{"id":"https://openalex.org/W2107400955","doi":"https://doi.org/10.1039/b904489b","title":"Conformational behaviour and first crystal structures of a calix[4]arene featuring a laterally positioned carboxylic acid function in unsolvated and solvent-complexed forms","display_name":"Conformational behaviour and first crystal structures of a calix[4]arene featuring a laterally positioned carboxylic acid function in unsolvated and solvent-complexed forms","publication_year":2010,"publication_date":"2010-01-01","ids":{"openalex":"https://openalex.org/W2107400955","doi":"https://doi.org/10.1039/b904489b","mag":"2107400955"},"language":"en","primary_location":{"id":"doi:10.1039/b904489b","doi":"https://doi.org/10.1039/b904489b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b904489b","pdf_url":null,"source":{"id":"https://openalex.org/S36793815","display_name":"New Journal of Chemistry","issn_l":"0398-9836","issn":["0398-9836","1144-0546","1369-9261"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"New Journal of Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://figshare.com/articles/journal_contribution/Conformational_behaviour_and_first_crystal_structures_of_a_calix_4_arene_featuring_a_laterally_positioned_carboxylic_acid_function_in_unsolvated_and_solvent-complexed_forms/24345199","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5103257395","display_name":"Tobias Gruber","orcid":"https://orcid.org/0000-0001-5056-8778","observed_orcids":["https://orcid.org/0000-0001-5056-8778"]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Tobias Gruber","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany","institution_ids":["https://openalex.org/I61893789"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110254593","display_name":"\u041c\u0430\u0440\u0433\u0438\u0442 \u0413\u0440\u04af\u043d\u0435\u0440","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I78650965","display_name":"Technische Universit\u00e4t Dresden","ror":"https://ror.org/042aqky30","country_code":"DE","type":"education","lineage":["https://openalex.org/I78650965"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Margit Gruner","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Dresden, Mommsenstr. 13, D-01062 Dresden, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Dresden, Mommsenstr. 13, D-01062 Dresden, Germany","institution_ids":["https://openalex.org/I78650965"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5084527401","display_name":"Conrad Fischer","orcid":"https://orcid.org/0000-0002-2289-010X","observed_orcids":["https://orcid.org/0000-0002-2289-010X"]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Conrad Fischer","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany","institution_ids":["https://openalex.org/I61893789"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113617892","display_name":"Wilhelm Seichter","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Wilhelm Seichter","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany","institution_ids":["https://openalex.org/I61893789"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072000259","display_name":"Petra Bombicz","orcid":"https://orcid.org/0000-0002-5509-1515","observed_orcids":["https://orcid.org/0000-0002-5509-1515"]},"institutions":[{"id":"https://openalex.org/I7597260","display_name":"Hungarian Academy of Sciences","ror":"https://ror.org/02ks8qq67","country_code":"HU","type":"government","lineage":["https://openalex.org/I7597260"]},{"id":"https://openalex.org/I80251312","display_name":"HUN-REN Research Centre for Natural Sciences","ror":"https://ror.org/03zwxja46","country_code":"HU","type":"facility","lineage":["https://openalex.org/I4387152226","https://openalex.org/I80251312"]}],"countries":["HU"],"is_corresponding":false,"raw_author_name":"Petra Bombicz","raw_affiliation_strings":["Institute of Structural Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P. O. Box 17, H-1525 Budapest, Hungary"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Structural Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P. O. Box 17, H-1525 Budapest, Hungary","institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5002580128","display_name":"Edwin Weber","orcid":"https://orcid.org/0000-0002-5896-1205","observed_orcids":["https://orcid.org/0000-0002-5896-1205"]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Edwin Weber","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachs., Germany","institution_ids":["https://openalex.org/I61893789"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5002580128"],"corresponding_institution_ids":["https://openalex.org/I61893789"],"apc_list":null,"apc_paid":null,"fwci":3.0083,"has_fulltext":false,"cited_by_count":33,"citation_normalized_percentile":{"value":0.90975491,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"34","issue":"2","first_page":"250","last_page":"250"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/calix-4-arene","display_name":"calix[4]arene","score":0.9909999966621399},{"id":"https://openalex.org/keywords/carboxylic-acid-substituents","display_name":"carboxylic acid substituents","score":0.8740000128746033},{"id":"https://openalex.org/keywords/conformational-analysis","display_name":"conformational analysis","score":0.9419999718666077},{"id":"https://openalex.org/keywords/solvent-complexes","display_name":"solvent complexes","score":0.39899998903274536},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.7590000033378601},{"id":"https://openalex.org/keywords/aggregation-behavior","display_name":"aggregation behavior","score":0.7049999833106995},{"id":"https://openalex.org/keywords/conformational-chirality","display_name":"conformational chirality","score":0.9079999923706055},{"id":"https://openalex.org/keywords/2d-nmr","display_name":"2D NMR","score":0.6179999709129333},{"id":"https://openalex.org/keywords/temperature-dependent-conformation","display_name":"temperature-dependent conformation","score":0.5320000052452087}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9575092792510986},{"id":"https://openalex.org/C18705241","wikidata":"https://www.wikidata.org/wiki/Q1128023","display_name":"Conformational isomerism","level":3,"score":0.814504086971283},{"id":"https://openalex.org/C83263248","wikidata":"https://www.wikidata.org/wiki/Q423503","display_name":"Calixarene","level":3,"score":0.8024582266807556},{"id":"https://openalex.org/C2779074116","wikidata":"https://www.wikidata.org/wiki/Q134856","display_name":"Carboxylic acid","level":2,"score":0.7046381235122681},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5871582627296448},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.5852689743041992},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.5616976022720337},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5170262455940247},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.49189186096191406},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.48154953122138977},{"id":"https://openalex.org/C14036430","wikidata":"https://www.wikidata.org/wiki/Q3736076","display_name":"Function (biology)","level":2,"score":0.42526185512542725},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.2030389904975891},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1569817066192627},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0},{"id":"https://openalex.org/C52703039","wikidata":"https://www.wikidata.org/wiki/Q5101837","display_name":"Chiral symmetry breaking","level":3,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C78458016","wikidata":"https://www.wikidata.org/wiki/Q840400","display_name":"Evolutionary biology","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/b904489b","doi":"https://doi.org/10.1039/b904489b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b904489b","pdf_url":null,"source":{"id":"https://openalex.org/S36793815","display_name":"New Journal of Chemistry","issn_l":"0398-9836","issn":["0398-9836","1144-0546","1369-9261"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"New Journal of Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:eprints.lincoln.ac.uk:20031","doi":null,"is_oa":false,"landing_page_url":"http://eprints.lincoln.ac.uk/id/eprint/20031/1/__network.uni_staff_S2_jpartridge_b904489b.pdf","pdf_url":"http://eprints.lincoln.ac.uk/id/eprint/20031/1/__network.uni_staff_S2_jpartridge_b904489b.pdf","source":{"id":"https://openalex.org/S4377196275","display_name":"Lincoln Repository (University of Lincoln)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I51532219","host_organization_name":"University of Lincoln","host_organization_lineage":["https://openalex.org/I51532219"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Article"},{"id":"pmh:oai:figshare.com:article/24345199","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/journal_contribution/Conformational_behaviour_and_first_crystal_structures_of_a_calix_4_arene_featuring_a_laterally_positioned_carboxylic_acid_function_in_unsolvated_and_solvent-complexed_forms/24345199","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:figshare.com:article/24345199","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/journal_contribution/Conformational_behaviour_and_first_crystal_structures_of_a_calix_4_arene_featuring_a_laterally_positioned_carboxylic_acid_function_in_unsolvated_and_solvent-complexed_forms/24345199","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W1522217976","https://openalex.org/W1552652435","https://openalex.org/W1955189356","https://openalex.org/W1985977001","https://openalex.org/W1988911237","https://openalex.org/W1997523070","https://openalex.org/W2003857323","https://openalex.org/W2005088858","https://openalex.org/W2015769457","https://openalex.org/W2025853979","https://openalex.org/W2054793108","https://openalex.org/W2057784663","https://openalex.org/W2058922866","https://openalex.org/W2059744036","https://openalex.org/W2070073430","https://openalex.org/W2071788262","https://openalex.org/W2080238829","https://openalex.org/W2081243782","https://openalex.org/W2082338937","https://openalex.org/W2087203349","https://openalex.org/W2095878434","https://openalex.org/W2096566872","https://openalex.org/W2113701650","https://openalex.org/W2118884911","https://openalex.org/W2132840088","https://openalex.org/W2142340513","https://openalex.org/W2153702704","https://openalex.org/W2166689829","https://openalex.org/W2288063349","https://openalex.org/W2950777792","https://openalex.org/W2951562957","https://openalex.org/W2952603392","https://openalex.org/W4210991126","https://openalex.org/W4254954388"],"related_works":["https://openalex.org/W2952538555","https://openalex.org/W2118884911","https://openalex.org/W4213083272","https://openalex.org/W2050488684","https://openalex.org/W7153735281","https://openalex.org/W2330253741","https://openalex.org/W2495334195","https://openalex.org/W153161059","https://openalex.org/W1971115293","https://openalex.org/W1984132737"],"abstract_inverted_index":{"A":[0],"detailed":[1,84],"conformational":[2,93],"analysis":[3],"of":[4,9,53,56,86,96],"a":[5,11,18],"rarely":[6],"investigated":[7,88],"type":[8,59],"compound,":[10],"laterally":[12],"monosubstituted":[13],"calix[4]arene":[14,66],"(1,":[15],"which":[16],"has":[17],"carboxylic":[19,65],"acid":[20],"function":[21],"in":[22,36],"the":[23,47,63,87,97],"lateral":[24],"position),":[25],"is":[26,100],"reported.":[27],"2D":[28],"solution":[29],"NMR":[30],"techniques":[31],"at":[32],"various":[33],"temperatures":[34],"and":[35,67,74,90],"different":[37,48],"solvents":[38],"have":[39,79],"been":[40,80],"used,":[41],"showing":[42],"interesting":[43],"aggregation":[44],"behaviour":[45],"for":[46],"conformers.":[49],"The":[50],"first":[51],"illustrations":[52],"crystal":[54],"structures":[55],"this":[57],"compound":[58],"are":[60],"given,":[61],"including":[62],"unsolvated":[64],"two":[68],"mixed":[69],"solvent":[70],"complexes":[71],"containing":[72],"EtOH\u2013H2O":[73],"EtOH\u2013THF,":[75],"respectively.":[76],"Isostructurality":[77],"calculations":[78],"carried":[81],"out,":[82],"allowing":[83],"comparison":[85],"structures,":[89],"an":[91],"unusual":[92],"chirality":[94],"isomerism":[95],"calixarene":[98],"molecule":[99],"demonstrated.":[101]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":7},{"year":2012,"cited_by_count":3}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}