davis, CA 95616, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of California, Davis, CA 95616, USA","institution_ids":["https://openalex.org/I84218800"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002614185","display_name":"Shuao Wang","orcid":"https://orcid.org/0000-0002-1526-1102","observed_orcids":["https://orcid.org/0000-0002-1526-1102","https://orcid.org/0000-0002-1842-339X"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shuao Wang","raw_affiliation_strings":["Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA)","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069665652","display_name":"Evgeny V. Alekseev","orcid":"https://orcid.org/0000-0002-4919-5211","observed_orcids":["https://orcid.org/0000-0002-4919-5211"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Evgeny\u2005V. Alekseev","raw_affiliation_strings":["Department of Crystallography, University of Kiel, 24118 Kiel, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Crystallography, University of Kiel, 24118 Kiel, Germany","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022613552","display_name":"Wulf Depmeier","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Wulf Depmeier","raw_affiliation_strings":["Department of Crystallography, University of Kiel, 24118 Kiel, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Crystallography, University of Kiel, 24118 Kiel, Germany","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018754620","display_name":"David T Hobbs","orcid":"https://orcid.org/0000-0003-1287-0233","observed_orcids":["https://orcid.org/0000-0003-1287-0233"]},"institutions":[{"id":"https://openalex.org/I2799909505","display_name":"Savannah River National Laboratory","ror":"https://ror.org/05vc7qy59","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I2799909505","https://openalex.org/I4210093701"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"David\u2005T. Hobbs","raw_affiliation_strings":["Savannah River National Laboratory, Aiken, SC 29808 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Savannah River National Laboratory, Aiken, SC 29808 (USA)","institution_ids":["https://openalex.org/I2799909505"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051810231","display_name":"Thomas E. Albrecht\u2010Schmitt","orcid":"https://orcid.org/0000-0002-2989-3311","observed_orcids":["https://orcid.org/0000-0002-2989-3311"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas\u2005E. Albrecht\u2010Schmitt","raw_affiliation_strings":["Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA)","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055182973","display_name":"Brian L. Phillips","orcid":"https://orcid.org/0000-0002-9256-7500","observed_orcids":["https://orcid.org/0000-0002-9256-7500"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brian\u2005L. Phillips","raw_affiliation_strings":["Department of Geosciences, SUNY Stony Brook, Stony Brook, NY 11794-2100, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Geosciences, SUNY Stony Brook, Stony Brook, NY 11794-2100, USA","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5091318688","display_name":"William H. Casey","orcid":"https://orcid.org/0000-0002-3275-6465","observed_orcids":["https://orcid.org/0000-0002-3275-6465","https://orcid.org/0000-0001-7718-7385"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"William\u2005H. Casey","raw_affiliation_strings":["Department of Chemistry, Department of Geology, University of California, Davis, One Shields Ave, Davis, CA 95616 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Department of Geology, University of California, Davis, One Shields Ave, Davis, CA 95616 (USA)","institution_ids":["https://openalex.org/I84218800"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":11.1565,"has_fulltext":false,"cited_by_count":57,"citation_normalized_percentile":{"value":0.9814306,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"49","issue":"34","first_page":"5975","last_page":"5977"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12524","display_name":"Chemical Synthesis and Characterization","score":0.7490000128746033,"subfield":{"id":"https://openalex.org/subfields/2311","display_name":"Waste Management and Disposal"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12524","display_name":"Chemical Synthesis and Characterization","score":0.7490000128746033,"subfield":{"id":"https://openalex.org/subfields/2311","display_name":"Waste Management and Disposal"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.23080000281333923,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12506","display_name":"Nuclear materials and radiation effects","score":0.006899999920278788,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/technetium-99","display_name":"technetium-99","score":0.9879999756813049},{"id":"https://openalex.org/keywords/magic-angle-spinning-nmr","display_name":"magic angle spinning NMR","score":0.9240000247955322},{"id":"https://openalex.org/keywords/ion-trapping","display_name":"ion trapping","score":0.7300000190734863},{"id":"https://openalex.org/keywords/nuclear-waste-remediation","display_name":"nuclear waste remediation","score":0.7129999995231628},{"id":"https://openalex.org/keywords/metal-sorption","display_name":"metal sorption","score":0.3319999873638153}],"concepts":[{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.8102240562438965},{"id":"https://openalex.org/C84935128","wikidata":"https://www.wikidata.org/wiki/Q1884060","display_name":"Magic angle spinning","level":3,"score":0.7030686736106873},{"id":"https://openalex.org/C67787023","wikidata":"https://www.wikidata.org/wiki/Q6954755","display_name":"NMR spectra database","level":3,"score":0.6478745937347412},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6126206517219543},{"id":"https://openalex.org/C522557706","wikidata":"https://www.wikidata.org/wiki/Q1054","display_name":"Technetium","level":2,"score":0.5275965332984924},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.5181668996810913},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.46623751521110535},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.43001458048820496},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3285546898841858},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.2988501787185669},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.28857457637786865},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.247582346200943},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10728508234024048},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/anie.201002646","doi":"https://doi.org/10.1002/anie.201002646","is_oa":false,"landing_page_url":"https://doi.org/10.1002/anie.201002646","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:20632429","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/20632429","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8204609271","display_name":"TAS::89 0227::TAS RECOVERY; RECOVERY ACT -  MATERIALS SCIENCE OF ACTINIDES -- EFRC; PI - PETER BURNS","funder_award_id":"DESC0001089","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":9,"referenced_works":["https://openalex.org/W1975739932","https://openalex.org/W2047970996","https://openalex.org/W2059091834","https://openalex.org/W2072740412","https://openalex.org/W2082009539","https://openalex.org/W2106457636","https://openalex.org/W2951061286","https://openalex.org/W4231716512","https://openalex.org/W4233933016"],"related_works":["https://openalex.org/W2950567919","https://openalex.org/W2295546055","https://openalex.org/W2763975995","https://openalex.org/W2524760255","https://openalex.org/W2947319859","https://openalex.org/W3097493941","https://openalex.org/W2914286928","https://openalex.org/W2588934327","https://openalex.org/W4399296092","https://openalex.org/W4366251410"],"abstract_inverted_index":{"No":[0],"chance":[1],"for":[2],"technetium:":[3],"99Tc":[4,46],"magic-angle":[5],"spinning":[6],"(MAS)":[7],"NMR":[8,48],"spectra":[9,41,49],"show":[10,54],"that":[11,55],"TcO4\u2212":[12,57],"ions,":[13],"which":[14],"are":[15,42],"generated":[16],"by":[17],"nuclear":[18,65],"fission":[19],"and":[20,31,53],"can":[21,25,59],"contaminate":[22],"the":[23,29,44,56],"environment,":[24],"be":[26,60],"trapped":[27],"within":[28],"channels":[30],"cavities":[32],"of":[33],"a":[34],"cationic":[35],"framework":[36],"material":[37],"(see":[38],"picture).":[39],"These":[40],"among":[43],"first":[45],"MAS":[47],"reported":[50],"to":[51],"date,":[52],"ions":[58],"efficiently":[61],"removed":[62],"from":[63],"simulated":[64],"waste":[66],"solutions.":[67]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":2},{"year":2012,"cited_by_count":5}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}