{"id":"https://openalex.org/W2104473196","doi":"https://doi.org/10.1039/c2sm06117a","title":"Self-assembly of a semi-fluorinated diblock copolymer in a selective solvent","display_name":"Self-assembly of a semi-fluorinated diblock copolymer in a selective solvent","publication_year":2012,"publication_date":"2012-01-01","ids":{"openalex":"https://openalex.org/W2104473196","doi":"https://doi.org/10.1039/c2sm06117a","mag":"2104473196"},"language":"en","primary_location":{"id":"doi:10.1039/c2sm06117a","doi":"https://doi.org/10.1039/c2sm06117a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2sm06117a","pdf_url":null,"source":{"id":"https://openalex.org/S6377669","display_name":"Soft Matter","issn_l":"1744-683X","issn":["1744-683X","1744-6848"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-2","medline","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Soft Matter","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110540108","display_name":"Dilru R. Ratnaweera","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Dilru R. Ratnaweera","raw_affiliation_strings":["Department of Chemistry, Clemson University, Clemson, SC, USA","Department of Chemistry, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Clemson University, Clemson, SC, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070094665","display_name":"Umesh M. Shrestha","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Umesh M. Shrestha","raw_affiliation_strings":["Department of Chemistry, Clemson University, Clemson, SC, USA","Department of Chemistry, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Clemson University, Clemson, SC, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077341845","display_name":"Naresh C. Osti","orcid":"https://orcid.org/0000-0002-0213-2299","observed_orcids":["https://orcid.org/0000-0002-0213-2299"]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Naresh Osti","raw_affiliation_strings":["Department of Chemistry, Clemson University, Clemson, SC, USA","Department of Chemistry, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Clemson University, Clemson, SC, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010278682","display_name":"Chung\u2010Mien Kuo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63135867","display_name":"University of Cincinnati","ror":"https://ror.org/01e3m7079","country_code":"US","type":"education","lineage":["https://openalex.org/I63135867"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Chung-Mien Kuo","raw_affiliation_strings":["Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, OH, USA","Department of Chemical and Materials Engineering, University of Cincinnati Cincinnati, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, OH, USA","institution_ids":["https://openalex.org/I63135867"]},{"raw_affiliation_string":"Department of Chemical and Materials Engineering, University of Cincinnati Cincinnati, USA","institution_ids":["https://openalex.org/I63135867"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004629185","display_name":"Stephen John Clarson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63135867","display_name":"University of Cincinnati","ror":"https://ror.org/01e3m7079","country_code":"US","type":"education","lineage":["https://openalex.org/I63135867"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stephen Clarson","raw_affiliation_strings":["Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, OH, USA","Department of Chemical and Materials Engineering, University of Cincinnati Cincinnati, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, OH, USA","institution_ids":["https://openalex.org/I63135867"]},{"raw_affiliation_string":"Department of Chemical and Materials Engineering, University of Cincinnati Cincinnati, USA","institution_ids":["https://openalex.org/I63135867"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049743322","display_name":"Kenneth C. Littrell","orcid":"https://orcid.org/0000-0003-2308-8618","observed_orcids":["https://orcid.org/0000-0003-2308-8618"]},"institutions":[{"id":"https://openalex.org/I1289243028","display_name":"Oak Ridge National Laboratory","ror":"https://ror.org/01qz5mb56","country_code":"US","type":"facility","lineage":["https://openalex.org/I1289243028","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I4210159294"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ken Littrell","raw_affiliation_strings":["Oak Ridge National Laboratory, PO Box 2008 MS6393, Oak Ridge, TN, USA","Oak Ridge National Laboratory, PO Box 2008 MS6393,Oak Ridge,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Oak Ridge National Laboratory, PO Box 2008 MS6393, Oak Ridge, TN, USA","institution_ids":["https://openalex.org/I1289243028"]},{"raw_affiliation_string":"Oak Ridge National Laboratory, PO Box 2008 MS6393,Oak Ridge,USA","institution_ids":["https://openalex.org/I1289243028"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067183345","display_name":"Dvora Perahia","orcid":"https://orcid.org/0000-0002-8486-8645","observed_orcids":["https://orcid.org/0000-0002-8486-8645"]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Dvora Perahia","raw_affiliation_strings":["Department of Chemistry, Clemson University, Clemson, SC, USA","Department of Chemistry, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Clemson University, Clemson, SC, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5067183345"],"corresponding_institution_ids":["https://openalex.org/I8078737"],"apc_list":null,"apc_paid":null,"fwci":0.1304,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.43468489,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":93},"biblio":{"volume":"8","issue":"7","first_page":"2176","last_page":"2176"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.9775000214576721,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.9775000214576721,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.021700000390410423,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polystyrene","display_name":"polystyrene","score":0.9860000014305115},{"id":"https://openalex.org/keywords/self-assembly","display_name":"self-assembly","score":0.7089999914169312},{"id":"https://openalex.org/keywords/selective-solvents","display_name":"selective solvents","score":0.746999979019165},{"id":"https://openalex.org/keywords/toluene","display_name":"toluene","score":0.968999981880188},{"id":"https://openalex.org/keywords/micelles","display_name":"micelles","score":0.7609999775886536},{"id":"https://openalex.org/keywords/micelle-dissociation","display_name":"micelle dissociation","score":0.7099999785423279},{"id":"https://openalex.org/keywords/complex-fluids","display_name":"complex fluids","score":0.48399999737739563},{"id":"https://openalex.org/keywords/volume-fraction-dependence","display_name":"volume fraction dependence","score":0.4269999861717224}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.8337993621826172},{"id":"https://openalex.org/C11268172","wikidata":"https://www.wikidata.org/wiki/Q421110","display_name":"Micelle","level":3,"score":0.8056305646896362},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.6732988357543945},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.6330093145370483},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5581433176994324},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5562813878059387},{"id":"https://openalex.org/C2776139660","wikidata":"https://www.wikidata.org/wiki/Q426680","display_name":"Siloxane","level":3,"score":0.547666072845459},{"id":"https://openalex.org/C132841051","wikidata":"https://www.wikidata.org/wiki/Q4165337","display_name":"Small-angle neutron scattering","level":4,"score":0.487021267414093},{"id":"https://openalex.org/C104015590","wikidata":"https://www.wikidata.org/wiki/Q1451740","display_name":"Neutron scattering","level":3,"score":0.4772998094558716},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4294183850288391},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.4200296103954315},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3186383545398712},{"id":"https://openalex.org/C191486275","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Scattering","level":2,"score":0.24810713529586792},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.24194857478141785},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2378932535648346},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1796664595603943},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.11227592825889587},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.09804549813270569},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c2sm06117a","doi":"https://doi.org/10.1039/c2sm06117a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2sm06117a","pdf_url":null,"source":{"id":"https://openalex.org/S6377669","display_name":"Soft Matter","issn_l":"1744-683X","issn":["1744-683X","1744-6848"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-2","medline","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Soft Matter","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320337367","display_name":"Division of Materials Research","ror":"https://ror.org/01pc7k308"},{"id":"https://openalex.org/F4320338287","display_name":"Oak Ridge National Laboratory","ror":"https://ror.org/01qz5mb56"},{"id":"https://openalex.org/F4320338304","display_name":"Los Alamos National Laboratory","ror":"https://ror.org/01e41cf67"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W162194035","https://openalex.org/W1496887052","https://openalex.org/W1969358893","https://openalex.org/W1982695846","https://openalex.org/W1994038143","https://openalex.org/W1999614104","https://openalex.org/W2013535146","https://openalex.org/W2022598588","https://openalex.org/W2028221498","https://openalex.org/W2031838059","https://openalex.org/W2040010630","https://openalex.org/W2040180490","https://openalex.org/W2041875237","https://openalex.org/W2045140855","https://openalex.org/W2047404584","https://openalex.org/W2050968397","https://openalex.org/W2052400470","https://openalex.org/W2055284325","https://openalex.org/W2055798675","https://openalex.org/W2063660942","https://openalex.org/W2070205561","https://openalex.org/W2074958549","https://openalex.org/W2077105665","https://openalex.org/W2079614807","https://openalex.org/W2086754548","https://openalex.org/W2089374014","https://openalex.org/W2090686376","https://openalex.org/W2094753447","https://openalex.org/W2105035967","https://openalex.org/W2105520290","https://openalex.org/W2107974138","https://openalex.org/W2117294616","https://openalex.org/W2120675668","https://openalex.org/W2157498061","https://openalex.org/W2163328781"],"related_works":["https://openalex.org/W2031015152","https://openalex.org/W2420222105","https://openalex.org/W2079614807","https://openalex.org/W2351506879","https://openalex.org/W2169105025","https://openalex.org/W2326603275","https://openalex.org/W2078682320","https://openalex.org/W2029060572","https://openalex.org/W2550758541","https://openalex.org/W2010980414"],"abstract_inverted_index":{"The":[0,111,149],"self-assembly":[1],"of":[2,39,57,63,68,78,81,90,114,124],"a":[3,17,44,69],"highly":[4],"incompatible":[5],"siloxane":[6,64],"containing":[7],"semi-fluorinated":[8,70],"diblock":[9],"copolymer,":[10],"polytrifluoro":[11],"propyl":[12],"methylsiloxane-b-polystyrene":[13],"(SiF-PS),":[14],"in":[15,96,155,163],"toluene,":[16],"selective":[18],"solvent":[19],"for":[20],"polystyrene,":[21],"was":[22],"studied":[23],"using":[24],"Small":[25],"Angle":[26],"Neutron":[27],"Scattering.":[28],"Incompatibility":[29],"is":[30],"often":[31],"enhanced":[32],"by":[33,161],"inserting":[34],"fluorinated":[35],"segments":[36],"into":[37,65,175],"one":[38],"the":[40,48,55,58,61,66,79,115,125,140,158,164,169,172],"blocks":[41],"and":[42,75],"as":[43],"result":[45],"not":[46],"only":[47],"interchain":[49],"interactions":[50,83],"are":[51,133],"changed":[52],"but":[53],"also":[54],"rigidity":[56],"blocks.":[59],"Herein":[60],"incorporation":[62],"backbone":[67],"block":[71,117],"maintains":[72],"its":[73],"flexibility":[74],"allows":[76],"separation":[77],"effects":[80],"direct":[82],"due":[84],"to":[85,109,178],"fluorine":[86],"atoms":[87],"from":[88,107],"those":[89],"rigidity.":[91],"Measurements":[92],"were":[93,147],"carried":[94],"out":[95],"dilute":[97],"solutions":[98],"below":[99],"1":[100],"wt%,":[101],"at":[102,120,135],"volume":[103,122],"fractions":[104,123],"\u03d5SiF":[105,136],"ranging":[106],"0.0":[108],"0.5.":[110],"high":[112],"incompatibility":[113],"SiF":[116,126],"drives":[118],"aggregation":[119],"low":[121],"block,":[127],"where":[128],"spherical":[129],"core\u2013Gaussian":[130],"shell":[131],"aggregates":[132,159],"detected":[134],"=":[137],"0.16.":[138],"In":[139],"symmetric":[141],"SiF-PS":[142],"complex":[143],"fluid,":[144],"elongated":[145],"micelles":[146,150,173],"observed.":[148],"exhibited":[151],"unique":[152],"temperature":[153,170],"stability":[154],"comparison":[156],"with":[157],"formed":[160],"diblock-copolymers":[162],"lower":[165],"segregation":[166],"regime.":[167],"As":[168],"increases":[171],"dissociate":[174],"free":[176],"chains":[177],"form":[179],"unimolecular":[180],"micelles.":[181]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}