{"id":"https://openalex.org/W2111361997","doi":"https://doi.org/10.13005/ojc/280154","title":"Synthesis and Characterization of Zirconium (IV) Derivatives of Meso-tetra(p-methylphenyl)porphyrin with Acetylacetonate and Different Phenolates at Axial Positions","display_name":"Synthesis and Characterization of Zirconium (IV) Derivatives of Meso-tetra(p-methylphenyl)porphyrin with Acetylacetonate and Different Phenolates at Axial Positions","publication_year":2012,"publication_date":"2012-03-18","ids":{"openalex":"https://openalex.org/W2111361997","doi":"https://doi.org/10.13005/ojc/280154","mag":"2111361997"},"language":"en","primary_location":{"id":"doi:10.13005/ojc/280154","doi":"https://doi.org/10.13005/ojc/280154","is_oa":false,"landing_page_url":"https://doi.org/10.13005/ojc/280154","pdf_url":null,"source":{"id":"https://openalex.org/S2764376875","display_name":"Oriental Journal Of Chemistry","issn_l":"0970-020X","issn":["0970-020X","2231-5039"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","poland-40"],"host_organization":"https://openalex.org/P4320800656","host_organization_name":"Oriental Scientific Publishing Company","host_organization_lineage":["https://openalex.org/P4320800656"],"host_organization_lineage_names":["Oriental Scientific Publishing Company"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Oriental Journal Of Chemistry","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2111361997"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5016238809","display_name":"Gauri D. Bajju","orcid":"https://orcid.org/0000-0002-6143-8853","observed_orcids":["https://orcid.org/0000-0002-6143-8853"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gauri D. Bajju","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046154940","display_name":"Sunil Kumar Anand","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Sunil Kumar Anand","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017059357","display_name":"Sujata Kundan","orcid":"https://orcid.org/0000-0001-8665-3667","observed_orcids":["https://orcid.org/0000-0001-8665-3667"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Sujata Kundan","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000641254","display_name":"Deepmala Deepmala","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Deepmala Deepmala","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072127132","display_name":"Ashu Ashu","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ashu Ashu","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5023247797","display_name":"Gita Gita","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gita Gita","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.1304,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.38363891,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"28","issue":"1","first_page":"417","last_page":"432"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12441","display_name":"Porphyrin Metabolism and Disorders","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acetylacetonate-ligands","display_name":"acetylacetonate ligands","score":0.8159999847412109},{"id":"https://openalex.org/keywords/axial-ligand-substitution","display_name":"axial ligand substitution","score":0.5899999737739563},{"id":"https://openalex.org/keywords/metalloporphyrin-synthesis","display_name":"metalloporphyrin synthesis","score":0.8479999899864197},{"id":"https://openalex.org/keywords/electronic-absorption-spectra","display_name":"electronic absorption spectra","score":0.7310000061988831},{"id":"https://openalex.org/keywords/1h-nmr-spectra","display_name":"1H NMR spectrum","score":0.7419999837875366},{"id":"https://openalex.org/keywords/mass-spectrometry-fragmentation","display_name":"mass spectral fragmentation","score":0.5580000281333923}],"concepts":[{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.8749933838844299},{"id":"https://openalex.org/C2777873363","wikidata":"https://www.wikidata.org/wiki/Q13533436","display_name":"Tetra","level":2,"score":0.8559838533401489},{"id":"https://openalex.org/C534791751","wikidata":"https://www.wikidata.org/wiki/Q1038","display_name":"Zirconium","level":2,"score":0.850538969039917},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7890950441360474},{"id":"https://openalex.org/C2777327606","wikidata":"https://www.wikidata.org/wiki/Q5367527","display_name":"Elsevier Biobase","level":5,"score":0.7574717998504639},{"id":"https://openalex.org/C2994357257","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Material chemistry","level":5,"score":0.6207318305969238},{"id":"https://openalex.org/C16653646","wikidata":"https://www.wikidata.org/wiki/Q321150","display_name":"Theoretical chemistry","level":5,"score":0.5846283435821533},{"id":"https://openalex.org/C91558341","wikidata":"https://www.wikidata.org/wiki/Q725361","display_name":"Green chemistry","level":4,"score":0.5492425560951233},{"id":"https://openalex.org/C2993208542","wikidata":"https://www.wikidata.org/wiki/Q207652","display_name":"Industrial chemistry","level":2,"score":0.5322679281234741},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.5193268060684204},{"id":"https://openalex.org/C93275456","wikidata":"https://www.wikidata.org/wiki/Q756449","display_name":"Supramolecular chemistry","level":3,"score":0.5031315684318542},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.49985194206237793},{"id":"https://openalex.org/C33905637","wikidata":"https://www.wikidata.org/wiki/Q5513183","display_name":"GEOBASE","level":5,"score":0.459375262260437},{"id":"https://openalex.org/C2778985474","wikidata":"https://www.wikidata.org/wiki/Q16992241","display_name":"FLUIDEX","level":5,"score":0.4486510753631592},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3475334644317627},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3334905207157135},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28937506675720215},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.22176632285118103},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.12226125597953796},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.11723276972770691},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.09843233227729797},{"id":"https://openalex.org/C183696295","wikidata":"https://www.wikidata.org/wiki/Q2487696","display_name":"Biochemical engineering","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.13005/ojc/280154","doi":"https://doi.org/10.13005/ojc/280154","is_oa":false,"landing_page_url":"https://doi.org/10.13005/ojc/280154","pdf_url":null,"source":{"id":"https://openalex.org/S2764376875","display_name":"Oriental Journal Of Chemistry","issn_l":"0970-020X","issn":["0970-020X","2231-5039"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","poland-40"],"host_organization":"https://openalex.org/P4320800656","host_organization_name":"Oriental Scientific Publishing Company","host_organization_lineage":["https://openalex.org/P4320800656"],"host_organization_lineage_names":["Oriental Scientific Publishing Company"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Oriental Journal Of Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2105338309","https://openalex.org/W1967425238","https://openalex.org/W4291118974","https://openalex.org/W1994344272","https://openalex.org/W2112691770","https://openalex.org/W2089407487","https://openalex.org/W2016789115","https://openalex.org/W2016881834","https://openalex.org/W258793846","https://openalex.org/W2035562106"],"abstract_inverted_index":{"In":[0],"continuation":[1],"with":[2,9,54,182],"the":[3,49,99,123],"previous":[4],"research":[5],"work":[6],"carried":[7],"out":[8],"axially":[10],"ligated":[11],"Zirconium(IV)pmethoxy-meso-tetraphenylporphyrin[Zr(p-OCH":[12],"3":[13,42,169],"TPP)(Y)(X)":[14],"[Y":[15],"=":[16,20],"acac":[17],"and":[18,45,57,64,74,90,121,152,186],"X":[19],"different":[21,34,58],"phenolates]":[22,47],"here":[23],"we":[24],"have":[25],"undertaken":[26],"to":[27,166],"synthesize":[28],"meso-tetra(p-methylphenyl)":[29],"porphinatozirconium":[30],"(IV)":[31],"acetylacetonatophenolates":[32],"containing":[33],"phenols":[35,59],"as":[36,164],"axial":[37],"ligands":[38],"i.":[39],"e.":[40],"[Zr(p-CH":[41],"TPP)(Y)(X)]":[43],"[Y=acac":[44],"X=different":[46],"by":[48,79,104,107,196],"reaction":[50],"of":[51,66,95,109,125,136,188],"meso-tetra(p-methylphenyl)porphyrin":[52,167],"(pCH3H2TPP)":[53],"Zirconium(IV)acetylacetonate":[55],"(Zr(acac)4)":[56],"at":[60,112,118,132],"200-220\u00b0C.":[61],"The":[62,93,156,173],"separation":[63],"isolation":[65],"these":[67,137,192],"compounds":[68,138,193],"were":[69,77,194],"achieved":[70],"through":[71],"chromatographic":[72],"methods":[73],"their":[75],"characterization":[76],"done":[78],"Electronic":[80],"absorption":[81,134],"spectra,":[82,84],"IR":[83,105],"1":[85,157],"H":[86,158,170],"NMR,":[87],"elemental":[88,197],"analysis":[89],"mass":[91],"spectroscopy.":[92],"incorporation":[94,124],"metal":[96],"ion":[97],"in":[98,127,191],"porphyrin":[100],"ring":[101],"was":[102],"confirmed":[103,195],"spectra":[106,135,160,175],"appearance":[108],"Zr-N":[110],"band":[111,117,130,142],"457-502cm":[113],"-1":[114,120],",":[115],"Zr-O":[116,129],"649680cm":[119],"also":[122],"(acac)(C5H7O2)":[126],"which":[128,179],"appeared":[131],"702818cm-1.The":[133],"showed":[139,161],"one":[140,153],"soret":[141],"i.e.,":[143,149],"B(0,0),":[144],"two":[145],"normal":[146],"Q":[147],"bands":[148],"Q(0,0),":[150],"Q(1,0)":[151],"shoulder":[154],"Q(2,0).":[155],"NMR":[159],"upfield":[162],"(shielded)":[163],"compared":[165],"(p-CH":[168],"2":[171],"TPP).":[172],"Mass":[174],"determined":[176],"m/z":[177,184],"ratio\u2019s":[178],"agreed":[180],"well":[181],"calculated":[183],"values":[185],"percentage":[187],"various":[189],"elements":[190],"analysis.":[198]},"counts_by_year":[{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2016-06-24T00:00:00"}