{"id":"https://openalex.org/W2107624974","doi":"https://doi.org/10.1039/p29930001901","title":"Conformation of 6-morpholino-3-azabicyclo[3.1.0]hexane derivatives","display_name":"Conformation of 6-morpholino-3-azabicyclo[3.1.0]hexane derivatives","publication_year":1993,"publication_date":"1993-01-01","ids":{"openalex":"https://openalex.org/W2107624974","doi":"https://doi.org/10.1039/p29930001901","mag":"2107624974"},"language":"en","primary_location":{"id":"doi:10.1039/p29930001901","doi":"https://doi.org/10.1039/p29930001901","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29930001901","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5059850565","display_name":"Claus Tetzlaff","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Claus Tetzlaff","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052675006","display_name":"Volker Butz","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Volker Butz","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113662457","display_name":"Elmar Vilsmaier","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Elmar Vilsmaier","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022278745","display_name":"Rolf Wagemann","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Rolf Wagemann","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071407584","display_name":"Gerhard Maas","orcid":"https://orcid.org/0000-0002-9289-4210","observed_orcids":["https://orcid.org/0000-0002-9289-4210"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gerhard Maas","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019235672","display_name":"Andreas Ritter von Onciul","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Andreas Ritter von Onciul","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5017203543","display_name":"Timothy Clark","orcid":"https://orcid.org/0000-0001-7931-4659","observed_orcids":["https://orcid.org/0000-0001-7931-4659"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Timothy Clark","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.5715,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.79987711,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":null,"issue":"10","first_page":"1901","last_page":"1901"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12410","display_name":"Structural and Chemical Analysis of Organic and Inorganic Compounds","score":0.9106000065803528,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12410","display_name":"Structural and Chemical Analysis of Organic and Inorganic Compounds","score":0.9106000065803528,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.048900000751018524,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.015699999406933784,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chair-conformation","display_name":"chair conformation","score":0.8600000143051147},{"id":"https://openalex.org/keywords/boat-conformation","display_name":"boat conformation","score":0.9990000128746033},{"id":"https://openalex.org/keywords/ring-puckering","display_name":"ring puckering","score":0.640999972820282},{"id":"https://openalex.org/keywords/dihedral-angle","display_name":"dihedral angle","score":0.9010000228881836},{"id":"https://openalex.org/keywords/diastereomers","display_name":"diastereomers","score":0.8880000114440918},{"id":"https://openalex.org/keywords/conformational-analysis","display_name":"conformational analysis","score":0.7379999756813049}],"concepts":[{"id":"https://openalex.org/C89025888","wikidata":"https://www.wikidata.org/wiki/Q911907","display_name":"Dihedral angle","level":4,"score":0.8235403895378113},{"id":"https://openalex.org/C2777077568","wikidata":"https://www.wikidata.org/wiki/Q150440","display_name":"Hexane","level":2,"score":0.7938156127929688},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7757751941680908},{"id":"https://openalex.org/C136571751","wikidata":"https://www.wikidata.org/wiki/Q424607","display_name":"Morpholino","level":4,"score":0.7528966665267944},{"id":"https://openalex.org/C24961977","wikidata":"https://www.wikidata.org/wiki/Q225972","display_name":"Bicyclic molecule","level":2,"score":0.6830217242240906},{"id":"https://openalex.org/C138716334","wikidata":"https://www.wikidata.org/wiki/Q268477","display_name":"Diastereomer","level":2,"score":0.6566539406776428},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.6319758892059326},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5257202982902527},{"id":"https://openalex.org/C6652555","wikidata":"https://www.wikidata.org/wiki/Q3285479","display_name":"Cyclohexane conformation","level":4,"score":0.5115697979927063},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18578138947486877},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.18085497617721558},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.17330512404441833},{"id":"https://openalex.org/C2776878037","wikidata":"https://www.wikidata.org/wiki/Q169444","display_name":"Zebrafish","level":3,"score":0.0},{"id":"https://openalex.org/C104317684","wikidata":"https://www.wikidata.org/wiki/Q7187","display_name":"Gene","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/p29930001901","doi":"https://doi.org/10.1039/p29930001901","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29930001901","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/14","display_name":"Life below water","score":0.6000000238418579}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1969064467","https://openalex.org/W1974360526","https://openalex.org/W1983699801","https://openalex.org/W2009564785","https://openalex.org/W2033990154","https://openalex.org/W2035514752","https://openalex.org/W2051619103","https://openalex.org/W2085469819","https://openalex.org/W2343343333","https://openalex.org/W2949340188"],"related_works":["https://openalex.org/W2111846691","https://openalex.org/W2068091317","https://openalex.org/W2952994875","https://openalex.org/W2030959183","https://openalex.org/W1993655219","https://openalex.org/W2015919608","https://openalex.org/W2057766301","https://openalex.org/W1983839742","https://openalex.org/W2102922693","https://openalex.org/W2062060733"],"abstract_inverted_index":{"1":[0],"H":[1],"NMR":[2],"spectroscopic":[3],"studies":[4],"established":[5],"the":[6,33,76],"presence":[7],"of":[8,27,53],"a":[9,42],"chair":[10],"conformation":[11],"for":[12,75],"endo-3-methyl-6-morpholino-3-azabicyclo[3.1.0]hexane":[13],"derivatives":[14],"8a":[15],"and":[16,32,50,81],"b.":[17],"This":[18],"was":[19,56,69],"additionally":[20],"confirmed":[21],"by":[22,58,71],"an":[23],"X-ray":[24],"structural":[25,63],"analysis":[26],"8b.":[28],"The":[29,45],"diastereomers":[30],"10a,b":[31],"N-demethyl-endo-morpholino":[34],"compounds":[35,79],"9a,b,":[36],"however,":[37],"were":[38],"found":[39],"to":[40],"prefer":[41],"boat":[43],"conformation.":[44],"correlation":[46],"between":[47],"dihedral":[48],"angles":[49],"ring":[51],"buckle":[52],"3-azabicyclo[3.1.0]hexane":[54,77],"4":[55,80],"determined":[57],"MNDOC":[59],"semiempirical":[60],"calculations.":[61],"Further":[62],"information":[64],"about":[65],"this":[66],"bicyclic":[67],"system":[68],"obtained":[70],"HF/6\u201331":[72],"G*":[73],"calculations":[74],"parent":[78],"5.":[82]},"counts_by_year":[{"year":2015,"cited_by_count":1}],"updated_date":"2026-07-30T17:31:21.811387","created_date":"2016-06-24T00:00:00"}