{"id":"https://openalex.org/W2106663880","doi":"https://doi.org/10.1039/b813368a","title":"Synthesis and photophysical property of well-defined donor\u2013acceptor diblock copolymer based on regioregular poly(3-hexylthiophene) and fullerene","display_name":"Synthesis and photophysical property of well-defined donor\u2013acceptor diblock copolymer based on regioregular poly(3-hexylthiophene) and fullerene","publication_year":2009,"publication_date":"2009-01-01","ids":{"openalex":"https://openalex.org/W2106663880","doi":"https://doi.org/10.1039/b813368a","mag":"2106663880"},"language":"en","primary_location":{"id":"doi:10.1039/b813368a","doi":"https://doi.org/10.1039/b813368a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b813368a","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://scholarworks.umass.edu/pse_faculty_pubs/879","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5042376010","display_name":"Jea Uk Lee","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I139264467","display_name":"Seoul National University","ror":"https://ror.org/04h9pn542","country_code":"KR","type":"education","lineage":["https://openalex.org/I139264467"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jea Uk Lee","raw_affiliation_strings":["Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Korea","Department of Materials Science & Engineering Seoul National University Seoul 151\u2010742 Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Korea","institution_ids":["https://openalex.org/I139264467"]},{"raw_affiliation_string":"Department of Materials Science & Engineering Seoul National University Seoul 151\u2010742 Korea","institution_ids":["https://openalex.org/I139264467"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065417392","display_name":"Ali \u00c7\u0131rpan","orcid":"https://orcid.org/0000-0003-3051-8380","observed_orcids":["https://orcid.org/0000-0003-3051-8380"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ali Cirpan","raw_affiliation_strings":["Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030195131","display_name":"Todd S. Emrick","orcid":"https://orcid.org/0000-0003-0460-1797","observed_orcids":["https://orcid.org/0000-0003-0460-1797"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Todd Emrick","raw_affiliation_strings":["Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029685348","display_name":"Thomas P. Russell","orcid":"https://orcid.org/0000-0001-6384-5826","observed_orcids":["https://orcid.org/0000-0001-6384-5826","https://orcid.org/0000-0001-5702-7851"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas P. Russell","raw_affiliation_strings":["Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111848902","display_name":"Won Ho Jo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I139264467","display_name":"Seoul National University","ror":"https://ror.org/04h9pn542","country_code":"KR","type":"education","lineage":["https://openalex.org/I139264467"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Won Ho Jo","raw_affiliation_strings":["Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Korea","Department of Materials Science & Engineering Seoul National University Seoul 151\u2010742 Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Korea","institution_ids":["https://openalex.org/I139264467"]},{"raw_affiliation_string":"Department of Materials Science & Engineering Seoul National University Seoul 151\u2010742 Korea","institution_ids":["https://openalex.org/I139264467"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5111848902"],"corresponding_institution_ids":["https://openalex.org/I139264467"],"apc_list":null,"apc_paid":null,"fwci":14.0154,"has_fulltext":false,"cited_by_count":130,"citation_normalized_percentile":{"value":0.9915992,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":100},"biblio":{"volume":"19","issue":"10","first_page":"1483","last_page":"1483"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.9653000235557556,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.9653000235557556,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.011699999682605267,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.004399999976158142,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/regioregular-poly-3-hexylthiophene","display_name":"regioregular poly(3-hexylthiophene)","score":0.9610000252723694},{"id":"https://openalex.org/keywords/c60","display_name":"C60","score":0.8769999742507935},{"id":"https://openalex.org/keywords/grignard-metathesis-polymerization","display_name":"Grignard metathesis polymerization","score":0.9309999942779541},{"id":"https://openalex.org/keywords/atom-transfer-radical-polymerization","display_name":"atom transfer radical polymerization","score":0.9279999732971191},{"id":"https://openalex.org/keywords/macroinitiator","display_name":"macroinitiator","score":0.925000011920929},{"id":"https://openalex.org/keywords/methyl-methacrylate","display_name":"methyl methacrylate","score":0.7269999980926514},{"id":"https://openalex.org/keywords/2-hydroxyethyl-methacrylate","display_name":"2-hydroxyethyl methacrylate","score":0.9990000128746033},{"id":"https://openalex.org/keywords/phase-separation","display_name":"phase separation","score":0.6140000224113464},{"id":"https://openalex.org/keywords/photoluminescence-quenching","display_name":"photoluminescence quenching","score":0.8679999709129333},{"id":"https://openalex.org/keywords/charge-transfer","display_name":"charge transfer","score":0.8840000033378601},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.5419999957084656},{"id":"https://openalex.org/keywords/organic-solar-cells","display_name":"organic solar cells","score":0.46700000762939453}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.8634226322174072},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.804261326789856},{"id":"https://openalex.org/C162862793","wikidata":"https://www.wikidata.org/wiki/Q178026","display_name":"Fullerene","level":2,"score":0.6342946887016296},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6298408508300781},{"id":"https://openalex.org/C132050475","wikidata":"https://www.wikidata.org/wiki/Q736232","display_name":"Methacrylate","level":4,"score":0.5268881320953369},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.4904157817363739},{"id":"https://openalex.org/C2779892579","wikidata":"https://www.wikidata.org/wiki/Q912138","display_name":"Acceptor","level":2,"score":0.4873717427253723},{"id":"https://openalex.org/C85080765","wikidata":"https://www.wikidata.org/wiki/Q614893","display_name":"Photoluminescence","level":2,"score":0.4667392671108246},{"id":"https://openalex.org/C150539798","wikidata":"https://www.wikidata.org/wiki/Q757561","display_name":"Atom-transfer radical-polymerization","level":4,"score":0.46274641156196594},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2924773097038269},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1458943784236908},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.10860773921012878},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.057086825370788574},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1039/b813368a","doi":"https://doi.org/10.1039/b813368a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b813368a","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:scholarworks.umass.edu:pse_faculty_pubs-1214","doi":null,"is_oa":false,"landing_page_url":"https://scholarworks.umass.edu/pse_faculty_pubs/215","pdf_url":null,"source":{"id":"https://openalex.org/S4306402240","display_name":"ScholarWorks@UMassAmherst (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Polymer Science and Engineering Department Faculty Publication Series","raw_type":"text"},{"id":"pmh:oai:scholarworks.umass.edu:pse_faculty_pubs-1878","doi":null,"is_oa":true,"landing_page_url":"https://scholarworks.umass.edu/pse_faculty_pubs/879","pdf_url":null,"source":{"id":"https://openalex.org/S4306402240","display_name":"ScholarWorks@UMassAmherst (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Polymer Science and Engineering Department Faculty Publication Series","raw_type":"text"},{"id":"pmh:oai:https://open.metu.edu.tr:11511/40262","doi":null,"is_oa":true,"landing_page_url":"https://hdl.handle.net/11511/40262","pdf_url":null,"source":{"id":"https://openalex.org/S4306402495","display_name":"OpenMETU (Middle East Technical University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I201799495","host_organization_name":"Middle East Technical University","host_organization_lineage":["https://openalex.org/I201799495"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Journal Article"},{"id":"pmh:oai:scholarworks.umass.edu:20.500.14394/41538","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/20.500.14394/41538","pdf_url":null,"source":{"id":"https://openalex.org/S4306402057","display_name":"Scholarworks (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"published","raw_type":"Article"}],"best_oa_location":{"id":"pmh:oai:scholarworks.umass.edu:pse_faculty_pubs-1878","doi":null,"is_oa":true,"landing_page_url":"https://scholarworks.umass.edu/pse_faculty_pubs/879","pdf_url":null,"source":{"id":"https://openalex.org/S4306402240","display_name":"ScholarWorks@UMassAmherst (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Polymer Science and Engineering Department Faculty Publication Series","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1964201673","https://openalex.org/W1975313650","https://openalex.org/W1987229291","https://openalex.org/W1989552368","https://openalex.org/W1996291528","https://openalex.org/W2002617028","https://openalex.org/W2015240500","https://openalex.org/W2019213642","https://openalex.org/W2024839231","https://openalex.org/W2025583925","https://openalex.org/W2033597053","https://openalex.org/W2048210519","https://openalex.org/W2049712036","https://openalex.org/W2054006338","https://openalex.org/W2056941140","https://openalex.org/W2066299337","https://openalex.org/W2066384548","https://openalex.org/W2069915015","https://openalex.org/W2071134066","https://openalex.org/W2073328540","https://openalex.org/W2078533766","https://openalex.org/W2081444239","https://openalex.org/W2082815739","https://openalex.org/W2087513315","https://openalex.org/W2094140969","https://openalex.org/W2098508266","https://openalex.org/W2102521642","https://openalex.org/W2123711607","https://openalex.org/W2131873809","https://openalex.org/W2132012759","https://openalex.org/W2143546404","https://openalex.org/W2150677598"],"related_works":["https://openalex.org/W2518230457","https://openalex.org/W2054932903","https://openalex.org/W2115588167","https://openalex.org/W2313574534","https://openalex.org/W2926791030","https://openalex.org/W3178600880","https://openalex.org/W2003744941","https://openalex.org/W2322930500","https://openalex.org/W2024839231","https://openalex.org/W2094140969"],"abstract_inverted_index":{"A":[0,55],"new,":[1],"well-defined":[2],"diblock":[3,52,81],"copolymer":[4,53,82,94,133],"(P3HT-b-C60)":[5],"based":[6],"on":[7],"regioregular":[8,16],"poly(3-hexylthiophene)":[9],"(P3HT)":[10],"and":[11,24,29,124,153],"fullerene":[12,56],"was":[13,18,65],"synthesized.":[14],"First,":[15],"P3HT":[17,39,109,123,152],"synthesized":[19],"through":[20],"Grignard":[21],"metathesis":[22],"polymerization,":[23],"then":[25,66],"methyl":[26],"methacrylate":[27,31],"(MMA)":[28],"2-hydroxyethyl":[30],"(HEMA)":[32],"were":[33],"copolymerized":[34],"by":[35],"using":[36],"an":[37],"end-functionalized":[38],"as":[40],"a":[41,51,80,99,127,138],"macroinitiator":[42],"for":[43,103],"the":[44,70,74,84,93,108,115,131,135],"atom":[45],"transfer":[46,150],"radical":[47],"polymerization":[48],"to":[49,69,78,111,119],"yield":[50],"(P3HT-b-P(MMA-r-HEMA)).":[54],"derivative":[57],"functionalized":[58],"with":[59,83],"carboxylic":[60],"acid,":[61],"[6,6]-phenyl-C61-butyric":[62],"acid":[63],"(PCBA),":[64],"chemically":[67],"linked":[68],"HEMA":[71],"unit":[72],"in":[73,107,134],"second":[75,85],"block":[76,86],"(P(MMA-r-HEMA))":[77],"produce":[79],"containing":[87],"fullerenes.":[88],"Annealing":[89],"thin":[90],"films":[91,136],"of":[92,122,130,141,143,148],"revealed":[95],"nanometer-scale":[96],"phase":[97],"separation,":[98],"more":[100,112],"suitable":[101],"morphology":[102],"enabling":[104],"excitons":[105],"generated":[106],"domain":[110],"efficiently":[113],"reach":[114],"donor\u2013acceptor":[116],"interface,":[117],"relative":[118],"simple":[120],"blends":[121],"C60.":[125],"As":[126],"result,":[128],"photoluminescence":[129,142],"P3HT-b-C60diblock":[132],"showed":[137],"complete":[139],"quenching":[140],"P3HT,":[144],"which":[145],"is":[146],"indicative":[147],"charge":[149],"between":[151],"fullerene.":[154]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":11},{"year":2015,"cited_by_count":14},{"year":2014,"cited_by_count":13},{"year":2013,"cited_by_count":15},{"year":2012,"cited_by_count":11}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2016-06-24T00:00:00"}
