{"id":"https://openalex.org/W2122913486","doi":"https://doi.org/10.1039/dt9730000470","title":"Surface oxidation of uranium metal as studied by X-ray photoelectron spectroscopy","display_name":"Surface oxidation of uranium metal as studied by X-ray photoelectron spectroscopy","publication_year":1973,"publication_date":"1973-01-01","ids":{"openalex":"https://openalex.org/W2122913486","doi":"https://doi.org/10.1039/dt9730000470","mag":"2122913486"},"language":"en","primary_location":{"id":"doi:10.1039/dt9730000470","doi":"https://doi.org/10.1039/dt9730000470","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9730000470","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5108514482","display_name":"Geoffrey Charles Allen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I56030857","display_name":"Central Electricity Generating Board","ror":"https://ror.org/01a4t3393","country_code":"GB","type":"government","lineage":["https://openalex.org/I56030857"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"G. C. Allen","raw_affiliation_strings":["Berkeley Nuclear Laboratories, Central Electricity Generating Board, Berkeley, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Berkeley Nuclear Laboratories, Central Electricity Generating Board, Berkeley, England","institution_ids":["https://openalex.org/I56030857"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5110046166","display_name":"P. M. Tucker","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I56030857","display_name":"Central Electricity Generating Board","ror":"https://ror.org/01a4t3393","country_code":"GB","type":"government","lineage":["https://openalex.org/I56030857"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"P. M. Tucker","raw_affiliation_strings":["Berkeley Nuclear Laboratories, Central Electricity Generating Board, Berkeley, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Berkeley Nuclear Laboratories, Central Electricity Generating Board, Berkeley, England","institution_ids":["https://openalex.org/I56030857"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I56030857"],"apc_list":null,"apc_paid":null,"fwci":6.1026,"has_fulltext":false,"cited_by_count":68,"citation_normalized_percentile":{"value":0.97128394,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":null,"issue":"5","first_page":"470","last_page":"470"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11242","display_name":"Nuclear Materials and Properties","score":0.8022000193595886,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11242","display_name":"Nuclear Materials and Properties","score":0.8022000193595886,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.16300000250339508,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12039","display_name":"Electron and X-Ray Spectroscopy Techniques","score":0.022600000724196434,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/uranium-oxidation","display_name":"uranium oxidation","score":0.8349999785423279},{"id":"https://openalex.org/keywords/uranium-metal","display_name":"uranium metal","score":0.6100000143051147},{"id":"https://openalex.org/keywords/surface-oxide-layer","display_name":"surface oxide layer","score":0.722000002861023},{"id":"https://openalex.org/keywords/uranium-dioxide","display_name":"uranium dioxide","score":0.8410000205039978},{"id":"https://openalex.org/keywords/uranium-monoxide","display_name":"uranium monoxide","score":0.7710000276565552},{"id":"https://openalex.org/keywords/uranium-carbide","display_name":"uranium carbide","score":0.9779999852180481},{"id":"https://openalex.org/keywords/interdiffusion","display_name":"interdiffusion","score":0.8889999985694885},{"id":"https://openalex.org/keywords/binding-energy","display_name":"binding energy","score":0.703000009059906},{"id":"https://openalex.org/keywords/surface-composition","display_name":"surface composition","score":0.3790000081062317},{"id":"https://openalex.org/keywords/high-temperature-oxidation","display_name":"high-temperature oxidation","score":0.6759999990463257}],"concepts":[{"id":"https://openalex.org/C555451288","wikidata":"https://www.wikidata.org/wiki/Q1098","display_name":"Uranium","level":2,"score":0.9596075415611267},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.826766848564148},{"id":"https://openalex.org/C2779198548","wikidata":"https://www.wikidata.org/wiki/Q2500122","display_name":"Uranium oxide","level":3,"score":0.7466444373130798},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.699301540851593},{"id":"https://openalex.org/C2778472420","wikidata":"https://www.wikidata.org/wiki/Q378379","display_name":"Uranium dioxide","level":3,"score":0.6102718114852905},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.5731751918792725},{"id":"https://openalex.org/C197751951","wikidata":"https://www.wikidata.org/wiki/Q1046363","display_name":"Surface layer","level":3,"score":0.51804518699646},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.46316492557525635},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.459655225276947},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.45651909708976746},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4222240447998047},{"id":"https://openalex.org/C93282013","wikidata":"https://www.wikidata.org/wiki/Q420754","display_name":"Binding energy","level":2,"score":0.4136383533477783},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.38404932618141174},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3552657663822174},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.18162325024604797},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.12281712889671326},{"id":"https://openalex.org/C107872376","wikidata":"https://www.wikidata.org/wiki/Q321355","display_name":"Environmental chemistry","level":1,"score":0.08681187033653259},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.06302991509437561},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.051946938037872314},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/dt9730000470","doi":"https://doi.org/10.1039/dt9730000470","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9730000470","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2010660542","https://openalex.org/W7096945422","https://openalex.org/W2783102929","https://openalex.org/W3113035067","https://openalex.org/W2371549434","https://openalex.org/W2036266290","https://openalex.org/W2153936698","https://openalex.org/W2025829900","https://openalex.org/W2047501939","https://openalex.org/W1969354458"],"abstract_inverted_index":{"X-Ray":[0],"photoelectron":[1],"spectroscopy":[2],"has":[3],"been":[4,106],"used":[5],"to":[6,49,115],"study":[7],"the":[8,35,41,65,81,94],"oxidation":[9],"of":[10,27,37,70,73,83,97,118],"uranium":[11,39,54,84,98,120],"metal.":[12],"The":[13],"results":[14],"indicate":[15],"that":[16,61,89],"even":[17],"at":[18],"1073":[19],"K":[20],"in":[21,100],"a":[22,51,71],"residual":[23],"oxygen":[24],"partial":[25],"pressure":[26],"less":[28],"than":[29],"1":[30],"\u00d7":[31],"10\u20138":[32],"N":[33],"m\u20132":[34],"interdiffusion":[36],"pure":[38,53,74,119],"and":[40,77,102],"surface":[42,66],"oxide":[43],"film":[44],"is":[45,57,68,87],"not":[46],"sufficiently":[47],"rapid":[48],"produce":[50],"completely":[52],"surface.":[55,111],"Evidence":[56],"presented":[58],"which":[59],"suggests":[60],"under":[62],"spectrometer":[63],"conditions":[64],"layer":[67],"composed":[69],"mixture":[72],"uranium,":[75],"UO2":[76],"\u2018UO\u2019":[78],"stabilised":[79],"by":[80],"presence":[82],"carbide.":[85],"It":[86],"shown":[88],"values":[90,113],"previously":[91],"reported":[92],"for":[93],"binding":[95],"energies":[96],"are":[99,121],"error":[101],"they":[103],"must":[104],"have":[105],"obtained":[107],"from":[108],"an":[109],"oxidised":[110],"Accordingly":[112],"believed":[114],"be":[116],"representative":[117],"presented.":[122]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":4},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}