{"id":"https://openalex.org/W2129727174","doi":"https://doi.org/10.1002/macp.1980.021810513","title":"Kinetics of nitrogen dioxide initiated polymerization of acrylamide","display_name":"Kinetics of nitrogen dioxide initiated polymerization of acrylamide","publication_year":1980,"publication_date":"1980-04-01","ids":{"openalex":"https://openalex.org/W2129727174","doi":"https://doi.org/10.1002/macp.1980.021810513","mag":"2129727174"},"language":"en","primary_location":{"id":"doi:10.1002/macp.1980.021810513","doi":"https://doi.org/10.1002/macp.1980.021810513","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.1980.021810513","pdf_url":null,"source":{"id":"https://openalex.org/S4210221479","display_name":"Die Makromolekulare Chemie","issn_l":"0025-116X","issn":["0025-116X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Die Makromolekulare Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5036026749","display_name":"Suraj N. Bhadani","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I112700253","display_name":"Ranchi University","ror":"https://ror.org/01hcvr073","country_code":"IN","type":"education","lineage":["https://openalex.org/I112700253"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Suraj N. Bhadani","raw_affiliation_strings":["Department of Chemistry, Ranchi University, Ranchi-8, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ranchi University, Ranchi-8, India","institution_ids":["https://openalex.org/I112700253"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030686819","display_name":"Yugal K. Prasad","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I112700253","display_name":"Ranchi University","ror":"https://ror.org/01hcvr073","country_code":"IN","type":"education","lineage":["https://openalex.org/I112700253"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Yugal K. Prasad","raw_affiliation_strings":["Department of Chemistry, Ranchi University, Ranchi-8, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ranchi University, Ranchi-8, India","institution_ids":["https://openalex.org/I112700253"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5036026749"],"corresponding_institution_ids":["https://openalex.org/I112700253"],"apc_list":null,"apc_paid":null,"fwci":2.2145,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.82386069,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"181","issue":"5","first_page":"1089","last_page":"1095"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.961899995803833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.961899995803833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.030700000002980232,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.003700000001117587,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acrylamide-polymerization","display_name":"acrylamide polymerization","score":0.9279999732971191},{"id":"https://openalex.org/keywords/free-radical-polymerization-kinetics","display_name":"radical polymerization kinetics","score":0.6899999976158142},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.8130000233650208},{"id":"https://openalex.org/keywords/copolymer-composition","display_name":"copolymer composition","score":0.8019999861717224},{"id":"https://openalex.org/keywords/free-radical-initiation","display_name":"free radical initiation","score":0.6840000152587891},{"id":"https://openalex.org/keywords/dimethylformamide","display_name":"dimethylformamide","score":0.6850000023841858}],"concepts":[{"id":"https://openalex.org/C2779402116","wikidata":"https://www.wikidata.org/wiki/Q342939","display_name":"Acrylamide","level":4,"score":0.8115306496620178},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.8044182062149048},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.7150532007217407},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.6422972679138184},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6179988384246826},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.540818452835083},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5307564735412598},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.4934021532535553},{"id":"https://openalex.org/C200113979","wikidata":"https://www.wikidata.org/wiki/Q3262188","display_name":"Solution polymerization","level":4,"score":0.4692884385585785},{"id":"https://openalex.org/C90958600","wikidata":"https://www.wikidata.org/wiki/Q3406609","display_name":"Precipitation polymerization","level":5,"score":0.42926186323165894},{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.4290611445903778},{"id":"https://openalex.org/C53856295","wikidata":"https://www.wikidata.org/wiki/Q6137196","display_name":"Bulk polymerization","level":5,"score":0.416487455368042},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3240417242050171},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.31416192650794983},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1359964907169342},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/macp.1980.021810513","doi":"https://doi.org/10.1002/macp.1980.021810513","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.1980.021810513","pdf_url":null,"source":{"id":"https://openalex.org/S4210221479","display_name":"Die Makromolekulare Chemie","issn_l":"0025-116X","issn":["0025-116X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Die Makromolekulare Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W1540257084","https://openalex.org/W1820325537","https://openalex.org/W1993117229","https://openalex.org/W2031053384","https://openalex.org/W2140422474","https://openalex.org/W2169377399","https://openalex.org/W4232322027","https://openalex.org/W4302354942"],"related_works":["https://openalex.org/W2077255343","https://openalex.org/W1952804248","https://openalex.org/W2063780931","https://openalex.org/W2369853036","https://openalex.org/W2393054974","https://openalex.org/W1965984680","https://openalex.org/W2052704334","https://openalex.org/W1511138906","https://openalex.org/W2045870746","https://openalex.org/W2370497809"],"abstract_inverted_index":{"Abstract":[0],"The":[1,12,35,51,68,78],"polymerization":[2,17,41,79],"of":[3,15,23,31,39,53,64],"acrylamide":[4,54],"initiated":[5,83],"by":[6,84],"NO2":[7,65],"in":[8,61,66,75],"DMF":[9],"was":[10,42,55,70],"investigated.":[11],"initial":[13],"rate":[14],"the":[16,20,24,32,40],"increases":[18],"with":[19,59],"first":[21],"power":[22,30],"monomer":[25],"concentration":[26],"and":[27],"a":[28,62],"half":[29],"initiator":[33],"concentration.":[34],"overall":[36],"activation":[37],"energy":[38],"determined":[43],"to":[44,72,81],"be":[45,73,82],"about":[46],"20":[47],"kcal/mol":[48],"(84":[49],"kJ/mol).":[50],"copolymerization":[52],"also":[56],"carried":[57],"out":[58],"MMA":[60,76],"solution":[63],"DMF.":[67],"copolymer":[69],"found":[71],"enriched":[74],"content.":[77],"appeared":[80],"free":[85],"radicals.":[86]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}