{"id":"https://openalex.org/W2114684886","doi":"https://doi.org/10.1002/macp.200290015","title":"Synthesis of High\u2010Molecular Weight Polymers Based on N,N\u2010Diallyl\u2010N\u2010Methylamine","display_name":"Synthesis of High\u2010Molecular Weight Polymers Based on N,N\u2010Diallyl\u2010N\u2010Methylamine","publication_year":2002,"publication_date":"2002-12-01","ids":{"openalex":"https://openalex.org/W2114684886","doi":"https://doi.org/10.1002/macp.200290015","mag":"2114684886"},"language":"en","primary_location":{"id":"doi:10.1002/macp.200290015","doi":"https://doi.org/10.1002/macp.200290015","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.200290015","pdf_url":null,"source":{"id":"https://openalex.org/S124744586","display_name":"Macromolecular Chemistry and Physics","issn_l":"1022-1352","issn":["1022-1352","1521-3935"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecular Chemistry and Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5026226353","display_name":"L. \u041c. Timofeeva","orcid":"https://orcid.org/0000-0002-5437-7933","observed_orcids":["https://orcid.org/0000-0002-5437-7933"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Larisa M. Timofeeva","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056947279","display_name":"Yu. A. Vasilieva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Yuliya A. Vasilieva","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035855137","display_name":"Natalia A. Klescheva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Natalia A. Klescheva","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038171851","display_name":"G. L. Gromova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Galina L. Gromova","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012049344","display_name":"Galina I. Timofeeva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Galina I. Timofeeva","raw_affiliation_strings":["Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 117813, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 117813, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113615327","display_name":"Alexander I. Rebrov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Alexandr I. Rebrov","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5110123148","display_name":"D. A. Topchiev","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210106238","display_name":"A.V. Topchiev Institute of Petrochemical Synthesis","ror":"https://ror.org/01jgbgc06","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210106238","https://openalex.org/I4210145551","https://openalex.org/I4210163714"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Dmitry A. Topchiev","raw_affiliation_strings":["A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, Moscow, GSP-1 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5026226353"],"corresponding_institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210106238"],"apc_list":{"value":4220,"currency":"USD","value_usd":4220},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":19,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"203","issue":"16","first_page":"2296","last_page":"2304"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/high-molecular-weight-polymers","display_name":"high molecular weight polymers","score":0.8759999871253967},{"id":"https://openalex.org/keywords/free-radical-polymerization","display_name":"radical polymerization","score":0.9049999713897705},{"id":"https://openalex.org/keywords/aqueous-solution-polymerization","display_name":"aqueous polymerization","score":0.9369999766349792},{"id":"https://openalex.org/keywords/trifluoroacetic-acid","display_name":"trifluoroacetic acid","score":0.9660000205039978},{"id":"https://openalex.org/keywords/bimolecular-termination","display_name":"bimolecular termination","score":0.8100000023841858},{"id":"https://openalex.org/keywords/degradative-chain-transfer","display_name":"degradative chain transfer","score":0.9179999828338623},{"id":"https://openalex.org/keywords/polymerization-rate-control","display_name":"polymerization rate control","score":0.8410000205039978},{"id":"https://openalex.org/keywords/molecular-weight-control","display_name":"molecular weight control","score":0.9929999709129333}],"concepts":[{"id":"https://openalex.org/C2778969155","wikidata":"https://www.wikidata.org/wiki/Q409304","display_name":"Methylamine","level":2,"score":0.9156241416931152},{"id":"https://openalex.org/C2780112151","wikidata":"https://www.wikidata.org/wiki/Q412033","display_name":"Trifluoroacetic acid","level":2,"score":0.7800999283790588},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7774758338928223},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.7172278165817261},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.7050583362579346},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5929421186447144},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.5494682788848877},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.50711989402771},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.46029648184776306},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.359494149684906},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1717475950717926}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/macp.200290015","doi":"https://doi.org/10.1002/macp.200290015","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.200290015","pdf_url":null,"source":{"id":"https://openalex.org/S124744586","display_name":"Macromolecular Chemistry and Physics","issn_l":"1022-1352","issn":["1022-1352","1521-3935"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecular Chemistry and Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W593265407","https://openalex.org/W1495482938","https://openalex.org/W1903533054","https://openalex.org/W1985045541","https://openalex.org/W2009358391","https://openalex.org/W2012211924","https://openalex.org/W2019436305","https://openalex.org/W2025484979","https://openalex.org/W2033882300","https://openalex.org/W2054373686","https://openalex.org/W2056490692","https://openalex.org/W2063739164","https://openalex.org/W2124879496","https://openalex.org/W2149311764","https://openalex.org/W2317506667","https://openalex.org/W2326298435","https://openalex.org/W2328461087","https://openalex.org/W2914540245","https://openalex.org/W4211159265"],"related_works":["https://openalex.org/W2056490692","https://openalex.org/W2022391656","https://openalex.org/W2068224180","https://openalex.org/W1998299950","https://openalex.org/W2521696854","https://openalex.org/W2027241082","https://openalex.org/W1894773746","https://openalex.org/W4394774655","https://openalex.org/W2063739164","https://openalex.org/W2051475358"],"abstract_inverted_index":{"Abstract":[0],"High\u2010molecular":[1],"weight":[2,78],"polymers,":[3],"namely":[4],"poly(N,N\u2010diallyl\u2010N\u2010methylammonium":[5],"trifluoroacetate)":[6],"and":[7,29,55,76],"poly(N,N\u2010diallyl\u2010N\u2010methylamine),":[8],"were":[9],"prepared":[10],"by":[11,30,51],"radical":[12],"polymerization":[13,31,74],"of":[14,22,26,32,71,79,85],"N,N\u2010diallyl\u2010N\u2010methylamine":[15],"in":[16,19,40],"aqueous":[17],"solution":[18],"the":[20,33,52,73,86],"presence":[21],"an":[23],"equimolar":[24],"amount":[25],"trifluoroacetic":[27],"acid":[28],"newly":[34],"synthesized":[35],"equimolecular":[36],"salt":[37],"N,N\u2010diallyl\u2010N\u2010methylammonium":[38],"trifluoroacetate":[39],"gentle":[41],"conditions.":[42],"We":[43],"have":[44],"established":[45],"that":[46,56],"chain":[47,58,65],"termination":[48],"is":[49,81],"controlled":[50],"bimolecular":[53],"mechanism":[54],"degradative":[57],"transfer":[59,66],"to":[60],"monomer":[61],"transforms":[62],"into":[63],"effective":[64],"(see":[67],"Scheme).":[68],"The":[69,83],"possibility":[70],"controlling":[72],"rate":[75],"molecular":[77],"polymers":[80],"demonstrated.":[82],"mechanisms":[84],"observed":[87],"phenomena":[88],"are":[89],"discussed.":[90],"magnified":[91],"image":[92]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":3},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-06-24T00:00:00"}