{"id":"https://openalex.org/W2120237604","doi":"https://doi.org/10.1002/sia.3043","title":"TFAA chemical derivatization and XPS. Analysis of OH and NHx polymers","display_name":"TFAA chemical derivatization and XPS. Analysis of OH and NHx polymers","publication_year":2009,"publication_date":"2009-02-24","ids":{"openalex":"https://openalex.org/W2120237604","doi":"https://doi.org/10.1002/sia.3043","mag":"2120237604"},"language":"en","primary_location":{"id":"doi:10.1002/sia.3043","doi":"https://doi.org/10.1002/sia.3043","is_oa":false,"landing_page_url":"https://doi.org/10.1002/sia.3043","pdf_url":null,"source":{"id":"https://openalex.org/S114406758","display_name":"Surface and Interface Analysis","issn_l":"0142-2421","issn":["0142-2421","1096-9918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Surface and Interface Analysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057769834","display_name":"Falko Pippig","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210128116","display_name":"Fraunhofer Institute for Applied Polymer Research","ror":"https://ror.org/02yhs7m71","country_code":"DE","type":"facility","lineage":["https://openalex.org/I4210128116","https://openalex.org/I4923324"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Falko Pippig","raw_affiliation_strings":["Fraunhofer-Institut fu\u0308r Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","Fraunhofer-Institut f\u00fcr Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fraunhofer-Institut fu\u0308r Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","institution_ids":["https://openalex.org/I4210128116"]},{"raw_affiliation_string":"Fraunhofer-Institut f\u00fcr Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","institution_ids":["https://openalex.org/I4210128116"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046631108","display_name":"Sanaa Sarghini","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I13469542","display_name":"Vrije Universiteit Brussel","ror":"https://ror.org/006e5kg04","country_code":"BE","type":"education","lineage":["https://openalex.org/I13469542"]},{"id":"https://openalex.org/I68522396","display_name":"Flemish Institute for Technological Research","ror":"https://ror.org/04gq0w522","country_code":"BE","type":"facility","lineage":["https://openalex.org/I68522396"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Sanaa Sarghini","raw_affiliation_strings":["VITO Materials Technology, Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, Belgium","VUB-Vrije Universiteit van Brussel, MACH - Pleinlaan 2, 1050 Brussels, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"VITO Materials Technology, Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, Belgium","institution_ids":["https://openalex.org/I68522396"]},{"raw_affiliation_string":"VUB-Vrije Universiteit van Brussel, MACH - Pleinlaan 2, 1050 Brussels, Belgium","institution_ids":["https://openalex.org/I13469542"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080276314","display_name":"Andreas Holl\u00e4nder","orcid":"https://orcid.org/0000-0001-8981-8906","observed_orcids":["https://orcid.org/0000-0001-8981-8906"]},"institutions":[{"id":"https://openalex.org/I4210128116","display_name":"Fraunhofer Institute for Applied Polymer Research","ror":"https://ror.org/02yhs7m71","country_code":"DE","type":"facility","lineage":["https://openalex.org/I4210128116","https://openalex.org/I4923324"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Andreas Holl\u00e4nder","raw_affiliation_strings":["Fraunhofer-Institut fu\u0308r Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","Fraunhofer-Institut f\u00fcr Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fraunhofer-Institut fu\u0308r Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","institution_ids":["https://openalex.org/I4210128116"]},{"raw_affiliation_string":"Fraunhofer-Institut f\u00fcr Angewandte Polymerforschung, Geiselbergstr. 69, 14476 Potsdam, Germany","institution_ids":["https://openalex.org/I4210128116"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070838726","display_name":"Sabine Paulussen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I68522396","display_name":"Flemish Institute for Technological Research","ror":"https://ror.org/04gq0w522","country_code":"BE","type":"facility","lineage":["https://openalex.org/I68522396"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Sabine Paulussen","raw_affiliation_strings":["VITO Materials Technology, Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"VITO Materials Technology, Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, Belgium","institution_ids":["https://openalex.org/I68522396"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5062702828","display_name":"Herman Albert Terryn","orcid":"https://orcid.org/0000-0003-2639-5496","observed_orcids":["https://orcid.org/0000-0003-2639-5496"]},"institutions":[{"id":"https://openalex.org/I13469542","display_name":"Vrije Universiteit Brussel","ror":"https://ror.org/006e5kg04","country_code":"BE","type":"education","lineage":["https://openalex.org/I13469542"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"Herman Terryn","raw_affiliation_strings":["VUB-Vrije Universiteit van Brussel, MACH - Pleinlaan 2, 1050 Brussels, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"VUB-Vrije Universiteit van Brussel, MACH - Pleinlaan 2, 1050 Brussels, Belgium","institution_ids":["https://openalex.org/I13469542"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5080276314"],"corresponding_institution_ids":["https://openalex.org/I4210128116"],"apc_list":{"value":3580,"currency":"USD","value_usd":3580},"apc_paid":null,"fwci":2.1867,"has_fulltext":false,"cited_by_count":68,"citation_normalized_percentile":{"value":0.84792986,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"41","issue":"5","first_page":"421","last_page":"429"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12039","display_name":"Electron and X-Ray Spectroscopy Techniques","score":0.9883000254631042,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12039","display_name":"Electron and X-Ray Spectroscopy Techniques","score":0.9883000254631042,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":0.006599999964237213,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12166","display_name":"Ion-surface interactions and analysis","score":0.002199999988079071,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/trifluoroacetic-anhydride-derivatization","display_name":"trifluoroacetic anhydride derivatization","score":0.9539999961853027},{"id":"https://openalex.org/keywords/hydroxyl-groups","display_name":"hydroxyl groups","score":0.675000011920929},{"id":"https://openalex.org/keywords/amino-groups","display_name":"amino groups","score":0.9570000171661377},{"id":"https://openalex.org/keywords/polyvinyl-alcohol","display_name":"polyvinyl alcohol","score":0.972000002861023},{"id":"https://openalex.org/keywords/poly-2-hydroxyethyl-methacrylate","display_name":"poly(2-hydroxyethyl methacrylate)","score":0.9789999723434448},{"id":"https://openalex.org/keywords/polyvinyl-butyral","display_name":"polyvinyl butyral","score":0.9990000128746033},{"id":"https://openalex.org/keywords/polyallylamine","display_name":"polyallylamine","score":0.9959999918937683},{"id":"https://openalex.org/keywords/trifluoroacetate","display_name":"trifluoroacetate","score":0.8379999995231628},{"id":"https://openalex.org/keywords/trifluoroacetamide","display_name":"trifluoroacetamide","score":0.9359999895095825}],"concepts":[{"id":"https://openalex.org/C2776923573","wikidata":"https://www.wikidata.org/wiki/Q2294884","display_name":"Derivatization","level":3,"score":0.7222680449485779},{"id":"https://openalex.org/C2781143453","wikidata":"https://www.wikidata.org/wiki/Q411501","display_name":"Trifluoroacetic anhydride","level":2,"score":0.6534076929092407},{"id":"https://openalex.org/C2778439535","wikidata":"https://www.wikidata.org/wiki/Q188777","display_name":"Amide","level":2,"score":0.6284022331237793},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6189560890197754},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6061772704124451},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.5737887024879456},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5369536280632019},{"id":"https://openalex.org/C2779751980","wikidata":"https://www.wikidata.org/wiki/Q143429","display_name":"Polyethylene","level":2,"score":0.4680212438106537},{"id":"https://openalex.org/C132050475","wikidata":"https://www.wikidata.org/wiki/Q736232","display_name":"Methacrylate","level":4,"score":0.4475850462913513},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.43193984031677246},{"id":"https://openalex.org/C2778927588","wikidata":"https://www.wikidata.org/wiki/Q417414","display_name":"Allylamine","level":4,"score":0.41889840364456177},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.34163913130760193},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.09948408603668213},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.09039726853370667},{"id":"https://openalex.org/C153356533","wikidata":"https://www.wikidata.org/wiki/Q901016","display_name":"Polyelectrolyte","level":3,"score":0.088960200548172},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C179998833","wikidata":"https://www.wikidata.org/wiki/Q381233","display_name":"High-performance liquid chromatography","level":2,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1002/sia.3043","doi":"https://doi.org/10.1002/sia.3043","is_oa":false,"landing_page_url":"https://doi.org/10.1002/sia.3043","pdf_url":null,"source":{"id":"https://openalex.org/S114406758","display_name":"Surface and Interface Analysis","issn_l":"0142-2421","issn":["0142-2421","1096-9918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Surface and Interface Analysis","raw_type":"journal-article"},{"id":"pmh:oai:fraunhofer.de:N-94692","doi":null,"is_oa":false,"landing_page_url":"http://publica.fraunhofer.de/documents/N-94692.html","pdf_url":null,"source":{"id":"https://openalex.org/S4306400801","display_name":"Publikationsdatenbank der Fraunhofer-Gesellschaft (Fraunhofer-Gesellschaft)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4923324","host_organization_name":"Fraunhofer-Gesellschaft","host_organization_lineage":["https://openalex.org/I4923324"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Fraunhofer IAP","raw_type":"Journal Article"},{"id":"pmh:oai:publica.fraunhofer.de:publica/218572","doi":null,"is_oa":false,"landing_page_url":"https://publica.fraunhofer.de/handle/publica/218572","pdf_url":null,"source":{"id":"https://openalex.org/S4306400318","display_name":"Fraunhofer-Publica (Fraunhofer-Gesellschaft)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4923324","host_organization_name":"Fraunhofer-Gesellschaft","host_organization_lineage":["https://openalex.org/I4923324"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"journal article"},{"id":"pmh:oai:vubissmart:VUBISSMART:2000:59582","doi":null,"is_oa":false,"landing_page_url":"https://biblio.vub.ac.be/vubir/tfaa-chemical-derivatization-and-xps-analysis-of-oh-and-nhx-polymers(4d7dfb92-a093-4e2d-a875-0dd5b96d2de5).html","pdf_url":null,"source":{"id":"https://openalex.org/S4306402573","display_name":"VUBIR (Vrije Universiteit Brussel)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I13469542","host_organization_name":"Vrije Universiteit Brussel","host_organization_lineage":["https://openalex.org/I13469542"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W183971313","https://openalex.org/W1970558099","https://openalex.org/W1971796440","https://openalex.org/W1977644850","https://openalex.org/W1985281442","https://openalex.org/W1988358520","https://openalex.org/W1991850510","https://openalex.org/W1992107458","https://openalex.org/W1996832852","https://openalex.org/W1998277016","https://openalex.org/W2008154037","https://openalex.org/W2018935165","https://openalex.org/W2024656643","https://openalex.org/W2025095627","https://openalex.org/W2042132131","https://openalex.org/W2043582695","https://openalex.org/W2049353642","https://openalex.org/W2050591528","https://openalex.org/W2052091881","https://openalex.org/W2061808190","https://openalex.org/W2063720102","https://openalex.org/W2065563529","https://openalex.org/W2067283194","https://openalex.org/W2084714969","https://openalex.org/W2092114133","https://openalex.org/W2099514329","https://openalex.org/W2106603672","https://openalex.org/W2135305694","https://openalex.org/W2137184378","https://openalex.org/W2161439370","https://openalex.org/W2169686270","https://openalex.org/W2323906887","https://openalex.org/W2943761892"],"related_works":["https://openalex.org/W2042132131","https://openalex.org/W1996832852","https://openalex.org/W7046087912","https://openalex.org/W2029361083","https://openalex.org/W2323906887","https://openalex.org/W2050591528","https://openalex.org/W2912722395","https://openalex.org/W1964420268","https://openalex.org/W1853403128","https://openalex.org/W2169686270"],"abstract_inverted_index":{"Abstract":[0],"The":[1,123,171,232,249],"determination":[2],"of":[3,86,95,103,133,173,240],"functional":[4],"groups":[5,26,29,135],"on":[6],"complex":[7],"polymer":[8,138,244],"surfaces":[9],"by":[10,19,130],"X\u2010ray":[11],"photoelectron":[12],"spectroscopy":[13],"(XPS)":[14],"can":[15],"be":[16,190],"improved":[17],"considerably":[18],"derivatization":[20,37],"reactions.":[21],"Simple":[22],"polymers":[23],"containing":[24],"hydroxyl":[25],"or":[27,119,228,252],"amino":[28],"were":[30,58,89],"investigated":[31],"as":[32,70,116,120,261],"reference":[33,74],"materials":[34],"for":[35,75,211],"the":[36,76,83,92,101,104,109,131,137,154,166,174,179,198,203,212,216,221,226,236,265],"with":[38,64,162,197,242],"trifluoroacetic":[39],"anhydride":[40],"(TFAA).":[41],"\u20101":[42],"Poly(vinyl":[43],"alcohol)":[44],"(PVA),":[45],"poly(hydroxyethyl":[46],"methacrylate)":[47],"(PHEMA),":[48],"poly(vinyl":[49],"butyral)":[50],"(PVB),":[51],"poly(allylamine)":[52],"(PAAm),":[53],"and":[54,62,185,192,220,259],"poly(diallyl":[55],"amine)":[56],"(PDAAm)":[57],"derivatized":[59],"using":[60],"TFAA":[61,241],"analyzed":[63],"XPS.":[65],"Polyethylene":[66],"(PE)":[67],"was":[68,98,187],"used":[69],"an":[71,117,121],"independent":[72],"external":[73],"binding":[77],"energy":[78],"(BE).":[79],"Applying":[80],"this":[81],"procedure,":[82],"BE":[84,102,126,155,167,172,204],"scales":[85],"all":[87],"measurements":[88],"referenced":[90],"to":[91,189,224],"carbon":[93,147,214,218,222],"atoms":[94],"PE.":[96],"It":[97],"found":[99,188],"that":[100,235],"CF":[105,124,175],"3":[106,125,176],"component":[107,177],"in":[108,136,160,178],"C1s":[110],"region":[111],"is":[112,127,156,168,205,230,246,255],"different":[113],"when":[114],"bonded":[115],"acetate":[118],"amide.":[122],"also":[128,210],"influenced":[129],"density":[132],"these":[134],"molecule.":[139],"In":[140],"TFAA\u2010PVA,":[141],"where":[142],"every":[143],"second":[144],"main":[145],"chain":[146],"atom":[148,223],"carries":[149],"a":[150,243,256,262],"trifluoroacetate":[151],"(TFAc)":[152],"group,":[153],"294.3":[157],"eV":[158],"while":[159],"TFAA\u2010PVB":[161],"only":[163],"isolated":[164],"groups,":[165],"293.6":[169],"eV.":[170],"trifluoroacetamides":[180],"(TFAAms)":[181],"prepared":[182],"from":[183],"PAAm":[184],"PDAAm":[186],"292.5":[191],"292.3":[193],"eV,":[194],"respectively.":[195],"Compared":[196],"analog":[199],"fluorine":[200],"free":[201],"compounds,":[202],"shifted":[206],"toward":[207],"higher":[208],"values":[209],"ester":[213,227,251],"atom,":[215,219],"amide":[217,229,253],"which":[225],"bonded.":[231],"data":[233],"suggest":[234],"gas":[237],"phase":[238],"reaction":[239,258],"surface":[245],"diffusion":[247],"limited.":[248],"actual":[250],"formation":[254],"fast":[257],"runs":[260],"wave":[263],"into":[264],"surface.":[266],"Copyright":[267],"\u00a9":[268],"2009":[269],"John":[270],"Wiley":[271],"&":[272],"Sons,":[273],"Ltd.":[274]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}