{"id":"https://openalex.org/W2113293154","doi":"https://doi.org/10.1021/jo9022765","title":"A Mild Synthesis of Unsymmetrical Bisalkoxysilanes through Catalyzed Alcoholysis of Hydridosilanes Containing C\u2212C Multiple Bonds and Aryl Halides","display_name":"A Mild Synthesis of Unsymmetrical Bisalkoxysilanes through Catalyzed Alcoholysis of Hydridosilanes Containing C\u2212C Multiple Bonds and Aryl Halides","publication_year":2009,"publication_date":"2009-12-02","ids":{"openalex":"https://openalex.org/W2113293154","doi":"https://doi.org/10.1021/jo9022765","mag":"2113293154","pmid":"https://pubmed.ncbi.nlm.nih.gov/19954142"},"language":"en","primary_location":{"id":"doi:10.1021/jo9022765","doi":"https://doi.org/10.1021/jo9022765","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo9022765","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5045024409","display_name":"Colleen N. Scott","orcid":"https://orcid.org/0000-0003-3332-2439","observed_orcids":["https://orcid.org/0000-0003-3332-2439"]},"institutions":[{"id":"https://openalex.org/I170201317","display_name":"University of Pittsburgh","ror":"https://ror.org/01an3r305","country_code":"US","type":"education","lineage":["https://openalex.org/I170201317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Colleen N. Scott","raw_affiliation_strings":["Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260","Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260","institution_ids":["https://openalex.org/I170201317"]},{"raw_affiliation_string":"Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA","institution_ids":["https://openalex.org/I170201317"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5006492877","display_name":"Craig S. Wilcox","orcid":"https://orcid.org/0000-0001-6049-1225","observed_orcids":["https://orcid.org/0000-0001-6049-1225"]},"institutions":[{"id":"https://openalex.org/I170201317","display_name":"University of Pittsburgh","ror":"https://ror.org/01an3r305","country_code":"US","type":"education","lineage":["https://openalex.org/I170201317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Craig S. Wilcox","raw_affiliation_strings":["Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Combinatorial Chemistry Center, University of Pittsburgh, Pittsburgh, Pennsylvania 15260","institution_ids":["https://openalex.org/I170201317"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I170201317"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.1612,"has_fulltext":false,"cited_by_count":19,"citation_normalized_percentile":{"value":0.51789352,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"75","issue":"1","first_page":"253","last_page":"256"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.9473000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.9473000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.021400000900030136,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12420","display_name":"Silicone and Siloxane Chemistry","score":0.0052999998442828655,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alcoholysis","display_name":"alcoholysis","score":0.9229999780654907},{"id":"https://openalex.org/keywords/aryl-halides","display_name":"aryl halides","score":0.9200000166893005},{"id":"https://openalex.org/keywords/alkyl-bromides","display_name":"alkyl bromides","score":0.8569999933242798},{"id":"https://openalex.org/keywords/aprotic-conditions","display_name":"aprotic conditions","score":0.7110000252723694},{"id":"https://openalex.org/keywords/two-step-synthesis","display_name":"two-step synthesis","score":0.6520000100135803}],"concepts":[{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.8497774600982666},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.7855702638626099},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7279395461082458},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7081191539764404},{"id":"https://openalex.org/C2776300020","wikidata":"https://www.wikidata.org/wiki/Q422423","display_name":"Bromide","level":2,"score":0.6959990859031677},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.6791959404945374},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.6685582399368286},{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.577019453048706},{"id":"https://openalex.org/C528890316","wikidata":"https://www.wikidata.org/wiki/Q731","display_name":"Manganese","level":2,"score":0.5575258135795593},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.42544323205947876},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.41137203574180603},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.38026168942451477},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3380574882030487}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/jo9022765","doi":"https://doi.org/10.1021/jo9022765","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo9022765","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmid:19954142","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19954142","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of organic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6","score":0.4000000059604645}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W1971733406","https://openalex.org/W1986626048","https://openalex.org/W1995731758","https://openalex.org/W2004453684","https://openalex.org/W2009709988","https://openalex.org/W2011995559","https://openalex.org/W2019238574","https://openalex.org/W2021936154","https://openalex.org/W2035225418","https://openalex.org/W2058395321","https://openalex.org/W2062922586","https://openalex.org/W2072473343","https://openalex.org/W2074203459","https://openalex.org/W2082899522","https://openalex.org/W2128044171","https://openalex.org/W2132202606","https://openalex.org/W2139997991","https://openalex.org/W2949532448","https://openalex.org/W2950305711","https://openalex.org/W2952269859"],"related_works":["https://openalex.org/W2952346504","https://openalex.org/W2949088067","https://openalex.org/W1721701343","https://openalex.org/W3186507204","https://openalex.org/W4403882306","https://openalex.org/W2952678194","https://openalex.org/W3029250135","https://openalex.org/W2001433953","https://openalex.org/W4381737439","https://openalex.org/W2919725042"],"abstract_inverted_index":{"The":[0],"synthesis":[1],"of":[2,22,49],"unsymmetrical":[3,62],"bisalkoxysilanes":[4,63],"containing":[5],"unsaturated":[6],"C-C":[7],"bonds":[8],"and":[9,11,36],"alkyl":[10],"aryl":[12],"bromides":[13],"has":[14],"been":[15],"developed.":[16],"This":[17],"method":[18],"is":[19],"a":[20,55],"modification":[21],"our":[23],"previously":[24],"reported":[25],"two-step":[26,60],"procedure":[27],"that":[28,66],"utilizes":[29],"readily":[30],"available":[31],"catalysts":[32],"(rhodium":[33],"acetate":[34],"dimer":[35],"manganese":[37],"pentacarbonyl":[38],"bromide)":[39],"under":[40],"mild":[41],"neutral":[42],"aprotic":[43],"conditions.":[44],"Good":[45],"to":[46,78],"moderate":[47],"yields":[48],"the":[50,76,80],"products":[51],"were":[52],"obtained":[53],"in":[54],"short":[56],"period.":[57],"In":[58],"this":[59],"synthesis,":[61],"with":[64],"groups":[65],"can":[67,71],"be":[68,72],"further":[69],"functionalized":[70],"prepared":[73],"effectively":[74],"without":[75],"need":[77],"isolate":[79],"intermediates.":[81]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":4}],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2016-06-24T00:00:00"}