{"id":"https://openalex.org/W2126571061","doi":"https://doi.org/10.1021/cs400333q","title":"Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin","display_name":"Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin","publication_year":2013,"publication_date":"2013-05-21","ids":{"openalex":"https://openalex.org/W2126571061","doi":"https://doi.org/10.1021/cs400333q","mag":"2126571061"},"language":"en","primary_location":{"id":"doi:10.1021/cs400333q","doi":"https://doi.org/10.1021/cs400333q","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cs400333q","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2126571061"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5033226796","display_name":"Julian M. W. Chan","orcid":"https://orcid.org/0000-0002-2734-6496","observed_orcids":["https://orcid.org/0000-0002-2734-6496"]},"institutions":[{"id":"https://openalex.org/I38257878","display_name":"Energy Biosciences Institute","ror":"https://ror.org/04pgv9784","country_code":"US","type":"facility","lineage":["https://openalex.org/I38257878"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Julian M. W. Chan","raw_affiliation_strings":["Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I38257878"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States","institution_ids":["https://openalex.org/I38257878"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109968903","display_name":"\u0160tefan Bauer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I38257878","display_name":"Energy Biosciences Institute","ror":"https://ror.org/04pgv9784","country_code":"US","type":"facility","lineage":["https://openalex.org/I38257878"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stefan Bauer","raw_affiliation_strings":["Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I38257878"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States","institution_ids":["https://openalex.org/I38257878"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032131680","display_name":"Hagit Sorek","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I38257878","display_name":"Energy Biosciences Institute","ror":"https://ror.org/04pgv9784","country_code":"US","type":"facility","lineage":["https://openalex.org/I38257878"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hagit Sorek","raw_affiliation_strings":["Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I38257878"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States","institution_ids":["https://openalex.org/I38257878"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025530962","display_name":"Sanil Sreekumar","orcid":"https://orcid.org/0000-0003-3299-4735","observed_orcids":["https://orcid.org/0000-0003-3299-4735"]},"institutions":[{"id":"https://openalex.org/I38257878","display_name":"Energy Biosciences Institute","ror":"https://ror.org/04pgv9784","country_code":"US","type":"facility","lineage":["https://openalex.org/I38257878"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sanil Sreekumar","raw_affiliation_strings":["Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I38257878"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States","institution_ids":["https://openalex.org/I38257878"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100366661","display_name":"Kun Wang","orcid":"https://orcid.org/0000-0002-4701-5344","observed_orcids":["https://orcid.org/0000-0002-4701-5344"]},"institutions":[{"id":"https://openalex.org/I31683504","display_name":"Beijing Forestry University","ror":"https://ror.org/04xv2pc41","country_code":"CN","type":"education","lineage":["https://openalex.org/I1327237609","https://openalex.org/I31683504","https://openalex.org/I4210127390"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["CN","US"],"is_corresponding":false,"raw_author_name":"Kun Wang","raw_affiliation_strings":["Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China","Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","Institute of Biomass#R#Chemistry#R#and Technology, Beijing Forestry University, Beijing 100083, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China","institution_ids":["https://openalex.org/I31683504"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Institute of Biomass#R#Chemistry#R#and Technology, Beijing Forestry University, Beijing 100083, China","institution_ids":["https://openalex.org/I31683504"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5044828615","display_name":"F. Dean Toste","orcid":"https://orcid.org/0000-0001-8018-2198","observed_orcids":["https://orcid.org/0000-0001-8018-2198"]},"institutions":[{"id":"https://openalex.org/I38257878","display_name":"Energy Biosciences Institute","ror":"https://ror.org/04pgv9784","country_code":"US","type":"facility","lineage":["https://openalex.org/I38257878"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"F. Dean Toste","raw_affiliation_strings":["Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United States","institution_ids":["https://openalex.org/I38257878"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, Berkeley, California#R#94720, United States","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"Energy Biosciences Institute (EBI), Berkeley, California 94720, United#R#States","institution_ids":["https://openalex.org/I38257878"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5044828615"],"corresponding_institution_ids":["https://openalex.org/I38257878","https://openalex.org/I95457486"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":9.7139,"has_fulltext":false,"cited_by_count":174,"citation_normalized_percentile":{"value":0.98775895,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":100},"biblio":{"volume":"3","issue":"6","first_page":"1369","last_page":"1377"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10171","display_name":"Biofuel production and bioconversion","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lignin-depolymerization","display_name":"lignin depolymerization","score":0.8690000176429749},{"id":"https://openalex.org/keywords/vanadium-catalysts","display_name":"vanadium catalysts","score":0.9729999899864197},{"id":"https://openalex.org/keywords/miscanthus-giganteus","display_name":"Miscanthus \u00d7 giganteus","score":0.9869999885559082},{"id":"https://openalex.org/keywords/organosolv-lignin","display_name":"organosolv lignin","score":0.8119999766349792},{"id":"https://openalex.org/keywords/beta-o-4-linkage-cleavage","display_name":"\u03b2-O-4 bond cleavage","score":0.8579999804496765},{"id":"https://openalex.org/keywords/lignin-model-compounds","display_name":"lignin model compounds","score":0.6759999990463257},{"id":"https://openalex.org/keywords/molecular-weight-reduction","display_name":"molecular weight reduction","score":0.824999988079071},{"id":"https://openalex.org/keywords/biomass-valorization","display_name":"biomass valorization","score":0.6299999952316284}],"concepts":[{"id":"https://openalex.org/C2780761721","wikidata":"https://www.wikidata.org/wiki/Q7102099","display_name":"Organosolv","level":3,"score":0.9828085899353027},{"id":"https://openalex.org/C49852136","wikidata":"https://www.wikidata.org/wiki/Q906487","display_name":"Depolymerization","level":2,"score":0.935893177986145},{"id":"https://openalex.org/C2781052789","wikidata":"https://www.wikidata.org/wiki/Q184817","display_name":"Lignin","level":2,"score":0.9110942482948303},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7936916351318359},{"id":"https://openalex.org/C504678139","wikidata":"https://www.wikidata.org/wiki/Q722","display_name":"Vanadium","level":2,"score":0.7503307461738586},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7470906972885132},{"id":"https://openalex.org/C63179538","wikidata":"https://www.wikidata.org/wiki/Q854422","display_name":"Gel permeation chromatography","level":3,"score":0.6113214492797852},{"id":"https://openalex.org/C2779012619","wikidata":"https://www.wikidata.org/wiki/Q131542","display_name":"Miscanthus","level":4,"score":0.5763021111488342},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4919755160808563},{"id":"https://openalex.org/C2779679103","wikidata":"https://www.wikidata.org/wiki/Q5251805","display_name":"Degradation (telecommunications)","level":2,"score":0.4198175072669983},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.21718183159828186},{"id":"https://openalex.org/C156380964","wikidata":"https://www.wikidata.org/wiki/Q18556","display_name":"Bioenergy","level":3,"score":0.09491395950317383},{"id":"https://openalex.org/C53991642","wikidata":"https://www.wikidata.org/wiki/Q128991","display_name":"Biofuel","level":2,"score":0.0700613260269165},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C18903297","wikidata":"https://www.wikidata.org/wiki/Q7150","display_name":"Ecology","level":1,"score":0.0},{"id":"https://openalex.org/C76155785","wikidata":"https://www.wikidata.org/wiki/Q418","display_name":"Telecommunications","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/cs400333q","doi":"https://doi.org/10.1021/cs400333q","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cs400333q","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.706.8585","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.706.8585","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://www.julianchangroup.com/wp-content/uploads/2015/01/2013-ACS-Catal..pdf","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.6000000238418579,"display_name":"Responsible consumption and production","id":"https://metadata.un.org/sdg/12"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":76,"referenced_works":["https://openalex.org/W318912655","https://openalex.org/W1860349061","https://openalex.org/W1971062851","https://openalex.org/W1971144082","https://openalex.org/W1976950856","https://openalex.org/W1987576588","https://openalex.org/W1990717355","https://openalex.org/W1993514853","https://openalex.org/W1995234112","https://openalex.org/W1997074991","https://openalex.org/W1997164908","https://openalex.org/W1998321859","https://openalex.org/W1998435025","https://openalex.org/W1999057729","https://openalex.org/W2001135860","https://openalex.org/W2002753471","https://openalex.org/W2003321485","https://openalex.org/W2004040943","https://openalex.org/W2005291574","https://openalex.org/W2005960625","https://openalex.org/W2007444810","https://openalex.org/W2007790555","https://openalex.org/W2008655313","https://openalex.org/W2012417684","https://openalex.org/W2020195528","https://openalex.org/W2025207540","https://openalex.org/W2026624647","https://openalex.org/W2027700190","https://openalex.org/W2028316442","https://openalex.org/W2028354586","https://openalex.org/W2031509896","https://openalex.org/W2032835873","https://openalex.org/W2040378517","https://openalex.org/W2053689637","https://openalex.org/W2057510643","https://openalex.org/W2060684208","https://openalex.org/W2062565578","https://openalex.org/W2064003288","https://openalex.org/W2064445903","https://openalex.org/W2066003760","https://openalex.org/W2067122154","https://openalex.org/W2071247148","https://openalex.org/W2071592915","https://openalex.org/W2076314081","https://openalex.org/W2076592452","https://openalex.org/W2081123169","https://openalex.org/W2083082072","https://openalex.org/W2091670372","https://openalex.org/W2093359485","https://openalex.org/W2093848319","https://openalex.org/W2102288076","https://openalex.org/W2105503244","https://openalex.org/W2108979462","https://openalex.org/W2111858371","https://openalex.org/W2115321209","https://openalex.org/W2120446525","https://openalex.org/W2125056538","https://openalex.org/W2131504904","https://openalex.org/W2138390205","https://openalex.org/W2145332383","https://openalex.org/W2148999761","https://openalex.org/W2149902591","https://openalex.org/W2150962987","https://openalex.org/W2151818920","https://openalex.org/W2157038473","https://openalex.org/W2159635407","https://openalex.org/W2163011885","https://openalex.org/W2166109955","https://openalex.org/W2166468358","https://openalex.org/W2167277927","https://openalex.org/W2172132247","https://openalex.org/W2319563718","https://openalex.org/W2320095510","https://openalex.org/W2320507318","https://openalex.org/W2324066399","https://openalex.org/W4401655898"],"related_works":["https://openalex.org/W2925308592","https://openalex.org/W1978613484","https://openalex.org/W4399352336","https://openalex.org/W7025090082","https://openalex.org/W2395125393","https://openalex.org/W2163514255","https://openalex.org/W1902349022","https://openalex.org/W4241820475","https://openalex.org/W2991441415","https://openalex.org/W3181478357"],"abstract_inverted_index":{"Lignin":[0],"samples":[1],"isolated":[2],"from":[3],"Miscanthus":[4],"giganteus":[5],"using":[6],"organosolv":[7],"processes":[8],"were":[9,15,59,77,84],"treated":[10],"with":[11,26],"vanadium":[12],"catalysts":[13],"that":[14,23,56],"previously":[16],"developed":[17],"in":[18,31,38,62,68],"our":[19],"group.":[20],"We":[21],"demonstrate":[22],"the":[24,63,69,81],"catalyst":[25],"high":[27],"\u03b2-O-4\u2032":[28,57],"bond-cleaving":[29],"activity":[30],"dimeric":[32],"lignin":[33,72],"models":[34],"was":[35,44],"also":[36,78],"effective":[37],"depolymerizing":[39],"actual":[40],"lignin.":[41],"Molecular":[42],"weight-lowering":[43],"evidenced":[45],"by":[46,88],"gel":[47],"permeation":[48],"chromatography":[49],"(GPC),":[50],"whereas":[51],"2D":[52],"NMR":[53],"experiments":[54],"showed":[55],"linkages":[58],"selectively":[60],"cleaved":[61],"degradation":[64,75],"process,":[65],"just":[66],"as":[67],"case":[70],"of":[71],"models.":[73],"Monophenolic":[74],"products":[76],"formed,":[79],"and":[80,86],"individual":[82],"molecules":[83],"identified":[85],"quantified":[87],"GC/MS.":[89]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":9},{"year":2024,"cited_by_count":10},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":9},{"year":2021,"cited_by_count":13},{"year":2020,"cited_by_count":9},{"year":2019,"cited_by_count":20},{"year":2018,"cited_by_count":13},{"year":2017,"cited_by_count":18},{"year":2016,"cited_by_count":27},{"year":2015,"cited_by_count":27},{"year":2014,"cited_by_count":14},{"year":2013,"cited_by_count":2}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}