{"id":"https://openalex.org/W2124232014","doi":"https://doi.org/10.1002/polb.23642","title":"Small molecule-mediated glass transition of acrylic copolymers: Effect of hydrogen bonding strength on glass transition temperature","display_name":"Small molecule-mediated glass transition of acrylic copolymers: Effect of hydrogen bonding strength on glass transition temperature","publication_year":2014,"publication_date":"2014-12-01","ids":{"openalex":"https://openalex.org/W2124232014","doi":"https://doi.org/10.1002/polb.23642","mag":"2124232014"},"language":"en","primary_location":{"id":"doi:10.1002/polb.23642","doi":"https://doi.org/10.1002/polb.23642","is_oa":false,"landing_page_url":"https://doi.org/10.1002/polb.23642","pdf_url":null,"source":{"id":"https://openalex.org/S175770247","display_name":"Journal of Polymer Science Part B Polymer Physics","issn_l":"0887-6266","issn":["0887-6266","1099-0488"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","poland-20"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part B: Polymer Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037187271","display_name":"Chongyang Liu","orcid":"https://orcid.org/0000-0001-8045-2944","observed_orcids":["https://orcid.org/0000-0001-8045-2944"]},"institutions":[{"id":"https://openalex.org/I143593769","display_name":"East China University of Science and Technology","ror":"https://ror.org/01vyrm377","country_code":"CN","type":"education","lineage":["https://openalex.org/I143593769"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chongyang Liu","raw_affiliation_strings":["Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China","institution_ids":["https://openalex.org/I143593769"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007113754","display_name":"Xiaotong Yin","orcid":"https://orcid.org/0000-0001-9627-0336","observed_orcids":["https://orcid.org/0000-0001-9627-0336"]},"institutions":[{"id":"https://openalex.org/I143593769","display_name":"East China University of Science and Technology","ror":"https://ror.org/01vyrm377","country_code":"CN","type":"education","lineage":["https://openalex.org/I143593769"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiaotong Yin","raw_affiliation_strings":["Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China","institution_ids":["https://openalex.org/I143593769"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023764890","display_name":"Yu Lin","orcid":"https://orcid.org/0000-0002-5379-5359","observed_orcids":["https://orcid.org/0000-0002-5379-5359"]},"institutions":[{"id":"https://openalex.org/I143593769","display_name":"East China University of Science and Technology","ror":"https://ror.org/01vyrm377","country_code":"CN","type":"education","lineage":["https://openalex.org/I143593769"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yu Lin","raw_affiliation_strings":["Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China","institution_ids":["https://openalex.org/I143593769"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045375527","display_name":"Aiguo Guan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I143593769","display_name":"East China University of Science and Technology","ror":"https://ror.org/01vyrm377","country_code":"CN","type":"education","lineage":["https://openalex.org/I143593769"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Aiguo Guan","raw_affiliation_strings":["Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China","institution_ids":["https://openalex.org/I143593769"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032902004","display_name":"Guozhang Wu","orcid":"https://orcid.org/0000-0002-4139-2317","observed_orcids":["https://orcid.org/0000-0002-4139-2317"]},"institutions":[{"id":"https://openalex.org/I143593769","display_name":"East China University of Science and Technology","ror":"https://ror.org/01vyrm377","country_code":"CN","type":"education","lineage":["https://openalex.org/I143593769"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Guozhang Wu","raw_affiliation_strings":["Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science & Engineering; East China University of Science & Technology; Shanghai 200237 China","institution_ids":["https://openalex.org/I143593769"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5032902004"],"corresponding_institution_ids":["https://openalex.org/I143593769"],"apc_list":{"value":3200,"currency":"USD","value_usd":3200},"apc_paid":null,"fwci":0.6609,"has_fulltext":false,"cited_by_count":31,"citation_normalized_percentile":{"value":0.63116258,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"53","issue":"6","first_page":"400","last_page":"408"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10544","display_name":"Glass properties and applications","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/2503","display_name":"Ceramics and Composites"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/glass-transition-temperature","display_name":"glass transition temperature","score":0.8960000276565552},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.7110000252723694},{"id":"https://openalex.org/keywords/acrylic-copolymers","display_name":"acrylate copolymers","score":0.8899999856948853},{"id":"https://openalex.org/keywords/small-molecule-additives","display_name":"small molecule additives","score":0.7979999780654907},{"id":"https://openalex.org/keywords/self-association","display_name":"self-association","score":0.5490000247955322},{"id":"https://openalex.org/keywords/intermolecular-hydrogen-bonding","display_name":"intermolecular hydrogen bonding","score":0.7480000257492065},{"id":"https://openalex.org/keywords/polymer-blends","display_name":"polymer blends","score":0.34700000286102295}],"concepts":[{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.8541222810745239},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.6334437131881714},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.6001132726669312},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5632660388946533},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5627153515815735},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5171329379081726},{"id":"https://openalex.org/C166950319","wikidata":"https://www.wikidata.org/wiki/Q245031","display_name":"Intermolecular force","level":3,"score":0.4720386266708374},{"id":"https://openalex.org/C2779989194","wikidata":"https://www.wikidata.org/wiki/Q343016","display_name":"Acrylate","level":4,"score":0.4653051495552063},{"id":"https://openalex.org/C2777566558","wikidata":"https://www.wikidata.org/wiki/Q28917","display_name":"Styrene","level":4,"score":0.4567599892616272},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.4451933801174164},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.41939273476600647},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.36169782280921936},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.16373485326766968},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.15107190608978271},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14726990461349487},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/polb.23642","doi":"https://doi.org/10.1002/polb.23642","is_oa":false,"landing_page_url":"https://doi.org/10.1002/polb.23642","pdf_url":null,"source":{"id":"https://openalex.org/S175770247","display_name":"Journal of Polymer Science Part B Polymer Physics","issn_l":"0887-6266","issn":["0887-6266","1099-0488"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","poland-20"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part B: Polymer Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3319088836","display_name":null,"funder_award_id":"51373053","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320335787","display_name":"Fundamental Research Funds for the Central Universities","ror":null}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W1975030247","https://openalex.org/W1978572996","https://openalex.org/W1979739098","https://openalex.org/W1982311462","https://openalex.org/W1985071287","https://openalex.org/W1998366922","https://openalex.org/W1998647396","https://openalex.org/W2004094659","https://openalex.org/W2004101375","https://openalex.org/W2006747065","https://openalex.org/W2017004908","https://openalex.org/W2023633642","https://openalex.org/W2026074179","https://openalex.org/W2028534114","https://openalex.org/W2030339761","https://openalex.org/W2033855051","https://openalex.org/W2035356948","https://openalex.org/W2039740050","https://openalex.org/W2040982169","https://openalex.org/W2047948690","https://openalex.org/W2057009283","https://openalex.org/W2057771908","https://openalex.org/W2064749237","https://openalex.org/W2068850127","https://openalex.org/W2072753467","https://openalex.org/W2074293901","https://openalex.org/W2080331283","https://openalex.org/W2090685074","https://openalex.org/W2092040054","https://openalex.org/W2094208954","https://openalex.org/W2094875280","https://openalex.org/W2117441301","https://openalex.org/W2119394605","https://openalex.org/W2126922559","https://openalex.org/W2131411000","https://openalex.org/W2151228606","https://openalex.org/W2163594599","https://openalex.org/W2314521610","https://openalex.org/W2321947895","https://openalex.org/W2322086357","https://openalex.org/W2329557602","https://openalex.org/W2995725678"],"related_works":["https://openalex.org/W2336389233","https://openalex.org/W2903917472","https://openalex.org/W2076035817","https://openalex.org/W1971813731","https://openalex.org/W3032186458","https://openalex.org/W2071113575","https://openalex.org/W1888486357","https://openalex.org/W2023633642","https://openalex.org/W1994410539","https://openalex.org/W2312186031"],"abstract_inverted_index":{"Poly(styrene-co-ethyl":[0],"acrylate)":[1],"[P(St-co-EA)]":[2],"with":[3,10,45],"different":[4],"ratios":[5],"of":[6,21,60,105,114,133,135,142],"St/EA":[7,47,116],"was":[8,71,109,144],"mixed":[9],"the":[11,19,26,41,61,68,89,100,106,115,119,122,128,136],"small":[12,62,77,90,137],"molecule":[13,63,78],"4,4\u2032-thio-bis(6-tert-butyl-m-methyl":[14],"phenol)":[15],"(AO300)":[16],"to":[17,54,93,146],"investigate":[18],"influence":[20],"hydrogen":[22,101,151],"bonding":[23,152],"strength":[24],"on":[25,149],"glass":[27,31],"transition":[28,32],"behavior.":[29],"The":[30,139],"temperature":[33],"(Tg)":[34],"linearly":[35,129],"increased":[36,46],"after":[37],"adding":[38],"AO300,":[39],"and":[40,112,154],"slope":[42],"value":[43],"decreased":[44],"ratio.":[48,117],"All":[49],"lines":[50,131],"could":[51],"be":[52,94],"extended":[53,130],"62":[55],"\u00b0C,":[56],"demonstrating":[57],"that":[58,75,88],"Tg":[59,124,141],"in":[64],"situ":[65],"detected":[66],"by":[67,76],"polymer":[69,108],"chain":[70],"much":[72],"higher":[73],"than":[74],"itself":[79],"(29":[80],"\u00b0C).":[81],"Fourier":[82],"transform":[83],"infrared":[84],"spectroscopy":[85],"analysis":[86],"showed":[87],"molecules":[91],"began":[92],"self-associated":[95],"at":[96],"a":[97],"concentration":[98],"where":[99],"bonded":[102],"carbonyl":[103],"ratio":[104],"bulk":[107],"approximately":[110],"0.5":[111],"irrespective":[113],"Above":[118],"critical":[120],"loading,":[121],"mixture's":[123],"negatively":[125],"deviated":[126],"from":[127],"because":[132],"self-association":[134],"molecules.":[138],"apparent":[140],"AO300":[143],"found":[145],"strongly":[147],"depend":[148],"intermolecular":[150],"number":[153],"strength.":[155],"\u00a9":[156],"2014":[157],"Wiley":[158],"Periodicals,":[159],"Inc.":[160],"J.":[161],"Polym.":[162,166],"Sci.,":[163],"Part":[164],"B:":[165],"Phys.":[167],"2015,":[168],"53,":[169],"400\u2013408":[170]},"counts_by_year":[{"year":2026,"cited_by_count":5},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}