{"id":"https://openalex.org/W2105234635","doi":"https://doi.org/10.4319/lo.1997.42.5.0901","title":"The role of organic complexation on ambient iron chemistry in the equatorial Pacific Ocean and the response of a mesoscale iron addition experiment","display_name":"The role of organic complexation on ambient iron chemistry in the equatorial Pacific Ocean and the response of a mesoscale iron addition experiment","publication_year":1997,"publication_date":"1997-07-01","ids":{"openalex":"https://openalex.org/W2105234635","doi":"https://doi.org/10.4319/lo.1997.42.5.0901","mag":"2105234635"},"language":"en","primary_location":{"id":"doi:10.4319/lo.1997.42.5.0901","doi":"https://doi.org/10.4319/lo.1997.42.5.0901","is_oa":true,"landing_page_url":"https://doi.org/10.4319/lo.1997.42.5.0901","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.4319/lo.1997.42.5.0901","source":{"id":"https://openalex.org/S207705515","display_name":"Limnology and Oceanography","issn_l":"0024-3590","issn":["0024-3590","1939-5590","1939-5604"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Limnology and Oceanography","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.4319/lo.1997.42.5.0901","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110632191","display_name":"Eden L. Rue","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I135369504","display_name":"California State University, Monterey Bay","ror":"https://ror.org/00mjdtw98","country_code":"US","type":"education","lineage":["https://openalex.org/I135369504"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Eden L. Rue","raw_affiliation_strings":["Institute for Earth Systems Science and Policy, California State University Monterey Bay, Seaside, California 93955"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute for Earth Systems Science and Policy, California State University Monterey Bay, Seaside, California 93955","institution_ids":["https://openalex.org/I135369504"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5112111074","display_name":"Kenneth W. Bruland","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185103710","display_name":"University of California, Santa Cruz","ror":"https://ror.org/03s65by71","country_code":"US","type":"education","lineage":["https://openalex.org/I185103710"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kenneth W. Bruland","raw_affiliation_strings":["Institute of Marine Sciences, University of California at Santa Cruz, Santa Cruz, California 95064"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Marine Sciences, University of California at Santa Cruz, Santa Cruz, California 95064","institution_ids":["https://openalex.org/I185103710"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3530,"currency":"USD","value_usd":3530},"apc_paid":null,"fwci":13.7454,"has_fulltext":true,"cited_by_count":384,"citation_normalized_percentile":{"value":0.99519367,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":94,"max":100},"biblio":{"volume":"42","issue":"5","first_page":"901","last_page":"910"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10032","display_name":"Marine and coastal ecosystems","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1910","display_name":"Oceanography"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10032","display_name":"Marine and coastal ecosystems","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1910","display_name":"Oceanography"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11418","display_name":"Plant Micronutrient Interactions and Effects","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/1110","display_name":"Plant Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10109","display_name":"Paleontology and Stratigraphy of Fossils","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/1911","display_name":"Paleontology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iron-speciation","display_name":"iron speciation","score":0.5709999799728394},{"id":"https://openalex.org/keywords/organic-ligands","display_name":"organic ligands","score":0.5849999785423279},{"id":"https://openalex.org/keywords/dissolved-iron","display_name":"dissolved iron","score":0.7459999918937683},{"id":"https://openalex.org/keywords/equatorial-pacific","display_name":"equatorial Pacific","score":0.6570000052452087},{"id":"https://openalex.org/keywords/south-equatorial-current","display_name":"South Equatorial Current","score":0.9470000267028809},{"id":"https://openalex.org/keywords/conditional-stability-constants","display_name":"conditional stability constants","score":0.7440000176429749},{"id":"https://openalex.org/keywords/iron-bioavailability","display_name":"iron bioavailability","score":0.6389999985694885},{"id":"https://openalex.org/keywords/iron-limitation","display_name":"iron limitation","score":0.4009999930858612},{"id":"https://openalex.org/keywords/phytoplankton-growth","display_name":"phytoplankton growth","score":0.6499999761581421}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7630162239074707},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7293027639389038},{"id":"https://openalex.org/C2776838516","wikidata":"https://www.wikidata.org/wiki/Q187787","display_name":"Genetic algorithm","level":2,"score":0.4730089008808136},{"id":"https://openalex.org/C40382383","wikidata":"https://www.wikidata.org/wiki/Q2399824","display_name":"Mesoscale meteorology","level":2,"score":0.4473787248134613},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4148203730583191},{"id":"https://openalex.org/C36574619","wikidata":"https://www.wikidata.org/wiki/Q449096","display_name":"Dissolved organic carbon","level":2,"score":0.41008177399635315},{"id":"https://openalex.org/C107872376","wikidata":"https://www.wikidata.org/wiki/Q321355","display_name":"Environmental chemistry","level":1,"score":0.3857230544090271},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3375653326511383},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.08868932723999023},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.06349557638168335},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.06206348538398743},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C78458016","wikidata":"https://www.wikidata.org/wiki/Q840400","display_name":"Evolutionary biology","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.4319/lo.1997.42.5.0901","doi":"https://doi.org/10.4319/lo.1997.42.5.0901","is_oa":true,"landing_page_url":"https://doi.org/10.4319/lo.1997.42.5.0901","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.4319/lo.1997.42.5.0901","source":{"id":"https://openalex.org/S207705515","display_name":"Limnology and Oceanography","issn_l":"0024-3590","issn":["0024-3590","1939-5590","1939-5604"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Limnology and Oceanography","raw_type":"journal-article"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.297.1864","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.297.1864","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://www.aslo.org/lo/toc/vol_42/issue_5/0901.pdf","raw_type":"text"}],"best_oa_location":{"id":"doi:10.4319/lo.1997.42.5.0901","doi":"https://doi.org/10.4319/lo.1997.42.5.0901","is_oa":true,"landing_page_url":"https://doi.org/10.4319/lo.1997.42.5.0901","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.4319/lo.1997.42.5.0901","source":{"id":"https://openalex.org/S207705515","display_name":"Limnology and Oceanography","issn_l":"0024-3590","issn":["0024-3590","1939-5590","1939-5604"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Limnology and Oceanography","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/14","display_name":"Life below water","score":0.8899999856948853}],"study_designs":[],"awards":[{"id":"https://openalex.org/G2787413044","display_name":"Interdependence of Trace Metal Speciation and Phytoplankton Dynamics in the Eastern North Pacific","funder_award_id":"9416606","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337345","display_name":"Office of Naval Research","ror":"https://ror.org/00rk2pe57"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2105234635.pdf","grobid_xml":"https://content.openalex.org/works/W2105234635.grobid-xml"},"referenced_works_count":25,"referenced_works":["https://openalex.org/W1965102064","https://openalex.org/W1969647438","https://openalex.org/W1980773918","https://openalex.org/W1990337497","https://openalex.org/W1993144090","https://openalex.org/W2003714836","https://openalex.org/W2013900698","https://openalex.org/W2014077506","https://openalex.org/W2022723077","https://openalex.org/W2022800776","https://openalex.org/W2025700565","https://openalex.org/W2037669529","https://openalex.org/W2053660667","https://openalex.org/W2053751618","https://openalex.org/W2055898789","https://openalex.org/W2064040135","https://openalex.org/W2094254199","https://openalex.org/W2100612502","https://openalex.org/W2104229600","https://openalex.org/W2105911492","https://openalex.org/W2112246761","https://openalex.org/W2125252128","https://openalex.org/W2150336317","https://openalex.org/W2158931004","https://openalex.org/W2170089944"],"related_works":["https://openalex.org/W3139950680","https://openalex.org/W2980864800","https://openalex.org/W1577772939","https://openalex.org/W2747716046","https://openalex.org/W2013542667","https://openalex.org/W2019354284","https://openalex.org/W857662152","https://openalex.org/W2085182832","https://openalex.org/W2070071042","https://openalex.org/W2355923136"],"abstract_inverted_index":{"We":[0],"participated":[1],"on":[2],"the":[3,8,31,37,51,121,152,157,174,188,211,246,250],"Iron\u2010Ex":[4,154,227],"II":[5,155,228],"study":[6],"in":[7,30,218,224,262],"equatorial":[9],"Pacific":[10],"to":[11,19,165,187,198,264,268,276],"investigate":[12],"ambient":[13,122],"iron":[14,22,28,110,179,266,274],"chemistry":[15],"and":[16,74,81,91,132],"its":[17],"response":[18,263],"a":[20,70,75,82,87,92,169,207,225],"mesoscale":[21,178],"addition":[23],"experiment.":[24],"As":[25],"expected,":[26],"dissolved":[27,55,109,123],"values":[29],"high\u2010nutrient,":[32],"low\u2010chlorophyll":[33],"surface":[34],"waters":[35],"of":[36,50,54,61,78,95,120,182,249],"South":[38],"Equatorial":[39],"Current":[40],"(4\u20136\u00b0S,":[41],"105\u2013109\u00b0W)":[42],"were":[43,104,222],"extremely":[44],"low":[45],"(\u223c20":[46,112],"pM).":[47,113],"In":[48,151],"studies":[49],"chemical":[52],"speciation":[53],"iron,":[56],"we":[57],"found":[58],"two":[59,172],"classes":[60],"Fe(III)\u2010binding":[62,100,159,219,256],"organic":[63,101,130,257],"ligands\u2014a":[64],"strong":[65],"ligand":[66,102,160,190,203,220],"class":[67,84,204],"(L1)":[68],"with":[69,86,128,138],"conditional":[71,88],"stability":[72,89],"constant":[73,90],"mean":[76,93],"concentration":[77,94],"310":[79],"pM,":[80],"weaker":[83,202],"(L2)":[85],"190":[96],"pM.":[97],"The":[98,201,272],"total":[99,108,158,212],"concentrations":[103,111,161,221],"\u223c25\u00d7":[105],"higher":[106],"than":[107],"Thermodynamic":[114],"equilibrium":[115],"calculations":[116],"indicate":[117],"that":[118,254],">99.9%":[119],"Fe(III)":[124,136],"would":[125],"be":[126,277],"complexed":[127],"these":[129,255],"ligands":[131,258],"exist":[133],"as":[134,146],"low\u2010molecular\u2010weight":[135],"chelates,":[137],"<0.1%":[139],"(15":[140],"fM":[141],"or":[142,171,279],"\u223c10\u221214":[143],"M)":[144],"existing":[145],"an":[147,234],"inorganic":[148],"Fe(III)\u2032":[149],"fraction.":[150],"primary":[153],"study,":[156],"increased":[162,194,205],"by":[163,206],"400%":[164],"\u223c2":[166],"nM":[167,177,197,238],"within":[168,230],"day":[170],"after":[173,233],"initial":[175,235],"2":[176],"injection.":[180],"Most":[181],"this":[183,269],"increase":[184],"was":[185,214],"due":[186],"stronger":[189],"class,":[191],"L1,":[192],"which":[193],"from":[195,242],"0.3":[196],"1.3":[199],"nM.":[200],"similar":[208],"percentage,":[209],"although":[210],"magnitude":[213],"smaller.":[215],"Similar":[216],"increases":[217],"observed":[223],"secondary":[226],"experiment":[229],"17":[231],"h":[232],"low\u2010iron":[236,270],"0.4":[237],"infusion.":[239],"Results":[240],"obtained":[241],"samples":[243],"collected":[244],"throughout":[245],"entire":[247],"course":[248],"iron\u2010enrichment":[251],"experiments":[252],"suggest":[253],"are":[259],"produced":[260],"rapidly":[261],"small":[265],"additions":[267],"regime.":[271],"chelated":[273],"appears":[275],"directly":[278],"indirectly":[280],"accessible":[281],"for":[282],"growth.":[283]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":10},{"year":2022,"cited_by_count":6},{"year":2021,"cited_by_count":17},{"year":2020,"cited_by_count":10},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":8},{"year":2015,"cited_by_count":9},{"year":2014,"cited_by_count":15},{"year":2013,"cited_by_count":13},{"year":2012,"cited_by_count":18}],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2025-10-10T00:00:00"}