{"id":"https://openalex.org/W2109790243","doi":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","title":"Mechanism of oxidation of diazepam by Chloramine-B: A kinetic approach","display_name":"Mechanism of oxidation of diazepam by Chloramine-B: A kinetic approach","publication_year":1998,"publication_date":"1998-01-01","ids":{"openalex":"https://openalex.org/W2109790243","doi":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","mag":"2109790243"},"language":"en","primary_location":{"id":"doi:10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","doi":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S207430280","display_name":"International Journal of Chemical Kinetics","issn_l":"0538-8066","issn":["0538-8066","1097-4601"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-3","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Chemical Kinetics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111597244","display_name":"N. Nanda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I53465836","display_name":"Bangalore University","ror":"https://ror.org/050j2vm64","country_code":"IN","type":"education","lineage":["https://openalex.org/I53465836"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"N. Nanda","raw_affiliation_strings":["Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, Bangalore-560 001, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, Bangalore-560 001, India","institution_ids":["https://openalex.org/I53465836"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111690781","display_name":"S.M. Mayanna","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I53465836","display_name":"Bangalore University","ror":"https://ror.org/050j2vm64","country_code":"IN","type":"education","lineage":["https://openalex.org/I53465836"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"S. M. Mayanna","raw_affiliation_strings":["Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, Bangalore-560 001, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, Bangalore-560 001, India","institution_ids":["https://openalex.org/I53465836"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113589166","display_name":"N. M. Made Gowda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I117942362","display_name":"Western Illinois University","ror":"https://ror.org/02sshz518","country_code":"US","type":"education","lineage":["https://openalex.org/I117942362"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"N. M. Made Gowda","raw_affiliation_strings":["Department of Chemistry, Western Illinois University, 1 University Circle, Macomb, Illinois 61455"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Western Illinois University, 1 University Circle, Macomb, Illinois 61455","institution_ids":["https://openalex.org/I117942362"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5111690781"],"corresponding_institution_ids":["https://openalex.org/I53465836"],"apc_list":{"value":3700,"currency":"USD","value_usd":3700},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"30","issue":"9","first_page":"605","last_page":"611"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.6851000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.6851000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.20569999516010284,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.04470000043511391,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diazepam","display_name":"diazepam","score":0.9750000238418579},{"id":"https://openalex.org/keywords/chloramine-b","display_name":"chloramine-B","score":0.9440000057220459},{"id":"https://openalex.org/keywords/oxidation-kinetics","display_name":"oxidation kinetics","score":0.7760000228881836},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9430000185966492},{"id":"https://openalex.org/keywords/activation-parameters","display_name":"activation parameters","score":0.7160000205039978},{"id":"https://openalex.org/keywords/solvent-isotope-effect","display_name":"solvent isotope effect","score":0.8820000290870667},{"id":"https://openalex.org/keywords/dielectric-constant-effect","display_name":"dielectric constant effect","score":0.7540000081062317},{"id":"https://openalex.org/keywords/ionic-strength","display_name":"ionic strength","score":0.7059999704360962},{"id":"https://openalex.org/keywords/benzenesulfonamide","display_name":"benzenesulfonamide","score":0.9089999794960022},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.7080000042915344},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.5270000100135803}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9667391777038574},{"id":"https://openalex.org/C2777436746","wikidata":"https://www.wikidata.org/wiki/Q2409","display_name":"Hydrochloric acid","level":2,"score":0.6162495613098145},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.6161203384399414},{"id":"https://openalex.org/C69928629","wikidata":"https://www.wikidata.org/wiki/Q1386472","display_name":"Kinetic isotope effect","level":3,"score":0.5966089963912964},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.5931124687194824},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.5559379458427429},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.5143634080886841},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.5074777007102966},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.49949216842651367},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.4760743975639343},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4715471565723419},{"id":"https://openalex.org/C2781060987","wikidata":"https://www.wikidata.org/wiki/Q420695","display_name":"Chloramine-T","level":2,"score":0.4219357967376709},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4167342782020569},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.32314354181289673},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.25703907012939453},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.25591039657592773},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.12970542907714844},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","doi":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S207430280","display_name":"International Journal of Chemical Kinetics","issn_l":"0538-8066","issn":["0538-8066","1097-4601"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-3","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Chemical Kinetics","raw_type":"journal-article"},{"id":"doi:10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.3.co;2-3","doi":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.3.co;2-3","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1097-4601(1998)30:9<605::aid-kin1>3.3.co;2-3","pdf_url":null,"source":{"id":"https://openalex.org/S207430280","display_name":"International Journal of Chemical Kinetics","issn_l":"0538-8066","issn":["0538-8066","1097-4601"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-3","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Chemical Kinetics","raw_type":"journal-article"},{"id":"pmh:oai:eprints-bangaloreuniversity.in:636","doi":null,"is_oa":false,"landing_page_url":"http://eprints-bangaloreuniversity.in/636/1/mayanna.pdf","pdf_url":"http://eprints-bangaloreuniversity.in/636/1/mayanna.pdf","source":{"id":"https://openalex.org/S4306401173","display_name":"ePrints@Bangalore University (Bangalore University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I53465836","host_organization_name":"Bangalore University","host_organization_lineage":["https://openalex.org/I53465836"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W2035044635","https://openalex.org/W2035479387","https://openalex.org/W2042954532","https://openalex.org/W2052997607","https://openalex.org/W2090969006","https://openalex.org/W2276249230","https://openalex.org/W2790660750","https://openalex.org/W2940996575"],"related_works":["https://openalex.org/W2020974541","https://openalex.org/W2502689726","https://openalex.org/W1983240558","https://openalex.org/W2490634692","https://openalex.org/W4390583293","https://openalex.org/W9614348","https://openalex.org/W2465265063","https://openalex.org/W3047831831","https://openalex.org/W2035479387","https://openalex.org/W2075252124"],"abstract_inverted_index":{"The":[0,19,26,45,72],"kinetics":[1],"of":[2,5,28,48],"the":[3,23,29,40,49,56,61,69,82],"oxidation":[4,20],"diazepam":[6],"(DZ)":[7],"by":[8],"Chloramine-B":[9],"(CAB)":[10],"has":[11,51],"been":[12],"studied":[13,35],"in":[14],"aqueous":[15],"hydrochloric":[16],"acid":[17],"medium.":[18],"reaction":[21,30,62,70],"follows":[22],"rate":[24,31],"law:":[25],"dependence":[27],"on":[32,55,68],"temperature":[33],"is":[34,76,86],"and":[36,60],"activation":[37],"parameters":[38],"for":[39,81],"rate-determining":[41],"step":[42],"are":[43],"evaluated.":[44],"dielectric":[46],"constant":[47],"medium":[50],"a":[52],"small":[53],"effect":[54,67,75],"rate.":[57,71],"Ionic":[58],"strength":[59],"product":[63],"benzenesulfonamide":[64],"have":[65],"no":[66],"solvent":[73],"isotope":[74],"studied.":[77],"A":[78],"probable":[79],"mechanism":[80],"observed":[83],"kinetic":[84],"data":[85],"proposed.":[87],"\u00a9":[88],"1998":[89,101],"John":[90],"Wiley":[91],"&":[92],"Sons,":[93],"Inc.":[94],"Int":[95],"J":[96],"Chem":[97],"Kinet:":[98],"30:":[99],"605\u2013611,":[100]},"counts_by_year":[{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}