{"id":"https://openalex.org/W2113459485","doi":"https://doi.org/10.1039/c2dt11097k","title":"Palladacycles bearing tridentate CNS-type benzamidinate ligands as catalysts for cross-coupling reactions","display_name":"Palladacycles bearing tridentate CNS-type benzamidinate ligands as catalysts for cross-coupling reactions","publication_year":2012,"publication_date":"2012-01-01","ids":{"openalex":"https://openalex.org/W2113459485","doi":"https://doi.org/10.1039/c2dt11097k","mag":"2113459485","pmid":"https://pubmed.ncbi.nlm.nih.gov/22278632"},"language":"en","primary_location":{"id":"doi:10.1039/c2dt11097k","doi":"https://doi.org/10.1039/c2dt11097k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2dt11097k","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5108085027","display_name":"Wei-Chi Wang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I162838928","display_name":"National Chung Hsing University","ror":"https://ror.org/05vn3ca78","country_code":"TW","type":"education","lineage":["https://openalex.org/I162838928"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Wei-Chi Wang","raw_affiliation_strings":["Department of Chemistry, National Chung Hsing University, Taichung, Taiwan, Republic of China","Department of Chemistry, National Chung-Hsing University, Taichung, 402, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Chung Hsing University, Taichung, Taiwan, Republic of China","institution_ids":["https://openalex.org/I162838928"]},{"raw_affiliation_string":"Department of Chemistry, National Chung-Hsing University, Taichung, 402, Taiwan, Republic of China","institution_ids":["https://openalex.org/I162838928"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003204162","display_name":"Kuo\u2010Fu Peng","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I162838928","display_name":"National Chung Hsing University","ror":"https://ror.org/05vn3ca78","country_code":"TW","type":"education","lineage":["https://openalex.org/I162838928"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Kuo-Fu Peng","raw_affiliation_strings":["Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China","institution_ids":["https://openalex.org/I162838928"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047005461","display_name":"Ming\u2010Tsz Chen","orcid":"https://orcid.org/0000-0002-7949-305X","observed_orcids":["https://orcid.org/0000-0002-7949-305X"]},"institutions":[{"id":"https://openalex.org/I162838928","display_name":"National Chung Hsing University","ror":"https://ror.org/05vn3ca78","country_code":"TW","type":"education","lineage":["https://openalex.org/I162838928"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Ming-Tsz Chen","raw_affiliation_strings":["Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China","institution_ids":["https://openalex.org/I162838928"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5028273166","display_name":"Chi\u2010Tien Chen","orcid":"https://orcid.org/0000-0002-2077-5917","observed_orcids":["https://orcid.org/0000-0002-2077-5917"]},"institutions":[{"id":"https://openalex.org/I162838928","display_name":"National Chung Hsing University","ror":"https://ror.org/05vn3ca78","country_code":"TW","type":"education","lineage":["https://openalex.org/I162838928"]}],"countries":["TW"],"is_corresponding":true,"raw_author_name":"Chi-Tien Chen","raw_affiliation_strings":["Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China","institution_ids":["https://openalex.org/I162838928"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5028273166"],"corresponding_institution_ids":["https://openalex.org/I162838928"],"apc_list":null,"apc_paid":null,"fwci":0.4101,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.54011578,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"41","issue":"10","first_page":"3022","last_page":"3022"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.9477999806404114,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.9477999806404114,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.04610000178217888,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/palladacycles","display_name":"palladacycles","score":0.949999988079071},{"id":"https://openalex.org/keywords/palladium-complexes","display_name":"palladium complexes","score":0.8050000071525574},{"id":"https://openalex.org/keywords/suzuki-miyaura-coupling","display_name":"Suzuki coupling","score":0.6380000114440918},{"id":"https://openalex.org/keywords/heck-reaction","display_name":"Heck reaction","score":0.9919999837875366},{"id":"https://openalex.org/keywords/cross-coupling-catalysts","display_name":"cross-coupling catalysts","score":0.9210000038146973},{"id":"https://openalex.org/keywords/dinuclear-palladium-complexes","display_name":"dinuclear palladium complexes","score":0.8600000143051147},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.578000009059906},{"id":"https://openalex.org/keywords/palladium-ii-chloride-complexes","display_name":"palladium(II) chloride complexes","score":0.47200000286102295}],"concepts":[{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.919588565826416},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8385918736457825},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6980115175247192},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.659838080406189},{"id":"https://openalex.org/C2994067411","wikidata":"https://www.wikidata.org/wiki/Q125264","display_name":"Molar ratio","level":3,"score":0.6325116157531738},{"id":"https://openalex.org/C2777077568","wikidata":"https://www.wikidata.org/wiki/Q150440","display_name":"Hexane","level":2,"score":0.5822839140892029},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5707409381866455},{"id":"https://openalex.org/C13205572","wikidata":"https://www.wikidata.org/wiki/Q899891","display_name":"Suzuki reaction","level":4,"score":0.45056408643722534},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.42034536600112915},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.40617403388023376},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.23979809880256653},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21830964088439941}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c2dt11097k","doi":"https://doi.org/10.1039/c2dt11097k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2dt11097k","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:22278632","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22278632","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321040","display_name":"National Science Council","ror":"https://ror.org/02kv4zf79"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W1484918035","https://openalex.org/W1967274063","https://openalex.org/W1970542027","https://openalex.org/W1973247289","https://openalex.org/W1974172008","https://openalex.org/W1978126832","https://openalex.org/W1978289623","https://openalex.org/W1982881636","https://openalex.org/W1983292179","https://openalex.org/W1984509264","https://openalex.org/W1987322083","https://openalex.org/W1990148488","https://openalex.org/W1992238722","https://openalex.org/W1994868799","https://openalex.org/W1997194549","https://openalex.org/W1997756169","https://openalex.org/W1998420946","https://openalex.org/W2002788226","https://openalex.org/W2006467738","https://openalex.org/W2010220109","https://openalex.org/W2014068474","https://openalex.org/W2016747704","https://openalex.org/W2016970210","https://openalex.org/W2025007041","https://openalex.org/W2034939111","https://openalex.org/W2041515392","https://openalex.org/W2041580566","https://openalex.org/W2046479183","https://openalex.org/W2066217002","https://openalex.org/W2076875012","https://openalex.org/W2086535799","https://openalex.org/W2091652545","https://openalex.org/W2093006776","https://openalex.org/W2095132420","https://openalex.org/W2099104340","https://openalex.org/W2102208605","https://openalex.org/W2104377066","https://openalex.org/W2144279056","https://openalex.org/W2149295256","https://openalex.org/W2167593504","https://openalex.org/W2952408971","https://openalex.org/W2952735401"],"related_works":["https://openalex.org/W2099104340","https://openalex.org/W2346655366","https://openalex.org/W2025007041","https://openalex.org/W3165176066","https://openalex.org/W4404860738","https://openalex.org/W2046968506","https://openalex.org/W2079256398","https://openalex.org/W1971104789","https://openalex.org/W2949629514","https://openalex.org/W4281839390"],"abstract_inverted_index":{"Three":[0],"pendant":[1],"benzamidines,":[2],"[Ph-C(=NC(6)H(5))-{NH(E)}]":[3],"[E":[4,33,89],"=":[5,34,90],"-(CH(2))(2)SMe":[6,35,91],"(1);":[7],"-(CH(2))(2)S(t)Bu":[8,37,93],"(2);":[9],"-o-C(6)H(4)SMe":[10,39,95],"(3)],":[11],"are":[12,107],"described.":[13],"Reactions":[14],"of":[15,24,66,75,80,117],"1,":[16,67],"2":[17,68],"or":[18,69],"3":[19,70],"with":[20,71],"one":[21,72],"molar":[22,73],"equivalent":[23,74],"Pd(OAc)(2)":[25],"in":[26,77,82],"CH(2)Cl(2)":[27,83],"give":[28],"the":[29,78,85,122],"palladacyclic":[30,86,119],"complexes,":[31,87],"[Ph-C{-NH(\u03b7(1)-C(6)H(4))}{=N(E)}]Pd(OAc)":[32],"(4);":[36],"(5);":[38],"(6)],":[40],"as":[41,50,55,97],"mononuclear":[42,98],"palladium":[43,58,99],"complexes":[44,100,120],"respectively.":[45,101],"A":[46],"minor":[47],"product":[48],"described":[49],"5',":[51],"{[Ph-C{-N(C(6)H(5))}{-N(CH(2))(2)S(t)Bu}]Pd(OAc)}(2),":[52],"was":[53,128],"isolated":[54],"benzamidinate-bridged":[56],"dinuclear":[57],"complex":[59],"upon":[60],"recrystallizing":[61],"from":[62],"Et(2)O/hexane":[63],"solution.":[64],"Treatment":[65],"PdCl(2)":[76],"presence":[79],"NEt(3)":[81],"gives":[84],"[Ph-C{-NH(\u03b7(1)-C(6)H(4))}{=N(E)}]PdCl":[88],"(7);":[92],"(8);":[94],"(9)],":[96],"The":[102,115],"crystal":[103],"and":[104,113,124],"molecular":[105],"structures":[106],"reported":[108],"for":[109],"compounds":[110],"5,":[111],"5'":[112],"6-8.":[114],"application":[116],"these":[118],"to":[121],"Suzuki":[123],"Heck":[125],"coupling":[126],"reactions":[127],"examined.":[129]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":5},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}